**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 129-16-8 |Mercurochrome | 100 | 204-933-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 26/27/28 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation, in contact with skin and if swallowed.
Danger of cumulative effects.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Skin:
May be fatal if absorbed through the skin. May cause irritation and
dermatitis.
Ingestion:
May be fatal if swallowed. May cause central nervous system
depression. May cause excessive salivation and loosening of the
teeth. May cause nausea, vomiting, and diarrhea, possibly with
blood.
Inhalation:
May be fatal if inhaled. May produce general weakness, vomiting,
diarrhea, chest pains, coughing, shortness of breath, and cardiac
insufficiency. Causes irritation of the mucous membrane and upper
respiratory tract.
Chronic:
There is a danger of cumulative effects. Chronic exposure to mercury
compounds may produce immunologic glomerular disease.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Do not flush into a sewer. Avoid generating dusty
conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Do not ingest or
inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Poison room locked. Store in a
cool, dry area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 129-16-8:
United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary
and inorganic compounds).
Belgium - TWA: (listed as mercury, aryl and inorganic compounds):
mg/m3 VLE (as Hg)
France - VME: (listed as mercury, aryl and inorganic compounds):
mg/m3 VME (as Hg)
Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m
VME (as Hg)
Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1
mg/m3 TWA (as Hg)
Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/
VLA-ED (as Hg)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: green
Odor: none reported
pH: 8.8 (0.5% aq. soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: Not available.
Molecular Formula: C20H8Br2HgO6Na2
Molecular Weight: 750.43
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Acids, alkaloid salts, strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 129-16-8: LM5250000
LD50/LC50:
Not available.
Carcinogenicity:
Mercurochrome -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHENYLMERCURIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 2026
Packing Group: II
IMO
Shipping Name: PHENYLMERCURIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 2026
Packing Group: II
RID/ADR
Shipping Name: PHENYLMERCURIC COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 2026
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 129-16-8: No information available.
Canada
CAS# 129-16-8 is listed on Canada's DSL List.
CAS# 129-16-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 129-16-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 1/18/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tridecanenitrile, 98%
| 629-60-7 |
|
Nitrosylsulfuric acid (40% in 87% sulfuric acid), 40%
| 7664-93-9 |
|
Nickel Cyclohexanebutyrate, min. 13.5%Ni
| 3906-55-6 |
|
4-Aminophenyl Sulfone, 97%
| 80-08-0 |
|
5-Fluorosalicylic Acid, 99%
| 345-16-4 |
|
4'-Bromo-3'-Nitroacetophenone, 99+%(TLC)
| 18640-58-9 |
|
1,3,5-Triethylhexahydro-S-Triazine, 97%
| 7779-27-3 |
|
Indole-3-Carbinol Hydrate, 99%
| 123334-15-6 |
|
3,5,5-Trimethylhexanoic acid, 95%(gc)
| 3302-10-1 |
|
3,4-Dimethoxybenzoic Acid, 99+%
| 93-07-2 |
|
2-Ethynylpyridine, 98+%
| 1945-84-2 |
|
Nitromethane
| 75-52-5 |
|
3,7-Dimethyl-2,6-Octadienenitrile, 97%, (Mixture of Isomers)
| 5146-66-7 |
|
Rhodium (III) Chloride, Anhydrous
| 10049-07-7 |
|
Methyl 4-Amino-1-Benzyl-1,2,5,6-Tetrahydropyridine-3-Carboxylate, 99%
| 0-01-1 |
|
Ruthenium on carbon 5% ruthenium, ca. 50% moisture
| |
|
5-Chloro-2-nitrobenzotrifluoride, 99%
| 118-79-6 |
|
4-Iodotoluene, 98%
| 624-31-7 |
|
Sodium Nitroprusside
| 14402-89-2 |
|
1,2,4-Butanetriol, 95%
| 3068-00-6 |
|
Ethyl dichlorophosphite, 98%
| 1498-42-6 |
|
L-(-)-Malic Acid, Disodium Salt Monohydrate, 98%
| 64887-73-6 |
|
Riboflavin 5'-Phosphate Sodium Salt, Dihydrate, 73.0-79.0% (on Dry
| 6184-17-4 |
|
3-Fluorophthalic anhydride, 98%
| 652-39-1 |
|
2,4-Thiazolidinedione, 99%
| 2295-31-0 |
|
Tris-Phosphate, 98%
| 6992-39-8 |
|
Mercurochrome, 24-27% Mercury (corrected for volatiles)
| 129-16-8 |
|
3-Bromophenylhydrazine Hydrochloride, 98%
| 27246-81-7 |
|
1,2-Diiodoethane, 99%
| 624-60-2 |
|
4-Methylbenzhydrol, 98%
| 1517-63-1 |
|
2-Propoxyethanol, 98% (gc)
| 2807-30-9 |
|
3,5-Dimethyl-p-anisic acid, 98%
| 21553-46-8 |
|
n-Methylisatin 3-(thiosemicarbazone), 96%
| 1910-68-5 |
|
Benzeneseleninic anhydride, 98%
| 17697-12-0 |
|
Sodium Sulfide Hydrate, 60-62%, scales
| 27610-45-3 |
|
N-(2-Chloroethyl)benzamide, 99%
| 26385-07-9 |
|
2-Chlorophenyl isothiocyanate, 99%
| 2740-81-0 |
|
4-Indanol, 98%
| 1641-41-4 |
|
1,4-Thioxane, 98%
| 15980-15-1 |
|
Quinine, anhydrous, 99% (titr)
| 130-95-0 |
|
Potassium Phosphate, Dibasic Trihydrate, 99+%
| 16788-57-1 |
|
Benzyl Methyl Sulfide, 98%
| 766-92-7 |
|
5-Nitro-2-furaldehyde, 99%
| 698-63-5 |
|
o-Cresol, 99+% (gc)
| 95-48-7 |
|
(+)-Octopine
| 34522-32-2 |
|
o-Dichlorobenzene
| 95-50-1 |
|
5,7-Dichloro-8-Hydroxyquinoline, 99%
| 773-76-2 |
|
3,3,5,5-Tetramethylcyclohexanol, 96%
| 2650-40-0 |
|
Pentafluoropyridine, 99+%
| 700-16-3 |
|
Perfluoro-1-iodohexane, 99%
| 355-43-1 |
|
|