**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 595-89-1 |Tetraphenyllead | 97% | 209-871-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 20/22 33 61 62
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Danger of cumulative
effects. May cause harm to the unborn child. Possible risk of
impaired fertility.Dangerous for the environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause central nervous
system depression. May cause blood abnormalities. Ingestion of lead
compounds can cause toxic effects in the blood-forming organs,
kidneys and central nervous system. Symptoms of lead poisoning or
plumbism include weakness, weight loss, lassitude, insomnia, and
hypotension. It also includes constipation, anorexia, abdominal
discomfort and colic.
Inhalation:
May cause respiratory tract irritation. Inhalation of fumes may
cause metal fume fever, which is characterized by flu-like symptoms
with metallic taste, fever, chills, cough, weakness, chest pain,
muscle pain and increased white blood cell count. May cause effects
similar to those described for ingestion.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Chronic exposure may cause reproductive disorders and teratogenic
effects. Chronic exposure to lead may result in plumbism which is
characterized by lead line in gum, headache, muscle weakness, mental
changes.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further
exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of Dimercaprol or BAL (British Anti-Lewisite) as a chelating
agent should be determined by qualified medical personnel. The use of
d-Penicillamine as a chelating agent should be determined by
qualified medical personnel. The use of Calcium disodium EDTA as a
chelating agent should be determined by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use
extinguishing media appropriate to the surrounding fire. Substance is
noncombustible. Dust can be an explosion hazard when exposed to heat
or flame.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Keep from contact with oxidizing
materials. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 595-89-1:
United Kingdom, WEL - TWA: (listed as lead compounds): 0.15 mg/m3
(as Pb)
United Kingdom, WEL - STEL: (listed as lead compounds): 0.45 mg/m
TWA (as Pb)
France - VME: (listed as lead compounds): 0.1 mg/m3 VME (as Pb)
Germany: (listed as lead compounds): 0.1 mg/m3 VME (as Pb)
Japan: (listed as lead compounds): 0.1 mg/m3 OEL (except alkyl le
compounds, as Pb)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 126 deg C @ 13.00mm Hg
Freezing/Melting Point: 227 - 228 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C24H20Pb
Molecular Weight: 515.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, lead/lead oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 595-89-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetraphenyllead -
California: carcinogen, initial date 10/1/92 (listed as Lead compounds
NTP: Suspect carcinogen (listed as Lead compounds).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
LC50 Japanese quail (Coturnix japonica), males or females, 14 days
old, oral (5-day adlibitum in diet) >5,000 ppm; at 1000, 2236 & 5000
onset of toxic signs began at 7, 7 & 7 days and remissed at 11, 11 &
12 days, respectively, no mortality was observed; control references
were dieldrin & dicrotophos; corn oil diluent was added to diet at
ratio of 2:98 by wt; (extreme concentrations: 1,000-5,000 ppm) /Lead
metal, 100%.
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 61 May cause harm to the unborn child.
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 62 Possible risk of impaired fertility.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 595-89-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 595-89-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 595-89-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl isocyanoacetate, tech., 95+%
| 39687-95-1 |
|
2-Methyl-2-thiopseudourea sulfate, 98%
| 867-44-7 |
|
2-Octanol
| 123-96-6 |
|
Methanesulfonyl Chloride, 99.5% (gc)
| 124-63-0 |
|
1-Acetyl-4-(4-hydroxyphenyl)piperazine, 98%
| 67914-60-7 |
|
2-(2-Hydroxyethylamino)-2-(hydroxymethyl)- 1,3-propanediol, 99%
| 7343-51-3 |
|
Salicylsalicylic Acid, 99%(Titr.;Dry Substance)
| 552-94-3 |
|
N-Phenylethylenediamine, 99%
| 1664-40-0 |
|
Phenyltrimethylammonium hydroxide, 0.1M in methanol
| 67-56-1 |
|
9-Hydroxy-4-methoxyacridine, 96%
| 35308-00-0 |
|
2-Amino-1,5-Naphthalenedisulfonic Acid, Tech.
| 117-62-4 |
|
trans-2-Amino-1-cyclohexanecarboxylic acid , 98%
| 5691-19-0 |
|
Trans-2,3,4-Trimethoxycinnamic Acid 99%
| 33130-03-9 |
|
2-Phenylbenzimidazole-5-sulfonic acid, 98%
| 27503-81-7 |
|
1,2,5,6-Diepoxycyclooctane, 96%
| 27035-39-8 |
|
2-Amino-5-Nitrobenzotrifluoride, 98%
| 121-01-7 |
|
Sebacic Acid (Pract), 90% (GC)
| 111-20-6 |
|
Desoxyanisoin, 98%
| 120-44-5 |
|
1-Chloroheptane, 97%
| 629-06-1 |
|
3-Bromofuran, 98%
| 22037-28-1 |
|
2-Bromoethyl Methyl Ether, 95%
| 6482-24-2 |
|
N-Benzyloxycarbonyloxy-Succinimide, 98%
| 13139-17-8 |
|
2-(2-Aminoethylamino)ethanol, 99+%
| 111-41-1 |
|
5-Fluoro-2-Nitrophenol 99 %
| 446-36-6 |
|
Lithium Hydride, 98%
| 7580-67-8 |
|
2-Acetyl-1-naphthol 99%
| 711-79-5 |
|
2,5-Dimethoxytoluene, 99%
| 24599-58-4 |
|
Ergosterol, 98%
| 57-87-4 |
|
Fluorescein, laser grade, 99% (uv-vis)
| 2321-07-5 |
|
Isooctane
| 540-84-1 |
|
5-Nitro-3-indazolinone, 97+%
| 61346-19-8 |
|
Methyl 4-Trifluoromethylbenzoylacetate
| |
|
Succinic Anhydride, 99+%
| 108-30-5 |
|
4'-Ethoxyacetophenone
| 1676-63-7 |
|
2-(p-tolyl)-ethylamine, 97%
| 3261-62-9 |
|
Fusaric acid, 99%
| 536-69-6 |
|
1-(4-Methylphenyl)-1-cyclohexanecarboxylic acid 97%
| 84682-27-9 |
|
Lithium borohydride, 95%
| 16949-15-8 |
|
2-Amino-3-Methylnaphtho(1,2)Imidazole, 99%
| 35199-58-7 |
|
Mechlorethamine hydrochloride, 98%
| 55-86-7 |
|
2,4,5-Trichlorobenzenesulfonyl Hydrazide, 98%
| 6655-72-7 |
|
2',3',4'-Trichloroacetophenone, 95%
| 13608-87-2 |
|
Pyrogallol red
| 32638-88-3 |
|
3-Nitrobiphenyl, 97%
| 2113-58-8 |
|
2,3-Dihydroxynaphthalene, 98%
| 92-44-4 |
|
2,5-Dibromothiophene, 95%
| 3141-27-3 |
|
Hexakis(diethoxyphosphoryl)calix[6]arene, 97%
| |
|
Dl-3-methyl-2-butanol, 98%
| 598-75-4 |
|
Indan, 95%
| 496-11-7 |
|
Tetraphenyllead, 97%
| 595-89-1 |
|
|