**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7580-67-8 |Lithium Hydride | 98 | 231-484-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 14/15 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water liberating extremely flammable gases.
Causes severe burns.Corrosive.Light sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. Use water spray to keep fire-exposed containers
cool. Containers may explode in the heat of a fire.
Extinguishing Media:
DO NOT USE WATER! Use only graphite powder, soda ash, powdered
sodium chloride, or an appropriate metal-fire-extinguishing dry
powder. Do NOT get water inside containers. Cool containers with
flooding quantities of water until well after fire is out. For large
fires, use dry sand, dry chemical, soda ash or lime or withdraw from
area and let fire burn.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Use a spark-proof tool. Provide ventilation. Do not get
water on spilled substances or inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Keep container tightly closed. Do not get on skin
or in eyes. Do not ingest or inhale. Use with adequate ventilation.
Store protected from light. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Keep away from water.
Corrosives area. Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7580-67-8:
United Kingdom, WEL - TWA: 0.025 mg/m3 TWA
United Kingdom, WEL - STEL: 0.075 mg/m3 STEL
United States OSHA: 0.025 mg/m3 TWA
Belgium - TWA: 0.025 mg/m3 VLE
France - VME: 0.025 mg/m3 VME
Germany: 0.025 mg/m3 TWA
Malaysia: 0.025 mg/m3 TWA
Netherlands: 0.025 mg/m3 MAC
Spain: 0.025 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear butyl rubber gloves, apron, and/or clothing.
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear butyl rubber gloves, apron, and/or clothing.
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Wear a NIOSH/MSHA
or European Standard EN 149 approved full-facepiece
airline respirator in the positive pressure mode with
emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: off-white to gray
Odor: odorless
pH: Not available.
Vapor Pressure: 0 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 680 deg C
Autoignition Temperature: 200 deg C ( 392.00 deg F)
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Decomposes.
Specific Gravity/Density: .8200g/cm3
Molecular Formula: HLi
Molecular Weight: 7.95
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, moisture, excess heat, strong
oxidants, moist air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen gas, lithium
hydroxide, hydrogen gas, lithium hydride.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7580-67-8: OJ6300000
LD50/LC50:
CAS# 7580-67-8: Oral, rat: LD50 = 77500 ug/kg.
Carcinogenicity:
Lithium Hydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: LITHIUM HYDRIDE
Hazard Class: 4.3
UN Number: 1414
Packing Group: I
IMO
Shipping Name: LITHIUM HYDRIDE
Hazard Class: 4.3
UN Number: 1414
Packing Group: I
RID/ADR
Shipping Name: LITHIUM HYDRIDE
Hazard Class: 4.3
UN Number: 1414
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 14/15 Reacts violently with water liberating
extremely flammable gases.
R 35 Causes severe burns.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7580-67-8: No information available.
Canada
CAS# 7580-67-8 is listed on Canada's NDSL List.
CAS# 7580-67-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7580-67-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/03/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Methyl isocyanoacetate, tech., 95+%
| 39687-95-1 |
|
2-Methyl-2-thiopseudourea sulfate, 98%
| 867-44-7 |
|
2-Octanol
| 123-96-6 |
|
Methanesulfonyl Chloride, 99.5% (gc)
| 124-63-0 |
|
1-Acetyl-4-(4-hydroxyphenyl)piperazine, 98%
| 67914-60-7 |
|
2-(2-Hydroxyethylamino)-2-(hydroxymethyl)- 1,3-propanediol, 99%
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|
Salicylsalicylic Acid, 99%(Titr.;Dry Substance)
| 552-94-3 |
|
N-Phenylethylenediamine, 99%
| 1664-40-0 |
|
Phenyltrimethylammonium hydroxide, 0.1M in methanol
| 67-56-1 |
|
9-Hydroxy-4-methoxyacridine, 96%
| 35308-00-0 |
|
2-Amino-1,5-Naphthalenedisulfonic Acid, Tech.
| 117-62-4 |
|
trans-2-Amino-1-cyclohexanecarboxylic acid , 98%
| 5691-19-0 |
|
Trans-2,3,4-Trimethoxycinnamic Acid 99%
| 33130-03-9 |
|
2-Phenylbenzimidazole-5-sulfonic acid, 98%
| 27503-81-7 |
|
1,2,5,6-Diepoxycyclooctane, 96%
| 27035-39-8 |
|
2-Amino-5-Nitrobenzotrifluoride, 98%
| 121-01-7 |
|
Sebacic Acid (Pract), 90% (GC)
| 111-20-6 |
|
Desoxyanisoin, 98%
| 120-44-5 |
|
1-Chloroheptane, 97%
| 629-06-1 |
|
3-Bromofuran, 98%
| 22037-28-1 |
|
2-Bromoethyl Methyl Ether, 95%
| 6482-24-2 |
|
N-Benzyloxycarbonyloxy-Succinimide, 98%
| 13139-17-8 |
|
2-(2-Aminoethylamino)ethanol, 99+%
| 111-41-1 |
|
5-Fluoro-2-Nitrophenol 99 %
| 446-36-6 |
|
Lithium Hydride, 98%
| 7580-67-8 |
|
2-Acetyl-1-naphthol 99%
| 711-79-5 |
|
2,5-Dimethoxytoluene, 99%
| 24599-58-4 |
|
Ergosterol, 98%
| 57-87-4 |
|
Fluorescein, laser grade, 99% (uv-vis)
| 2321-07-5 |
|
Isooctane
| 540-84-1 |
|
5-Nitro-3-indazolinone, 97+%
| 61346-19-8 |
|
Methyl 4-Trifluoromethylbenzoylacetate
| |
|
Succinic Anhydride, 99+%
| 108-30-5 |
|
4'-Ethoxyacetophenone
| 1676-63-7 |
|
2-(p-tolyl)-ethylamine, 97%
| 3261-62-9 |
|
Fusaric acid, 99%
| 536-69-6 |
|
1-(4-Methylphenyl)-1-cyclohexanecarboxylic acid 97%
| 84682-27-9 |
|
Lithium borohydride, 95%
| 16949-15-8 |
|
2-Amino-3-Methylnaphtho(1,2)Imidazole, 99%
| 35199-58-7 |
|
Mechlorethamine hydrochloride, 98%
| 55-86-7 |
|
2,4,5-Trichlorobenzenesulfonyl Hydrazide, 98%
| 6655-72-7 |
|
2',3',4'-Trichloroacetophenone, 95%
| 13608-87-2 |
|
Pyrogallol red
| 32638-88-3 |
|
3-Nitrobiphenyl, 97%
| 2113-58-8 |
|
2,3-Dihydroxynaphthalene, 98%
| 92-44-4 |
|
2,5-Dibromothiophene, 95%
| 3141-27-3 |
|
Hexakis(diethoxyphosphoryl)calix[6]arene, 97%
| |
|
Dl-3-methyl-2-butanol, 98%
| 598-75-4 |
|
Indan, 95%
| 496-11-7 |
|
Tetraphenyllead, 97%
| 595-89-1 |
|
|