**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 56-40-6 |Glycine | 0.39 | 200-272-2 |
|----------------|--------------------------------------|----------|-----------|
| 7487-94-7 |Mercuric chloride | 0.001 | 231-299-8 |
|----------------|--------------------------------------|----------|-----------|
| 7647-01-0 |Hydrogen chloride | 0.18 | 231-595-7 |
|----------------|--------------------------------------|----------|-----------|
| 7647-14-5 |Sodium chloride | 0.31 | 231-598-3 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 99.119 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation and possible burns.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause severe irritation of the respiratory tract with possible
burns.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. Prolonged or repeated skin
contact may cause defatting and dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material will not burn. Use extinguishing media
appropriate to the surrounding fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 56-40-6:
Russia: 5 mg/m3 TWA
CAS# 7487-94-7:
United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary
and inorganic compounds).
Belgium - TWA: (listed as mercury, aryl and inorganic compounds):
mg/m3 VLE (as Hg)
France - VME: (listed as mercury, aryl and inorganic compounds):
mg/m3 VME (as Hg)
Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m
VME (as Hg)
Germany: (listed as mercury inorganic compounds): Skin absorber
Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1
mg/m3 TWA (as Hg)
Netherlands: (listed as mercury inorganic compounds): 0.15 mg/m3
Netherlands: (listed as mercury inorganic compounds): 0.05 mg/m3
Russia: (listed as mercury inorganic compounds): 0.2 mg/m3 TWA (a
Hg)
Russia: (listed as mercury inorganic compounds): 0.05 mg/m3 STEL
Hg)
Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/
VLA-ED (as Hg)
CAS# 7647-01-0:
United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg
TWA (aerosol mist and gas)
United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8
mg/m3 STEL (aerosol mist and gas)
United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE
France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE
Germany: 8 mg/m3 TWA
Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Netherlands: 10 ppm STEL; 15 mg/m3 STEL
Netherlands: 5 ppm MAC; 8 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC
CAS# 7647-14-5:
Russia: 5 mg/m3 TWA
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: 2.0
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Miscible with water
Specific Gravity/Density: 1.0
Molecular Formula: Mixture
Molecular Weight: Not available.
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
None reported.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, hydrogen gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 56-40-6: MB7600000
CAS# 7487-94-7: OV9100000
CAS# 7647-01-0: MW4025000 MW4031000
CAS# 7647-14-5: VZ4725000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 56-40-6: Oral, mouse: LD50 = 4920 mg/kg; Oral, rat: LD50 = 7930
mg/kg.
CAS# 7487-94-7: Draize test, rabbit, eye: 50 ug/24H Severe; Draize
test, rabbit, skin: 500 mg/24H Severe; Oral, mouse: LD50 = 6 mg/kg;
Oral, rat: LD50 = 1 mg/kg; Skin, rat: LD50 = 41 mg/kg.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation,
mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940
mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation,
rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M;
Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 =
45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral,
rabbit: LD50 = 900 mg/kg.
CAS# 7647-14-5: Draize test, rabbit, eye: 100 mg Mild; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, eye: 10 mg
Moderate; Draize test, rabbit, skin: 50 mg/24H Mild; Draize test,
rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >42 gm/m3/1H;
Oral, mouse: LD50 = 4 gm/kg; Oral, rat: LD50 = 3000 mg/kg; Skin,
rabbit: LD50 = >10 gm/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Glycine -
Not listed by ACGIH, IARC, or NTP.
Mercuric chloride -
Not listed by ACGIH, IARC, or NTP.
Hydrogen chloride -
Not listed by ACGIH, IARC, or NTP.
Sodium chloride -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 56-40-6: 0
CAS# 7487-94-7: 3
CAS# 7647-01-0: 1
CAS# 7647-14-5: 0
CAS# 7732-18-5: No information available.
Canada
CAS# 56-40-6 is listed on Canada's DSL List.
CAS# 7487-94-7 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 7647-14-5 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 56-40-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 7487-94-7 is listed on Canada's Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7647-14-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56-40-6 is listed on the TSCA inventory.
CAS# 7487-94-7 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
CAS# 7647-14-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 36/37/38 Irritating to eyes, respiratory system and
skin.
MSDS Creation Date: 12/12/1997 Revision #2 Date: 9/25/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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