**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 121-51-7 |Benzenesulfonyl chloride, 3-nitro- | 97 | 204-476-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. May cause abdominal
pain, nausea, vomiting, and inflammation of the gums and mouth.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER! Do NOT
get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Do not breathe dust,
vapor, mist, or gas. Keep container tightly closed. Do not get on
skin or in eyes. Do not ingest or inhale. Use with adequate
ventilation. Do not allow contact with water. Use only in a chemical
fume hood. Discard contaminated shoes. Keep from contact with moist
air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Corrosives area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 121-51-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to off-white
Odor: Sharp pungent odor.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 63 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes in water
Specific Gravity/Density:
Molecular Formula: C6H4ClNO4S
Molecular Weight: 221.62
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if heated.
Conditions to Avoid:
Incompatible materials, moisture, temperatures above 200C, exposure
to moist air or water.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of
sulfur, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 121-51-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzenesulfonyl chloride, 3-nitro- -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 121-51-7: 2
Canada
CAS# 121-51-7 is listed on Canada's DSL List.
CAS# 121-51-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 121-51-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/19/1999 Revision #3 Date: 10/10/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Iododecane, 99% (GC)
| 2050-77-3 |
|
N-Methylmaleamic Acid, 99+%
| 6936-48-7 |
|
9-Bromophenanthrene, 96%
| 573-17-1 |
|
N-(2-Chloroethyl)acetamide, 98%
| 7355-58-0 |
|
3-Nitrobenzenesulfonyl chloride, 97%
| 121-51-7 |
|
1,3-Diiodopropane, 99%
| 627-31-6 |
|
Ammonium Sulfobetaine - 15 % Solution in Water
| 0-00-1 |
|
2-Amino-3-picoline, 96%
| 1603-40-3 |
|
2-Amino-4-Phenyl-5-N-Tetradecylthiazole, 98%
| 64415-14-1 |
|
3-Endo-Aminobicyclo??2.2.1??Hept-5-ene-2-Endo-Carboxamide, 99+%
| 105786-38-7 |
|
Palladium on activated carbon (3% pd)
| |
|
Triphenylethylene, 98+%
| 58-72-0 |
|
Zirconyl(IV)-nitrate hydrate
| 14985-18-3 |
|
3-Hydrazinoquinoline dihydrochloride, 96% (titr.)
| 61621-35-0 |
|
Vinyl crotonate, 98%
| 14861-06-4 |
|
Cyclopropyl methyl carbinol, 96%
| 765-42-4 |
|
8,8'-Quinolyl Disulfide
| 1160-28-7 |
|
5-(Hydroxymethyl)Furfural, 98%
| 67-47-0 |
|
Beta-D-Ribofuranose 1-Acetate 2,3,5-Tri-Benzoate, 99+ %
| 6972-71-0 |
|
2,6-Dichloropurine, 97%
| 5451-40-1 |
|
9-Isopropylcarbazole
| 1484-09-9 |
|
alpha-Methylene-gamma-butyrolactone
| 547-65-9 |
|
Perfluoro-Compound FC-43
| 311-89-7 |
|
Hexanal, 96%
| 66-25-1 |
|
1-Chloro-4-Iodobenzene, 99%
| 637-87-6 |
|
(2R,3S)-(-)-2-Amino-3-hydroxy-4-methylpentanoic acid, 99.5+%
| 87421-23-6 |
|
5-Bromofuroic acid
| 585-70-6 |
|
Paraformaldehyde-D, 99+ atom% D
| 43094-80-0 |
|
Palladium(II) Acetate
| 3375-31-3 |
|
N-Glycyl-L-leucine
| 869-19-2 |
|
2-Aminopyridine, 99% (Titr.)
| 504-29-0 |
|
Terephthaldicarboxaldehyde, 98%
| 623-26-7 |
|
4-Hydroxy-3-methyl-2-butanone, tech. ca. 85%
| 3393-64-4 |
|
2-Chloroanthraquinone
| 131-09-9 |
|
2-Chloroethanol, 99+%
| 107-07-3 |
|
Benzilic acid, 99+%
| 76-93-7 |
|
trans-Diethyl caronate
| 67945-22-6 |
|
Quinine monohydrochloride dihydrate, 99%
| 6119-47-7 |
|
Ethyl 4-Chloroacetoacetate, 98%
| 638-07-3 |
|
2,4,6-Trinitrobenzenesulfonic acid, trihydrate, 90% (titr.)
| 2508-19-2 |
|
3,4-Dichlorobenzyl Chloride, 98+%
| 102-47-6 |
|
4-Aminobutyraldehyde diethyl acetal, ca. 95%(GC)
| 6346-09-4 |
|
Methyl propiolate, 99%
| 922-67-8 |
|
2-Mercaptobenzimidazole, 98%
| 583-39-1 |
|
(+/-)-2-Amino-1-butanol, 97%
| 13054-87-0 |
|
2-Hydrazinobenzoic Acid Hydrochloride, 97% (Titr.)
| 52356-01-1 |
|
Tetraphenylarsonium Chloride Hydrochloride Dihydrate, 97%
| 21006-74-6 |
|
Resazurin, sodium salt (cert), 85% (uv-vis )
| 62758-13-8 |
|
4-Hydroxy-3-Nitrobenzaldehyde, 97%
| 3011-34-5 |
|
Tributyl Citrate, 99+% (GC)
| 77-94-1 |
|
|