**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 124-63-0 |Methanesulfonyl chloride | 99% | 204-706-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes severe burns.Corrosive.Moisture sensitive.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Treat symptomatically and supportively.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT use water directly on fire. Use carbon dioxide or dry
chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation. Use only in a chemical fume
hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 124-63-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 12.0 mm Hg @ 53C
Viscosity: Not available.
Boiling Point: 161 deg C
Freezing/Melting Point: -33 deg C
Autoignition Temperature: Not available.
Flash Point: 110 deg C ( 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Moisture sensitive
Specific Gravity/Density: 1.4800
Molecular Formula: CH3ClO2S
Molecular Weight: 114.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Water - strong bases - oxidizing agents - alcohols.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 124-63-0: PB2790000
LD50/LC50:
CAS# 124-63-0: Dermal, guinea pig: LD50 = 100 uL/kg; Draize test,
rabbit, eye: 100 mg Severe; Draize test, rabbit, skin: 500 mg
Severe; Oral, mouse: LD50 = 200 mg/kg; Oral, rat: LD50 = 50 mg/kg.
Carcinogenicity:
Methanesulfonyl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Water-Danger/Protection : WGK1
Harmful to fish : LC50, 96hr (Leponis
macrochirus) = 11 mg/l
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: METHANESULPHONYL CHLORIDE
Hazard Class: 6.1 (8)
UN Number: 3246
Packing Group: I
IMO
Shipping Name: METHANESULPHONYL CHLORIDE
Hazard Class: 6.1 (8)
UN Number: 3246
Packing Group: I
RID/ADR
Shipping Name: METHANESULPHONYL CHLORIDE
Hazard Class: 6.1
UN Number: 3246
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 124-63-0: 2
Canada
CAS# 124-63-0 is listed on Canada's DSL List.
CAS# 124-63-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 124-63-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/29/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl isocyanoacetate, tech., 95+%
| 39687-95-1 |
|
2-Methyl-2-thiopseudourea sulfate, 98%
| 867-44-7 |
|
2-Octanol
| 123-96-6 |
|
Methanesulfonyl Chloride, 99.5% (gc)
| 124-63-0 |
|
1-Acetyl-4-(4-hydroxyphenyl)piperazine, 98%
| 67914-60-7 |
|
2-(2-Hydroxyethylamino)-2-(hydroxymethyl)- 1,3-propanediol, 99%
| 7343-51-3 |
|
Salicylsalicylic Acid, 99%(Titr.;Dry Substance)
| 552-94-3 |
|
N-Phenylethylenediamine, 99%
| 1664-40-0 |
|
Phenyltrimethylammonium hydroxide, 0.1M in methanol
| 67-56-1 |
|
9-Hydroxy-4-methoxyacridine, 96%
| 35308-00-0 |
|
2-Amino-1,5-Naphthalenedisulfonic Acid, Tech.
| 117-62-4 |
|
trans-2-Amino-1-cyclohexanecarboxylic acid , 98%
| 5691-19-0 |
|
Trans-2,3,4-Trimethoxycinnamic Acid 99%
| 33130-03-9 |
|
2-Phenylbenzimidazole-5-sulfonic acid, 98%
| 27503-81-7 |
|
1,2,5,6-Diepoxycyclooctane, 96%
| 27035-39-8 |
|
2-Amino-5-Nitrobenzotrifluoride, 98%
| 121-01-7 |
|
Sebacic Acid (Pract), 90% (GC)
| 111-20-6 |
|
Desoxyanisoin, 98%
| 120-44-5 |
|
1-Chloroheptane, 97%
| 629-06-1 |
|
3-Bromofuran, 98%
| 22037-28-1 |
|
2-Bromoethyl Methyl Ether, 95%
| 6482-24-2 |
|
N-Benzyloxycarbonyloxy-Succinimide, 98%
| 13139-17-8 |
|
2-(2-Aminoethylamino)ethanol, 99+%
| 111-41-1 |
|
5-Fluoro-2-Nitrophenol 99 %
| 446-36-6 |
|
Lithium Hydride, 98%
| 7580-67-8 |
|
2-Acetyl-1-naphthol 99%
| 711-79-5 |
|
2,5-Dimethoxytoluene, 99%
| 24599-58-4 |
|
Ergosterol, 98%
| 57-87-4 |
|
Fluorescein, laser grade, 99% (uv-vis)
| 2321-07-5 |
|
Isooctane
| 540-84-1 |
|
5-Nitro-3-indazolinone, 97+%
| 61346-19-8 |
|
Methyl 4-Trifluoromethylbenzoylacetate
| |
|
Succinic Anhydride, 99+%
| 108-30-5 |
|
4'-Ethoxyacetophenone
| 1676-63-7 |
|
2-(p-tolyl)-ethylamine, 97%
| 3261-62-9 |
|
Fusaric acid, 99%
| 536-69-6 |
|
1-(4-Methylphenyl)-1-cyclohexanecarboxylic acid 97%
| 84682-27-9 |
|
Lithium borohydride, 95%
| 16949-15-8 |
|
2-Amino-3-Methylnaphtho(1,2)Imidazole, 99%
| 35199-58-7 |
|
Mechlorethamine hydrochloride, 98%
| 55-86-7 |
|
2,4,5-Trichlorobenzenesulfonyl Hydrazide, 98%
| 6655-72-7 |
|
2',3',4'-Trichloroacetophenone, 95%
| 13608-87-2 |
|
Pyrogallol red
| 32638-88-3 |
|
3-Nitrobiphenyl, 97%
| 2113-58-8 |
|
2,3-Dihydroxynaphthalene, 98%
| 92-44-4 |
|
2,5-Dibromothiophene, 95%
| 3141-27-3 |
|
Hexakis(diethoxyphosphoryl)calix[6]arene, 97%
| |
|
Dl-3-methyl-2-butanol, 98%
| 598-75-4 |
|
Indan, 95%
| 496-11-7 |
|
Tetraphenyllead, 97%
| 595-89-1 |
|
|