**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 67-47-0 |5-(Hydroxymethyl)Furfural | 98 | 200-654-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Light sensitive.The toxicological properties of this material have
not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Produces harmless yellow stains on the
skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 67-47-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: light brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 114.0 - 116.0 deg C @ 1.00mmH
Freezing/Melting Point: 32.00 - 35.00 deg C
Autoignition Temperature: Not available.
Flash Point: 79 deg C ( 174.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: C6H6O3
Molecular Weight: 126.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-47-0: LT7031100
LD50/LC50:
CAS# 67-47-0: Oral, rat: LD50 = 2500 mg/kg.
Carcinogenicity:
5-(Hydroxymethyl)Furfural -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 67-47-0: No information available.
Canada
CAS# 67-47-0 is listed on Canada's DSL List.
CAS# 67-47-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-47-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/25/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Iododecane, 99% (GC)
| 2050-77-3 |
|
N-Methylmaleamic Acid, 99+%
| 6936-48-7 |
|
9-Bromophenanthrene, 96%
| 573-17-1 |
|
N-(2-Chloroethyl)acetamide, 98%
| 7355-58-0 |
|
3-Nitrobenzenesulfonyl chloride, 97%
| 121-51-7 |
|
1,3-Diiodopropane, 99%
| 627-31-6 |
|
Ammonium Sulfobetaine - 15 % Solution in Water
| 0-00-1 |
|
2-Amino-3-picoline, 96%
| 1603-40-3 |
|
2-Amino-4-Phenyl-5-N-Tetradecylthiazole, 98%
| 64415-14-1 |
|
3-Endo-Aminobicyclo??2.2.1??Hept-5-ene-2-Endo-Carboxamide, 99+%
| 105786-38-7 |
|
Palladium on activated carbon (3% pd)
| |
|
Triphenylethylene, 98+%
| 58-72-0 |
|
Zirconyl(IV)-nitrate hydrate
| 14985-18-3 |
|
3-Hydrazinoquinoline dihydrochloride, 96% (titr.)
| 61621-35-0 |
|
Vinyl crotonate, 98%
| 14861-06-4 |
|
Cyclopropyl methyl carbinol, 96%
| 765-42-4 |
|
8,8'-Quinolyl Disulfide
| 1160-28-7 |
|
5-(Hydroxymethyl)Furfural, 98%
| 67-47-0 |
|
Beta-D-Ribofuranose 1-Acetate 2,3,5-Tri-Benzoate, 99+ %
| 6972-71-0 |
|
2,6-Dichloropurine, 97%
| 5451-40-1 |
|
9-Isopropylcarbazole
| 1484-09-9 |
|
alpha-Methylene-gamma-butyrolactone
| 547-65-9 |
|
Perfluoro-Compound FC-43
| 311-89-7 |
|
Hexanal, 96%
| 66-25-1 |
|
1-Chloro-4-Iodobenzene, 99%
| 637-87-6 |
|
(2R,3S)-(-)-2-Amino-3-hydroxy-4-methylpentanoic acid, 99.5+%
| 87421-23-6 |
|
5-Bromofuroic acid
| 585-70-6 |
|
Paraformaldehyde-D, 99+ atom% D
| 43094-80-0 |
|
Palladium(II) Acetate
| 3375-31-3 |
|
N-Glycyl-L-leucine
| 869-19-2 |
|
2-Aminopyridine, 99% (Titr.)
| 504-29-0 |
|
Terephthaldicarboxaldehyde, 98%
| 623-26-7 |
|
4-Hydroxy-3-methyl-2-butanone, tech. ca. 85%
| 3393-64-4 |
|
2-Chloroanthraquinone
| 131-09-9 |
|
2-Chloroethanol, 99+%
| 107-07-3 |
|
Benzilic acid, 99+%
| 76-93-7 |
|
trans-Diethyl caronate
| 67945-22-6 |
|
Quinine monohydrochloride dihydrate, 99%
| 6119-47-7 |
|
Ethyl 4-Chloroacetoacetate, 98%
| 638-07-3 |
|
2,4,6-Trinitrobenzenesulfonic acid, trihydrate, 90% (titr.)
| 2508-19-2 |
|
3,4-Dichlorobenzyl Chloride, 98+%
| 102-47-6 |
|
4-Aminobutyraldehyde diethyl acetal, ca. 95%(GC)
| 6346-09-4 |
|
Methyl propiolate, 99%
| 922-67-8 |
|
2-Mercaptobenzimidazole, 98%
| 583-39-1 |
|
(+/-)-2-Amino-1-butanol, 97%
| 13054-87-0 |
|
2-Hydrazinobenzoic Acid Hydrochloride, 97% (Titr.)
| 52356-01-1 |
|
Tetraphenylarsonium Chloride Hydrochloride Dihydrate, 97%
| 21006-74-6 |
|
Resazurin, sodium salt (cert), 85% (uv-vis )
| 62758-13-8 |
|
4-Hydroxy-3-Nitrobenzaldehyde, 97%
| 3011-34-5 |
|
Tributyl Citrate, 99+% (GC)
| 77-94-1 |
|
|