**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4801-27-8 |2-Bromoethyl chloroformate | 97 | 225-361-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation.Corrosive.Lachrymator (substance which increases
the flow of tears).Moisture sensitive.The toxicological properties of
this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. The toxicological properties of this material
have not been fully investigated. May cause cyanosis of the
extremities. May cause skin rash (in milder cases), and cold and
clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Do NOT use water directly on fire. In case of fire, use water, dry
chemical, chemical foam, or alcohol-resistant foam. Use water spray
to cool fire-exposed containers. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust. Use a
spark-proof tool. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Contents may
develop pressure upon prolonged storage. Do not get in eyes, on skin,
or on clothing. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Do not ingest or inhale. Do
not allow contact with water. Discard contaminated shoes. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Keep from contact with
moist air and steam.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep refrigerated. (Store below 4C/39F.)
Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 4801-27-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 175 mm Hg @ 67 deg C
Viscosity: Not available.
Boiling Point: 67.0 - 68.0 deg C @ 11.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 61 deg C ( 141.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Decomposes.
Specific Gravity/Density: 1.7490g/cm3
Molecular Formula: C3H4BrClO2
Molecular Weight: 187.42
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Acids, strong bases, alcohols, amines, moisture, water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4801-27-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromoethyl chloroformate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.*
Hazard Class: 6.1 (8)
UN Number: 3277
Packing Group: II
IMO
Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.
Hazard Class: 6.1 (8)
UN Number: 3277
Packing Group: II
RID/ADR
Shipping Name: CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.
Hazard Class: 6.1
UN Number: 3277
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23 Toxic by inhalation.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4801-27-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4801-27-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4801-27-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #8 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Succinamic Acid, 97%
| 638-32-4 |
|
Indole-6-Carboxylic Acid, 98+% (titr., dried basis)
| 1670-72-2 |
|
Methyl 2,2,2-Trichloroacetimidate, 98%
| 2533-69-9 |
|
(2R)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
2-Bromoethyl chloroformate, 97%
| 4801-27-8 |
|
4-Nitrobenzyl alcohol, 99%
| 619-73-8 |
|
4-Chlorotoluene, 98%
| 106-43-4 |
|
1,4-Dioxane-d8, 99 atom % D
| 123-91-1 |
|
1-Bromo-3-fluoropropane
| 352-91-0 |
|
(-)-Corey lactone benzoate
| 7732-18-5 |
|
4-Methoxy-3-buten-2-one, Tech., 90% (GC)
| 4652-27-1 |
|
1,2-Bis(diphenylphosphino)ethane
| 1663-45-2 |
|
Alpha, Alpha, Alpha-Tribromoquinaldine, 98+%
| 613-53-6 |
|
Methyl hydrazinocarboxylate, 97%
| 6294-89-9 |
|
2,6-Dinitroaniline, 97%
| 606-22-4 |
|
Alpha, Alpha-Dichlorotoluene, 95% (GC)
| 98-87-3 |
|
D-(+)-Turanose, 98%
| 547-25-1 |
|
Guanine Hydrochloride, 97% (UV-Vis)
| 635-39-2 |
|
Normal-Butylbenzene, 99+%
| 104-51-8 |
|
4-Cyanopyridine, 98%
| 100-48-1 |
|
1-Fluoro-3-nitrobenzene, 97%
| 402-67-5 |
|
(3-Cyanopropyl)trichlorosilane, 99+%
| 1071-27-8 |
|
Cholesteryl Myristate, Liquid Crystal, 97%
| 1989-52-2 |
|
4-Chloro-1,8-Naphthalic Anhydride, Tech., Contains ca 50% Moisture
| 4053-08-1 |
|
6-(Chloromethyl)uracil, 98%
| 18592-13-7 |
|
4,4'-Dipyridyl, 98%, Anhydrous
| 553-26-4 |
|
Aq 55s
| |
|
4-??n-(P-Methoxybenzylidene)Amino??Phenyl Acetate
| 10484-13-6 |
|
Tetraheptylammonium Iodide, 99% (Titr.)
| 3535-83-9 |
|
Abietic Acid, Tech., 85+% (titr.)
| 514-10-3 |
|
1,2,3,4-Tetrahydroquinoline, 98%
| 635-46-1 |
|
Fast Blue RR Salt
| 27766-45-6 |
|
6-Chloro-2,4-Dinitroaniline, 97%
| 3531-19-9 |
|
Tetrahexylammonium chloride
| 5922-92-9 |
|
3-Methyl-2-Nitrobenzyl Alcohol, 98%
| 80866-76-8 |
|
p-Fluorophenoxy-ethylbromide 95%
| 332-48-9 |
|
2-Chloro-2,2-diphenylacetyl chloride, 97%
| 2902-98-9 |
|
17-Methyltestosterone, 97.0-103.0% (on dry substance)
| 58-18-4 |
|
4-Fluorobenzoyl Chloride, 98%
| 403-43-0 |
|
3-Fluorophenol, 98%
| 372-20-3 |
|
1-(3-Dimethylaminopropyl)-3-Ethyl-Carbodiimide Hydrochloride, 98+%
| 25952-53-8 |
|
Poly(ethylene), Chlorosulfonated (contains 43% Cl, 1.1% S)
| 68037-39-8 |
|
2-Lepidylmalondialdehyde Sesquihydrate, 95%
| |
|
5-Bromosalicylaldehyde, 98%
| 1761-61-1 |
|
4-Morpholinobenzophenone, 99%
| 24758-49-4 |
|
Difurfurylsulfide, 96%
| 13678-67-6 |
|
3-(4-Fluorobenzoyl)-Propionic Acid, 97%
| 366-77-8 |
|
2-Formylphenoxyacetic acid, 98%
| 6280-80-4 |
|
3-Pentanol, 98%
| 584-02-1 |
|
Triphenylbismuth, 98% (GC)
| 603-33-8 |
|
|