**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 22037-28-1 |3-Bromofuran | 98 | 244-744-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and
skin.Highly flammable.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
Causes skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Containers may explode
in the heat of a fire. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Will be easily ignited by heat, sparks or
flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Keep refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 22037-28-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 103 deg C
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: 3 deg C ( 37.40 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.6350g/cm3
Molecular Formula: C4H3BrO
Molecular Weight: 146.97
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, bromine fumes, bromine.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 22037-28-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Bromofuran -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
WGK (Water Danger/Protection)
CAS# 22037-28-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 22037-28-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 22037-28-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/01/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl isocyanoacetate, tech., 95+%
| 39687-95-1 |
|
2-Methyl-2-thiopseudourea sulfate, 98%
| 867-44-7 |
|
2-Octanol
| 123-96-6 |
|
Methanesulfonyl Chloride, 99.5% (gc)
| 124-63-0 |
|
1-Acetyl-4-(4-hydroxyphenyl)piperazine, 98%
| 67914-60-7 |
|
2-(2-Hydroxyethylamino)-2-(hydroxymethyl)- 1,3-propanediol, 99%
| 7343-51-3 |
|
Salicylsalicylic Acid, 99%(Titr.;Dry Substance)
| 552-94-3 |
|
N-Phenylethylenediamine, 99%
| 1664-40-0 |
|
Phenyltrimethylammonium hydroxide, 0.1M in methanol
| 67-56-1 |
|
9-Hydroxy-4-methoxyacridine, 96%
| 35308-00-0 |
|
2-Amino-1,5-Naphthalenedisulfonic Acid, Tech.
| 117-62-4 |
|
trans-2-Amino-1-cyclohexanecarboxylic acid , 98%
| 5691-19-0 |
|
Trans-2,3,4-Trimethoxycinnamic Acid 99%
| 33130-03-9 |
|
2-Phenylbenzimidazole-5-sulfonic acid, 98%
| 27503-81-7 |
|
1,2,5,6-Diepoxycyclooctane, 96%
| 27035-39-8 |
|
2-Amino-5-Nitrobenzotrifluoride, 98%
| 121-01-7 |
|
Sebacic Acid (Pract), 90% (GC)
| 111-20-6 |
|
Desoxyanisoin, 98%
| 120-44-5 |
|
1-Chloroheptane, 97%
| 629-06-1 |
|
3-Bromofuran, 98%
| 22037-28-1 |
|
2-Bromoethyl Methyl Ether, 95%
| 6482-24-2 |
|
N-Benzyloxycarbonyloxy-Succinimide, 98%
| 13139-17-8 |
|
2-(2-Aminoethylamino)ethanol, 99+%
| 111-41-1 |
|
5-Fluoro-2-Nitrophenol 99 %
| 446-36-6 |
|
Lithium Hydride, 98%
| 7580-67-8 |
|
2-Acetyl-1-naphthol 99%
| 711-79-5 |
|
2,5-Dimethoxytoluene, 99%
| 24599-58-4 |
|
Ergosterol, 98%
| 57-87-4 |
|
Fluorescein, laser grade, 99% (uv-vis)
| 2321-07-5 |
|
Isooctane
| 540-84-1 |
|
5-Nitro-3-indazolinone, 97+%
| 61346-19-8 |
|
Methyl 4-Trifluoromethylbenzoylacetate
| |
|
Succinic Anhydride, 99+%
| 108-30-5 |
|
4'-Ethoxyacetophenone
| 1676-63-7 |
|
2-(p-tolyl)-ethylamine, 97%
| 3261-62-9 |
|
Fusaric acid, 99%
| 536-69-6 |
|
1-(4-Methylphenyl)-1-cyclohexanecarboxylic acid 97%
| 84682-27-9 |
|
Lithium borohydride, 95%
| 16949-15-8 |
|
2-Amino-3-Methylnaphtho(1,2)Imidazole, 99%
| 35199-58-7 |
|
Mechlorethamine hydrochloride, 98%
| 55-86-7 |
|
2,4,5-Trichlorobenzenesulfonyl Hydrazide, 98%
| 6655-72-7 |
|
2',3',4'-Trichloroacetophenone, 95%
| 13608-87-2 |
|
Pyrogallol red
| 32638-88-3 |
|
3-Nitrobiphenyl, 97%
| 2113-58-8 |
|
2,3-Dihydroxynaphthalene, 98%
| 92-44-4 |
|
2,5-Dibromothiophene, 95%
| 3141-27-3 |
|
Hexakis(diethoxyphosphoryl)calix[6]arene, 97%
| |
|
Dl-3-methyl-2-butanol, 98%
| 598-75-4 |
|
Indan, 95%
| 496-11-7 |
|
Tetraphenyllead, 97%
| 595-89-1 |
|
|