**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 123-61-5 |Benzene, 1,3-diisocyanato- | 96 | 204-637-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. Harmful if absorbed through the skin. May
cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Organic isocyanates can
cause local irritation and allergic reactions.
Ingestion:
Harmful if swallowed.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. At high
concentrations, isocyanates affect mucous membranes of the
respiratory tract and may lead to fatal pulmonary edema. Exposure to
low and often even unmeasurable isocyanate concentration results in
sensitization.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals. Chronic overexposure to isocyanates has been
reported to cause lung damage, including decreased lung fuction,
which may be permanent.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use carbon dioxide or dry chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid breathing dust.
Isocyanates react with water to form CO2 gas. This gas can cause
sealed containers to expand and possibly rupture.
Storage:
Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Storage under a nitrogen blanket has been
recommended. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 123-61-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white to light yellow powder
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 48-52 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Decomposes.
Specific Gravity/Density:
Molecular Formula: C8H4N2O2
Molecular Weight: 160.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 123-61-5: NR0150000
LD50/LC50:
Not available.
Carcinogenicity:
Benzene, 1,3-diisocyanato- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOCYANATES, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
IMO
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing Group: III
RID/ADR
Shipping Name: ISOCYANATES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2206
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 123-61-5: No information available.
Canada
CAS# 123-61-5 is listed on Canada's NDSL List.
CAS# 123-61-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 123-61-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/18/1999 Revision #3 Date: 7/23/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Methylcyclopropanecarboxylic Acid, 98%
| 29555-02-0 |
|
m-Phenylene diisocyanate
| 123-61-5 |
|
2-Dodecanol, 99%
| 10203-28-8 |
|
Oxalic Acid Bis(Benzylidenehydrazide), 97% (UV-Vis)
| 6629-10-3 |
|
5-Bromopyrimidine, 98%
| 4595-59-9 |
|
4,6-Diamino-2-Mercaptopyrimidine, Hemihydrate, 99%
| 1004-39-3 |
|
4-(4'-Aminophenylazo)-Phenylarsonic Acid
| 6966-64-9 |
|
2,4-Dicyano-3-Methylglutaramide, 99%
| 5447-66-5 |
|
Ethyl trimethylacetate, 98%
| 3938-95-2 |
|
2-Mercapto-4-methylpyrimidine hydrochloride, 99%
| 6959-66-6 |
|
1-Pyrrolidinecarboxaldehyde, 97%
| 3760-54-1 |
|
n-Methyleneglycinonitrile (trimer)
| 6865-92-5 |
|
5-Methoxytryptamine hydrochloride, 97%
| 66-83-1 |
|
Nifuroxime
| 555-15-7 |
|
N-Alpha-Acetyl-L-Histidine Monohydrate 99+%
| 39145-52-3 |
|
11-Bromoundecanoic acid, tech., 93%
| 2834-05-1 |
|
Tert.-Butyl Disulfide, 98%
| 110-06-5 |
|
4'-Dodecyloxyacetophenone, 94% (GC)
| 2175-80-6 |
|
Ethylmagnesium chloride, 25 wt% solution in tetrahydrofuran
| 109-99-9 |
|
Methyl Vinyl Ether/Maleic Acid Copolymer, Low Molecular Weight
| 25153-40-6 |
|
Chlorohydroquinone, tech., 90%
| 615-67-8 |
|
Tri-n-octylphosphine oxide, 97%
| 78-50-2 |
|
Silver proteinate (mild)
| 9008-42-8 |
|
Lead (IV) Oxide, P.A.
| 1309-60-0 |
|
1,4-Butane Sultone, 99+%
| 1633-83-6 |
|
4-Chloro-3-Iodobenzotrifluoride, 99%
| 672-57-1 |
|
Theophylline, Anhydrous, U.S.P./N.F.
| 58-55-9 |
|
P-Anisoyl Chloride, 99%
| 100-07-2 |
|
3-Carboxy-1,4-dimethyl-1h-pyrrole-2-acetic acid
| 33369-45-8 |
|
4-Amino-2,6-dichlorophenol, 98%
| 5930-28-9 |
|
Aminoguanidine Hemisulfate
| 996-19-0 |
|
N-Methylmorpholine hydrochloride, 99+%
| 3651-67-0 |
|
2-Chloro-4,6-dimethoxy-1,3,5-triazine, 98%
| 3140-73-6 |
|
1-Heptyne, 99%
| 628-71-7 |
|
(R)-(+)-2,2'-Bis(diphenylphosphino)- 1,1'-binaphthyl, 99+%
| 76189-55-4 |
|
2-Propene-1-Sulfonic Acid Sodium Salt (Pract)
| 2495-39-8 |
|
6-Amino-1-Hexanol, 94%
| 4048-33-3 |
|
2,5-Dibromonitrobenzene, 97%
| 3460-18-2 |
|
Rubidium Fluoride Hydrate, 99+%
| 16422-67-6 |
|
7-Chloro-2H-1,4-Benzothiazin-3(4H)-One,99%
| 5333-05-1 |
|
2-Methyl-2-Nitropropane, 99%
| 594-70-7 |
|
N-Ethyl-n-butylamine, 99%
| 13360-63-9 |
|
2,6-Dimethylaniline, 99%
| 87-62-7 |
|
2-Chloro-3-Methylquinoline, 97%
| 57876-69-4 |
|
3-Cyanobenzaldehyde, 99%
| 24964-64-5 |
|
N,N'-Diallyltartardiamide, 99+%
| 28843-34-7 |
|
3-Aminobenzonitrile, 99%
| 2237-30-1 |
|
2-Chloropyridine-n-oxide hydrochloride, 97%
| 20295-64-1 |
|
Sodium perchlorate
| 7601-89-0 |
|
Butadiene sulfone, 98%
| 77-79-2 |
|
|