**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-95-6 |Allyl bromide | 100 % | 203-446-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic if swallowed.Lachrymator (substance which
increases the flow of tears).Highly flammable.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns. May cause
perforation of the digestive tract.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema.
Chronic:
May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Material
will burn in a fire. Use water spray to keep fire-exposed containers
cool. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. May be ignited by friction, heat, sparks, or flame. May
polymerize explosively when involved in a fire. Containers may
explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. For large fires,
use water spray, fog or alcohol-resistant foam. Do NOT use straight
streams of water. Cool containers with flooding quantities of water
until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use only
in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Do not ingest or inhale. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry place. Keep container closed when not
in use. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 106-95-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Pungent odor.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 71 deg C
Freezing/Melting Point: -115 deg C
Autoignition Temperature: 295 deg C ( 563.00 deg F)
Flash Point: -1.1 deg C ( 30.02 deg F)
Explosion Limits, lower: 4.4
Explosion Limits, upper: 7.3
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 1.42 @ 20 C
Molecular Formula: C3H5Br
Molecular Weight: 120.939
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources.
Incompatibilities with Other Materials:
Strong oxidizing agents and strong bases. Contact with aluminum
chloride, boron trifluoride and sulfuric acid may cause exothermic
polymerization. Reacts violently with oxidants (e.g., bromine
difluoride, chromium (VI) oxide, potassium permanganate or sodium
peroxide.)
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-95-6: UC7090000
LD50/LC50:
CAS# 106-95-6: Inhalation, mouse: LC50 = 4110 mg/m3/2H; Inhalation,
rat: LC50 = 10 gm/m3/30M; Inhalation, rat: LC50 = 10000 mg/m3/2H;
Oral, rat: LD50 = 120 mg/kg.
Carcinogenicity:
Allyl bromide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYL BROMIDE
Hazard Class: 3
UN Number: 1099
Packing Group: I
IMO
Shipping Name: ALLYL BROMIDE
Hazard Class: 3
UN Number: 1099
Packing Group: I
RID/ADR
Shipping Name: ALLYL BROMIDE
Hazard Class: 3
UN Number: 1099
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 25 Toxic if swallowed.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 106-95-6: No information available.
Canada
CAS# 106-95-6 is listed on Canada's DSL List.
CAS# 106-95-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-95-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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