**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-43-4 |4-Chlorotoluene | 98.0 | 203-397-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 10 20 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure. Aspiration of material
into the lungs may cause chemical pneumonitis, which may be fatal.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Flammable
liquid and vapor.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with skin and eyes. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Use with adequate ventilation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 106-43-4:
Russia: 10 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colourless
Odor: None reported.
pH: Not available.
Vapor Pressure: 10 mm Hg @ 45 C
Viscosity: Not available.
Boiling Point: 162 deg C
Freezing/Melting Point: 7 deg C
Autoignition Temperature: Not applicable.
Flash Point: 121 deg F ( 49.44 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 1.070
Molecular Formula: C7H7Cl
Molecular Weight: 126.502
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-43-4: XS9010000
LD50/LC50:
CAS# 106-43-4: Inhalation, mouse: LC50 = 34 gm/m3/2H; Oral, mouse:
LD50 = 1900 mg/kg; Oral, rat: LD50 = 2100 mg/kg.
Carcinogenicity:
4-Chlorotoluene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROTOLUENES
Hazard Class: 3
UN Number: 2238
Packing Group: III
IMO
Shipping Name: CHLOROTOLUENES
Hazard Class: 3.3
UN Number: 2238
Packing Group: III
RID/ADR
Shipping Name: CHLOROTOLUENES
Hazard Class: 3
UN Number: 2238
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 106-43-4: 2
Canada
CAS# 106-43-4 is listed on Canada's NDSL List.
CAS# 106-43-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-43-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/04/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Succinamic Acid, 97%
| 638-32-4 |
|
Indole-6-Carboxylic Acid, 98+% (titr., dried basis)
| 1670-72-2 |
|
Methyl 2,2,2-Trichloroacetimidate, 98%
| 2533-69-9 |
|
(2R)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
2-Bromoethyl chloroformate, 97%
| 4801-27-8 |
|
4-Nitrobenzyl alcohol, 99%
| 619-73-8 |
|
4-Chlorotoluene, 98%
| 106-43-4 |
|
1,4-Dioxane-d8, 99 atom % D
| 123-91-1 |
|
1-Bromo-3-fluoropropane
| 352-91-0 |
|
(-)-Corey lactone benzoate
| 7732-18-5 |
|
4-Methoxy-3-buten-2-one, Tech., 90% (GC)
| 4652-27-1 |
|
1,2-Bis(diphenylphosphino)ethane
| 1663-45-2 |
|
Alpha, Alpha, Alpha-Tribromoquinaldine, 98+%
| 613-53-6 |
|
Methyl hydrazinocarboxylate, 97%
| 6294-89-9 |
|
2,6-Dinitroaniline, 97%
| 606-22-4 |
|
Alpha, Alpha-Dichlorotoluene, 95% (GC)
| 98-87-3 |
|
D-(+)-Turanose, 98%
| 547-25-1 |
|
Guanine Hydrochloride, 97% (UV-Vis)
| 635-39-2 |
|
Normal-Butylbenzene, 99+%
| 104-51-8 |
|
4-Cyanopyridine, 98%
| 100-48-1 |
|
1-Fluoro-3-nitrobenzene, 97%
| 402-67-5 |
|
(3-Cyanopropyl)trichlorosilane, 99+%
| 1071-27-8 |
|
Cholesteryl Myristate, Liquid Crystal, 97%
| 1989-52-2 |
|
4-Chloro-1,8-Naphthalic Anhydride, Tech., Contains ca 50% Moisture
| 4053-08-1 |
|
6-(Chloromethyl)uracil, 98%
| 18592-13-7 |
|
4,4'-Dipyridyl, 98%, Anhydrous
| 553-26-4 |
|
Aq 55s
| |
|
4-??n-(P-Methoxybenzylidene)Amino??Phenyl Acetate
| 10484-13-6 |
|
Tetraheptylammonium Iodide, 99% (Titr.)
| 3535-83-9 |
|
Abietic Acid, Tech., 85+% (titr.)
| 514-10-3 |
|
1,2,3,4-Tetrahydroquinoline, 98%
| 635-46-1 |
|
Fast Blue RR Salt
| 27766-45-6 |
|
6-Chloro-2,4-Dinitroaniline, 97%
| 3531-19-9 |
|
Tetrahexylammonium chloride
| 5922-92-9 |
|
3-Methyl-2-Nitrobenzyl Alcohol, 98%
| 80866-76-8 |
|
p-Fluorophenoxy-ethylbromide 95%
| 332-48-9 |
|
2-Chloro-2,2-diphenylacetyl chloride, 97%
| 2902-98-9 |
|
17-Methyltestosterone, 97.0-103.0% (on dry substance)
| 58-18-4 |
|
4-Fluorobenzoyl Chloride, 98%
| 403-43-0 |
|
3-Fluorophenol, 98%
| 372-20-3 |
|
1-(3-Dimethylaminopropyl)-3-Ethyl-Carbodiimide Hydrochloride, 98+%
| 25952-53-8 |
|
Poly(ethylene), Chlorosulfonated (contains 43% Cl, 1.1% S)
| 68037-39-8 |
|
2-Lepidylmalondialdehyde Sesquihydrate, 95%
| |
|
5-Bromosalicylaldehyde, 98%
| 1761-61-1 |
|
4-Morpholinobenzophenone, 99%
| 24758-49-4 |
|
Difurfurylsulfide, 96%
| 13678-67-6 |
|
3-(4-Fluorobenzoyl)-Propionic Acid, 97%
| 366-77-8 |
|
2-Formylphenoxyacetic acid, 98%
| 6280-80-4 |
|
3-Pentanol, 98%
| 584-02-1 |
|
Triphenylbismuth, 98% (GC)
| 603-33-8 |
|
|