**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2237-30-1 |3-Aminobenzonitrile | 99% | 218-800-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful
amounts. If absorbed, causes symptoms similar to those of ingestion.
Ingestion:
May cause irritation of the digestive tract. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death. Effects
may be delayed 2 to 4 hours. Methemoglobinemia is characterized by
dizziness, drowsiness, headache, shortness of breath, cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood), rapid heart rate and chocolate-brown colored blood.
Inhalation:
Effects may be delayed. May cause cyanosis (bluish discoloration of
skin due to deficient oxygenation of the blood). Causes respiratory
tract irritation. May cause effects similar to those described for
ingestion.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Wash area with soap and water. Clean up spills
immediately, observing precautions in the Protective Equipment
section. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with skin and eyes.
Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 2237-30-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 288 - 290 deg C @ 760.00mm Hg
Freezing/Melting Point: 51 - 53 deg C
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble in water
Specific Gravity/Density:
Molecular Formula: C7H6N2
Molecular Weight: 118.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Acids; acid chlorides; acid anhydrides; chloroformates; strong
oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2237-30-1: DI2454000
LD50/LC50:
Not available.
Carcinogenicity:
3-Aminobenzonitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 2237-30-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2237-30-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2237-30-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 29555-02-0 |
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m-Phenylene diisocyanate
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2-Dodecanol, 99%
| 10203-28-8 |
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Oxalic Acid Bis(Benzylidenehydrazide), 97% (UV-Vis)
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|
5-Bromopyrimidine, 98%
| 4595-59-9 |
|
4,6-Diamino-2-Mercaptopyrimidine, Hemihydrate, 99%
| 1004-39-3 |
|
4-(4'-Aminophenylazo)-Phenylarsonic Acid
| 6966-64-9 |
|
2,4-Dicyano-3-Methylglutaramide, 99%
| 5447-66-5 |
|
Ethyl trimethylacetate, 98%
| 3938-95-2 |
|
2-Mercapto-4-methylpyrimidine hydrochloride, 99%
| 6959-66-6 |
|
1-Pyrrolidinecarboxaldehyde, 97%
| 3760-54-1 |
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n-Methyleneglycinonitrile (trimer)
| 6865-92-5 |
|
5-Methoxytryptamine hydrochloride, 97%
| 66-83-1 |
|
Nifuroxime
| 555-15-7 |
|
N-Alpha-Acetyl-L-Histidine Monohydrate 99+%
| 39145-52-3 |
|
11-Bromoundecanoic acid, tech., 93%
| 2834-05-1 |
|
Tert.-Butyl Disulfide, 98%
| 110-06-5 |
|
4'-Dodecyloxyacetophenone, 94% (GC)
| 2175-80-6 |
|
Ethylmagnesium chloride, 25 wt% solution in tetrahydrofuran
| 109-99-9 |
|
Methyl Vinyl Ether/Maleic Acid Copolymer, Low Molecular Weight
| 25153-40-6 |
|
Chlorohydroquinone, tech., 90%
| 615-67-8 |
|
Tri-n-octylphosphine oxide, 97%
| 78-50-2 |
|
Silver proteinate (mild)
| 9008-42-8 |
|
Lead (IV) Oxide, P.A.
| 1309-60-0 |
|
1,4-Butane Sultone, 99+%
| 1633-83-6 |
|
4-Chloro-3-Iodobenzotrifluoride, 99%
| 672-57-1 |
|
Theophylline, Anhydrous, U.S.P./N.F.
| 58-55-9 |
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P-Anisoyl Chloride, 99%
| 100-07-2 |
|
3-Carboxy-1,4-dimethyl-1h-pyrrole-2-acetic acid
| 33369-45-8 |
|
4-Amino-2,6-dichlorophenol, 98%
| 5930-28-9 |
|
Aminoguanidine Hemisulfate
| 996-19-0 |
|
N-Methylmorpholine hydrochloride, 99+%
| 3651-67-0 |
|
2-Chloro-4,6-dimethoxy-1,3,5-triazine, 98%
| 3140-73-6 |
|
1-Heptyne, 99%
| 628-71-7 |
|
(R)-(+)-2,2'-Bis(diphenylphosphino)- 1,1'-binaphthyl, 99+%
| 76189-55-4 |
|
2-Propene-1-Sulfonic Acid Sodium Salt (Pract)
| 2495-39-8 |
|
6-Amino-1-Hexanol, 94%
| 4048-33-3 |
|
2,5-Dibromonitrobenzene, 97%
| 3460-18-2 |
|
Rubidium Fluoride Hydrate, 99+%
| 16422-67-6 |
|
7-Chloro-2H-1,4-Benzothiazin-3(4H)-One,99%
| 5333-05-1 |
|
2-Methyl-2-Nitropropane, 99%
| 594-70-7 |
|
N-Ethyl-n-butylamine, 99%
| 13360-63-9 |
|
2,6-Dimethylaniline, 99%
| 87-62-7 |
|
2-Chloro-3-Methylquinoline, 97%
| 57876-69-4 |
|
3-Cyanobenzaldehyde, 99%
| 24964-64-5 |
|
N,N'-Diallyltartardiamide, 99+%
| 28843-34-7 |
|
3-Aminobenzonitrile, 99%
| 2237-30-1 |
|
2-Chloropyridine-n-oxide hydrochloride, 97%
| 20295-64-1 |
|
Sodium perchlorate
| 7601-89-0 |
|
Butadiene sulfone, 98%
| 77-79-2 |
|
|