**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 90-43-7 |Dowicide B | <1.0 | 201-993-5 |
|----------------|--------------------------------------|----------|-----------|
| 554-13-2 |Lithium carbonate | <1.0 | 209-062-5 |
|----------------|--------------------------------------|----------|-----------|
| 7447-40-7 |Potassium chloride | <1.0 | 231-211-8 |
|----------------|--------------------------------------|----------|-----------|
| 7647-14-5 |Sodium chloride | <1.0 | 231-598-3 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 10035-04-8 |Calcium Chloride Dihydrate | <1.0 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause irritation with pain and stinging, especially if the skin
is abraded.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish
surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash hands before eating. Use with adequate ventilation. Avoid
contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Good general ventilation should be sufficient to control airborne
levels.
Exposure Limits
CAS# 90-43-7:
CAS# 554-13-2:
CAS# 7447-40-7:
Russia: 5 mg/m3 TWA
CAS# 7647-14-5:
Russia: 5 mg/m3 TWA
CAS# 7732-18-5:
CAS# 10035-04-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Odorless.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Complete in water.
Specific Gravity/Density: Not available.
Molecular Formula: Not applicable.
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
High temperatures, incompatible materials.
Incompatibilities with Other Materials:
Reacts with most nonnoble metals such as iron or steel, building
materials (such as cement), bromine, or trifluoride. Potentially
explosive reaction with dichloromaleic anhydride + urea. Electrolysis
of mixtures with nitrogen compounds may form explosive nitrogen
trichloride.
Hazardous Decomposition Products:
Toxic fumes of sodium oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 90-43-7: DV5775000
CAS# 554-13-2: OJ5800000
CAS# 7447-40-7: TS8050000
CAS# 7647-14-5: VZ4725000
CAS# 7732-18-5: ZC0110000
CAS# 10035-04-8: EV9810000
LD50/LC50:
CAS# 90-43-7: Draize test, rabbit, eye: 50 ug/24H Severe; Draize
test, rabbit, skin: 250 mg; Draize test, rabbit, skin: 20 mg/24H
Moderate; Oral, mouse: LD50 = 1050 mg/kg; Oral, rat: LD50 = 2 gm/kg;
Oral, rat: LD50 = 2700 mg/kg.
CAS# 554-13-2: Oral, mouse: LD50 = 531 mg/kg; Oral, mouse: LD50 =
531 mg/kg; Oral, rabbit: LD50 = 404 mg/kg; Oral, rat: LD50 = 525
mg/kg; Oral, rat: LD50 = 553 mg/kg.
CAS# 7447-40-7: Draize test, rabbit, eye: 500 mg/24H Mild; Oral,
mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 = 2600 mg/kg.
CAS# 7647-14-5: Draize test, rabbit, eye: 100 mg Mild; Draize test,
rabbit, eye: 100 mg/24H Moderate; Draize test, rabbit, eye: 10 mg
Moderate; Draize test, rabbit, skin: 50 mg/24H Mild; Draize test,
rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >42 gm/m3/1H;
Oral, mouse: LD50 = 4 gm/kg; Oral, rat: LD50 = 3000 mg/kg; Skin,
rabbit: LD50 = >10 gm/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 10035-04-8.
Carcinogenicity:
Dowicide B -
California: carcinogen, initial date 8/4/00
Lithium carbonate -
Not listed by ACGIH, IARC, or NTP.
Potassium chloride -
Not listed by ACGIH, IARC, or NTP.
Sodium chloride -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Calcium Chloride Dihydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
No information found
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 90-43-7: 2
CAS# 554-13-2: 1
CAS# 7447-40-7: 1
CAS# 7647-14-5: 0
CAS# 7732-18-5: No information available.
CAS# 10035-04-8: No information available.
Canada
CAS# 90-43-7 is listed on Canada's DSL List.
CAS# 554-13-2 is listed on Canada's DSL List.
CAS# 7447-40-7 is listed on Canada's DSL List.
CAS# 7647-14-5 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 90-43-7 is listed on Canada's Ingredient Disclosure List.
CAS# 554-13-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 7447-40-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7647-14-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 10035-04-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 90-43-7 is listed on the TSCA inventory.
CAS# 554-13-2 is listed on the TSCA inventory.
CAS# 7447-40-7 is listed on the TSCA inventory.
CAS# 7647-14-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 10035-04-8 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 10/07/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|