**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 98-87-3 |Benzal Chloride | 95 | 202-709-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 22 23 37/38 40 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Toxic by inhalation. Irritating to respiratory
system and skin. Limited evidence of a carcinogenic effect. Risk of
serious damage to eyes.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. May cause redness, pain, blurred vision and
possible eye damage. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin irritation. May cause irritation and dermatitis. May
cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation.
Aspiration may lead to pulmonary edema. Can produce delayed
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation. Inhalation of large amounts may cause
respiratory stimulation, followed by respiratory depression,
convulsions and possible death due to respiratory paralysis.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not allow contact with water. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Keep from contact with
moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 98-87-3:
Germany: 0.015 ppm TWA; 0.1 mg/m3 TWA
Russia: 0.5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: toluene-like odor
pH: Not available.
Vapor Pressure: 3 mm Hg @ 25 C
Viscosity: Not available.
Boiling Point: 82-84C @ 11mmHg
Freezing/Melting Point: -17 deg C
Autoignition Temperature: Not applicable.
Flash Point: 88 deg C ( 190.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2950g/cm3
Molecular Formula: C7H6Cl2
Molecular Weight: 161.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-87-3: CZ5075000
LD50/LC50:
CAS# 98-87-3: Inhalation, mouse: LC50 = 32 ppm/2H; Inhalation,
mouse: LC50 = 210 mg/m3; Inhalation, rat: LC50 = 61 ppm/2H;
Inhalation, rat: LC50 = 400 mg/m3; Oral, mouse: LD50 = 2462 mg/kg;
Oral, mouse: LD50 = 1400 mg/kg; Oral, rat: LD50 = 3249 mg/kg; Oral,
rat: LD50 = 1400 mg/kg.
Carcinogenicity:
Benzal Chloride -
IARC: Group 2A carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BENZYLIDENE CHLORIDE
Hazard Class: 6.1
UN Number: 1886
Packing Group: II
IMO
Shipping Name: BENZYLIDENE CHLORIDE
Hazard Class: 6.1
UN Number: 1886
Packing Group: II
RID/ADR
Shipping Name: BENZYLIDENE CHLORIDE
Hazard Class: 6.1
UN Number: 1886
Packing group: II
USA RQ: CAS# 98-87-3: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 22 Harmful if swallowed.
R 23 Toxic by inhalation.
R 37/38 Irritating to respiratory system and skin.
R 40 Limited evidence of a carcinogenic effect.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 98-87-3: 3
Canada
CAS# 98-87-3 is listed on Canada's NDSL List.
CAS# 98-87-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 98-87-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/30/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Succinamic Acid, 97%
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|
Indole-6-Carboxylic Acid, 98+% (titr., dried basis)
| 1670-72-2 |
|
Methyl 2,2,2-Trichloroacetimidate, 98%
| 2533-69-9 |
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(2R)-2-Boc-Amino-3-Phenylsulfonyl-1-(2-Tetrahydropyranyloxy)Propane,
| 0-01-1 |
|
2-Bromoethyl chloroformate, 97%
| 4801-27-8 |
|
4-Nitrobenzyl alcohol, 99%
| 619-73-8 |
|
4-Chlorotoluene, 98%
| 106-43-4 |
|
1,4-Dioxane-d8, 99 atom % D
| 123-91-1 |
|
1-Bromo-3-fluoropropane
| 352-91-0 |
|
(-)-Corey lactone benzoate
| 7732-18-5 |
|
4-Methoxy-3-buten-2-one, Tech., 90% (GC)
| 4652-27-1 |
|
1,2-Bis(diphenylphosphino)ethane
| 1663-45-2 |
|
Alpha, Alpha, Alpha-Tribromoquinaldine, 98+%
| 613-53-6 |
|
Methyl hydrazinocarboxylate, 97%
| 6294-89-9 |
|
2,6-Dinitroaniline, 97%
| 606-22-4 |
|
Alpha, Alpha-Dichlorotoluene, 95% (GC)
| 98-87-3 |
|
D-(+)-Turanose, 98%
| 547-25-1 |
|
Guanine Hydrochloride, 97% (UV-Vis)
| 635-39-2 |
|
Normal-Butylbenzene, 99+%
| 104-51-8 |
|
4-Cyanopyridine, 98%
| 100-48-1 |
|
1-Fluoro-3-nitrobenzene, 97%
| 402-67-5 |
|
(3-Cyanopropyl)trichlorosilane, 99+%
| 1071-27-8 |
|
Cholesteryl Myristate, Liquid Crystal, 97%
| 1989-52-2 |
|
4-Chloro-1,8-Naphthalic Anhydride, Tech., Contains ca 50% Moisture
| 4053-08-1 |
|
6-(Chloromethyl)uracil, 98%
| 18592-13-7 |
|
4,4'-Dipyridyl, 98%, Anhydrous
| 553-26-4 |
|
Aq 55s
| |
|
4-??n-(P-Methoxybenzylidene)Amino??Phenyl Acetate
| 10484-13-6 |
|
Tetraheptylammonium Iodide, 99% (Titr.)
| 3535-83-9 |
|
Abietic Acid, Tech., 85+% (titr.)
| 514-10-3 |
|
1,2,3,4-Tetrahydroquinoline, 98%
| 635-46-1 |
|
Fast Blue RR Salt
| 27766-45-6 |
|
6-Chloro-2,4-Dinitroaniline, 97%
| 3531-19-9 |
|
Tetrahexylammonium chloride
| 5922-92-9 |
|
3-Methyl-2-Nitrobenzyl Alcohol, 98%
| 80866-76-8 |
|
p-Fluorophenoxy-ethylbromide 95%
| 332-48-9 |
|
2-Chloro-2,2-diphenylacetyl chloride, 97%
| 2902-98-9 |
|
17-Methyltestosterone, 97.0-103.0% (on dry substance)
| 58-18-4 |
|
4-Fluorobenzoyl Chloride, 98%
| 403-43-0 |
|
3-Fluorophenol, 98%
| 372-20-3 |
|
1-(3-Dimethylaminopropyl)-3-Ethyl-Carbodiimide Hydrochloride, 98+%
| 25952-53-8 |
|
Poly(ethylene), Chlorosulfonated (contains 43% Cl, 1.1% S)
| 68037-39-8 |
|
2-Lepidylmalondialdehyde Sesquihydrate, 95%
| |
|
5-Bromosalicylaldehyde, 98%
| 1761-61-1 |
|
4-Morpholinobenzophenone, 99%
| 24758-49-4 |
|
Difurfurylsulfide, 96%
| 13678-67-6 |
|
3-(4-Fluorobenzoyl)-Propionic Acid, 97%
| 366-77-8 |
|
2-Formylphenoxyacetic acid, 98%
| 6280-80-4 |
|
3-Pentanol, 98%
| 584-02-1 |
|
Triphenylbismuth, 98% (GC)
| 603-33-8 |
|
|