**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 14985-18-3 |Zirconyl(IV)-nitrate hydrate | 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: O C
Risk Phrases: 34 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns. Contact with combustible material may cause
fire.Hygroscopic (absorbs moisture from the air).Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts.
Extinguishing Media:
Use water only! Do NOT get water inside containers. Contact
professional fire-fighters immediately.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Do not get water
inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Keep container tightly closed. Avoid contact with
clothing and other combustible materials. Do not get on skin or in
eyes. Avoid ingestion and inhalation. Use with adequate ventilation.
Do not allow contact with water. Use only in a chemical fume hood.
Discard contaminated shoes. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry place. Keep container
closed when not in use. Corrosives area. Store protected from
moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 14985-18-3:
United Kingdom, WEL - TWA: (listed as zirconium compounds, n.o.s.
mg/m3 TWA (as Zr)
United Kingdom, WEL - STEL: (listed as zirconium compounds, n.o.s
10 mg/m3 STEL (as Zr)
United States OSHA: 5 mg/m3 TWA (as Zr) (listed under Zirconium
compounds, n.o.s.).
Belgium - TWA: (listed as zirconium compounds, n.o.s.): 5 mg/m3 V
(as Zr)
Belgium - STEL: (listed as zirconium compounds, n.o.s.): 10 mg/m3
(as Zr)
Malaysia: (listed as zirconium compounds, n.o.s.): 5 mg/m3 TWA (a
Zr)
Netherlands: (listed as zirconium compounds, n.o.s.): 5 mg/m3 MAC
Zr)
Spain: (listed as zirconium compounds, n.o.s.): 5 mg/m3 VLA-ED (a
Zr)
Spain: (listed as zirconium compounds, n.o.s.): 10 mg/m3 VLA-EC (
Zr)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to
prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to off-white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 100 deg C ( 212.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 100 deg C
Solubility in water: soluble in alcohol
Specific Gravity/Density:
Molecular Formula: N2O7Zr.xH2O
Molecular Weight: 231.23
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture,
combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents, moisture.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 14985-18-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Zirconyl(IV)-nitrate hydrate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ZIRCONIUM NITRATE
Hazard Class: 5.1
UN Number: 2728
Packing Group: III
IMO
Shipping Name: ZIRCONIUM NITRATE
Hazard Class: 5.1
UN Number: 2728
Packing Group: III
RID/ADR
Shipping Name: ZIRCONIUM NITRATE
Hazard Class: 5.1
UN Number: 2728
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 34 Causes burns.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14985-18-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 14985-18-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14985-18-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/08/1999 Revision #3 Date: 4/29/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Iododecane, 99% (GC)
| 2050-77-3 |
|
N-Methylmaleamic Acid, 99+%
| 6936-48-7 |
|
9-Bromophenanthrene, 96%
| 573-17-1 |
|
N-(2-Chloroethyl)acetamide, 98%
| 7355-58-0 |
|
3-Nitrobenzenesulfonyl chloride, 97%
| 121-51-7 |
|
1,3-Diiodopropane, 99%
| 627-31-6 |
|
Ammonium Sulfobetaine - 15 % Solution in Water
| 0-00-1 |
|
2-Amino-3-picoline, 96%
| 1603-40-3 |
|
2-Amino-4-Phenyl-5-N-Tetradecylthiazole, 98%
| 64415-14-1 |
|
3-Endo-Aminobicyclo??2.2.1??Hept-5-ene-2-Endo-Carboxamide, 99+%
| 105786-38-7 |
|
Palladium on activated carbon (3% pd)
| |
|
Triphenylethylene, 98+%
| 58-72-0 |
|
Zirconyl(IV)-nitrate hydrate
| 14985-18-3 |
|
3-Hydrazinoquinoline dihydrochloride, 96% (titr.)
| 61621-35-0 |
|
Vinyl crotonate, 98%
| 14861-06-4 |
|
Cyclopropyl methyl carbinol, 96%
| 765-42-4 |
|
8,8'-Quinolyl Disulfide
| 1160-28-7 |
|
5-(Hydroxymethyl)Furfural, 98%
| 67-47-0 |
|
Beta-D-Ribofuranose 1-Acetate 2,3,5-Tri-Benzoate, 99+ %
| 6972-71-0 |
|
2,6-Dichloropurine, 97%
| 5451-40-1 |
|
9-Isopropylcarbazole
| 1484-09-9 |
|
alpha-Methylene-gamma-butyrolactone
| 547-65-9 |
|
Perfluoro-Compound FC-43
| 311-89-7 |
|
Hexanal, 96%
| 66-25-1 |
|
1-Chloro-4-Iodobenzene, 99%
| 637-87-6 |
|
(2R,3S)-(-)-2-Amino-3-hydroxy-4-methylpentanoic acid, 99.5+%
| 87421-23-6 |
|
5-Bromofuroic acid
| 585-70-6 |
|
Paraformaldehyde-D, 99+ atom% D
| 43094-80-0 |
|
Palladium(II) Acetate
| 3375-31-3 |
|
N-Glycyl-L-leucine
| 869-19-2 |
|
2-Aminopyridine, 99% (Titr.)
| 504-29-0 |
|
Terephthaldicarboxaldehyde, 98%
| 623-26-7 |
|
4-Hydroxy-3-methyl-2-butanone, tech. ca. 85%
| 3393-64-4 |
|
2-Chloroanthraquinone
| 131-09-9 |
|
2-Chloroethanol, 99+%
| 107-07-3 |
|
Benzilic acid, 99+%
| 76-93-7 |
|
trans-Diethyl caronate
| 67945-22-6 |
|
Quinine monohydrochloride dihydrate, 99%
| 6119-47-7 |
|
Ethyl 4-Chloroacetoacetate, 98%
| 638-07-3 |
|
2,4,6-Trinitrobenzenesulfonic acid, trihydrate, 90% (titr.)
| 2508-19-2 |
|
3,4-Dichlorobenzyl Chloride, 98+%
| 102-47-6 |
|
4-Aminobutyraldehyde diethyl acetal, ca. 95%(GC)
| 6346-09-4 |
|
Methyl propiolate, 99%
| 922-67-8 |
|
2-Mercaptobenzimidazole, 98%
| 583-39-1 |
|
(+/-)-2-Amino-1-butanol, 97%
| 13054-87-0 |
|
2-Hydrazinobenzoic Acid Hydrochloride, 97% (Titr.)
| 52356-01-1 |
|
Tetraphenylarsonium Chloride Hydrochloride Dihydrate, 97%
| 21006-74-6 |
|
Resazurin, sodium salt (cert), 85% (uv-vis )
| 62758-13-8 |
|
4-Hydroxy-3-Nitrobenzaldehyde, 97%
| 3011-34-5 |
|
Tributyl Citrate, 99+% (GC)
| 77-94-1 |
|
|