**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 16949-15-8 |Lithium borohydride, 95% | 95% | 241-021-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 15 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Causes
burns.Corrosive.Water-reactive.Hygroscopic (absorbs moisture from the
air).
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist.
Ingestion:
Causes gastrointestinal tract burns. Causes cough, sore throat,
chest pain, and lightheadedness.
Inhalation:
Effects may be delayed. May cause irritation of the respiratory
tract with burning pain in the nose and throat, coughing, wheezing,
shortness of breath and pulmonary edema. Causes chemical burns to
the respiratory tract. May cause abdominal pain, nausea, vomiting,
and inflammation of the gums and mouth. May cause lung damage.
Chronic:
May cause liver and kidney damage. May cause anemia and other blood
cell abnormalities. May cause digestive tract and cardiac
disturbances.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts violently with water giving off flammable
gas which may explode.
Extinguishing Media:
Do NOT use halogenated agents. Use approved class D extinguishing
agents or smother with dry sand, clay, or sodium bicarbonate. Do NOT
use water, carbon dioxide, or foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Do not flush into a sewer. Scoop up with a nonsparking
tool, then place into a suitable container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not allow water to get into the container because of violent
reaction. Contents may develop pressure upon prolonged storage. Do
not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin,
or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store
in a tightly closed container. Water free area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 16949-15-8:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear natural rubber gloves, apron, and/or clothing.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist
respirator or European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 280 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: 4.00 vol %
Explosion Limits, upper: 75.60 vol %
Decomposition Temperature: >280 deg C
Solubility in water: 20.9 G/100ML (10C)
Specific Gravity/Density: .6660g/cm3
Molecular Formula: H4BLi
Molecular Weight: 21.77
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to air, contact with water.
Incompatibilities with Other Materials:
Strong oxidizing agents, alcohols, acids, moist air or water,
halogenated hydrocarbons.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of boron, borane.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 16949-15-8: ED2725000
LD50/LC50:
CAS# 16949-15-8: Oral, mouse: LD50 = 87800 ug/kg.
Carcinogenicity:
Lithium borohydride, 95% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: LITHIUM BOROHYDRIDE
Hazard Class: 4.3
UN Number: 1413
Packing Group: I
IMO
Shipping Name: LITHIUM BOROHYDRIDE
Hazard Class: 4.3
UN Number: 1413
Packing Group: I
RID/ADR
Shipping Name: LITHIUM BOROHYDRIDE
Hazard Class: 4.3
UN Number: 1413
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 34 Causes burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 16949-15-8: No information available.
Canada
CAS# 16949-15-8 is listed on Canada's NDSL List.
CAS# 16949-15-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16949-15-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl isocyanoacetate, tech., 95+%
| 39687-95-1 |
|
2-Methyl-2-thiopseudourea sulfate, 98%
| 867-44-7 |
|
2-Octanol
| 123-96-6 |
|
Methanesulfonyl Chloride, 99.5% (gc)
| 124-63-0 |
|
1-Acetyl-4-(4-hydroxyphenyl)piperazine, 98%
| 67914-60-7 |
|
2-(2-Hydroxyethylamino)-2-(hydroxymethyl)- 1,3-propanediol, 99%
| 7343-51-3 |
|
Salicylsalicylic Acid, 99%(Titr.;Dry Substance)
| 552-94-3 |
|
N-Phenylethylenediamine, 99%
| 1664-40-0 |
|
Phenyltrimethylammonium hydroxide, 0.1M in methanol
| 67-56-1 |
|
9-Hydroxy-4-methoxyacridine, 96%
| 35308-00-0 |
|
2-Amino-1,5-Naphthalenedisulfonic Acid, Tech.
| 117-62-4 |
|
trans-2-Amino-1-cyclohexanecarboxylic acid , 98%
| 5691-19-0 |
|
Trans-2,3,4-Trimethoxycinnamic Acid 99%
| 33130-03-9 |
|
2-Phenylbenzimidazole-5-sulfonic acid, 98%
| 27503-81-7 |
|
1,2,5,6-Diepoxycyclooctane, 96%
| 27035-39-8 |
|
2-Amino-5-Nitrobenzotrifluoride, 98%
| 121-01-7 |
|
Sebacic Acid (Pract), 90% (GC)
| 111-20-6 |
|
Desoxyanisoin, 98%
| 120-44-5 |
|
1-Chloroheptane, 97%
| 629-06-1 |
|
3-Bromofuran, 98%
| 22037-28-1 |
|
2-Bromoethyl Methyl Ether, 95%
| 6482-24-2 |
|
N-Benzyloxycarbonyloxy-Succinimide, 98%
| 13139-17-8 |
|
2-(2-Aminoethylamino)ethanol, 99+%
| 111-41-1 |
|
5-Fluoro-2-Nitrophenol 99 %
| 446-36-6 |
|
Lithium Hydride, 98%
| 7580-67-8 |
|
2-Acetyl-1-naphthol 99%
| 711-79-5 |
|
2,5-Dimethoxytoluene, 99%
| 24599-58-4 |
|
Ergosterol, 98%
| 57-87-4 |
|
Fluorescein, laser grade, 99% (uv-vis)
| 2321-07-5 |
|
Isooctane
| 540-84-1 |
|
5-Nitro-3-indazolinone, 97+%
| 61346-19-8 |
|
Methyl 4-Trifluoromethylbenzoylacetate
| |
|
Succinic Anhydride, 99+%
| 108-30-5 |
|
4'-Ethoxyacetophenone
| 1676-63-7 |
|
2-(p-tolyl)-ethylamine, 97%
| 3261-62-9 |
|
Fusaric acid, 99%
| 536-69-6 |
|
1-(4-Methylphenyl)-1-cyclohexanecarboxylic acid 97%
| 84682-27-9 |
|
Lithium borohydride, 95%
| 16949-15-8 |
|
2-Amino-3-Methylnaphtho(1,2)Imidazole, 99%
| 35199-58-7 |
|
Mechlorethamine hydrochloride, 98%
| 55-86-7 |
|
2,4,5-Trichlorobenzenesulfonyl Hydrazide, 98%
| 6655-72-7 |
|
2',3',4'-Trichloroacetophenone, 95%
| 13608-87-2 |
|
Pyrogallol red
| 32638-88-3 |
|
3-Nitrobiphenyl, 97%
| 2113-58-8 |
|
2,3-Dihydroxynaphthalene, 98%
| 92-44-4 |
|
2,5-Dibromothiophene, 95%
| 3141-27-3 |
|
Hexakis(diethoxyphosphoryl)calix[6]arene, 97%
| |
|
Dl-3-methyl-2-butanol, 98%
| 598-75-4 |
|
Indan, 95%
| 496-11-7 |
|
Tetraphenyllead, 97%
| 595-89-1 |
|
|