**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7664-93-9 |Sulfuric acid | 52.2 | 231-639-5 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 7.8 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 7782-78-7 |Nitrosylsulphuric Acid | 40 | 231-964-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: O C
Risk Phrases: 14 35 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes severe burns. Contact with
combustible material may cause fire.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Causes eye burns. When substance becomes wet or comes in contact
with moisture of the mucous membranes, it will cause irritation. May
cause permanent corneal opacification. May cause chemical
conjunctivitis and corneal damage.
Skin:
Causes skin burns. Contact with skin causes irritation and possible
burns, especially if the skin is wet or moist. May cause skin rash
(in milder cases), and cold and clammy skin with cyanosis or pale
color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause burns to the gastrointestinal tract. May cause
systemic effects. May cause nausea, vomiting, and diarrhea, possibly
with blood.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects. May cause acute
pulmonary edema, asphyxia, chemical pneumonitis, and upper airway
obstruction caused by edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
If water-reactive products are embedded in the skin, no water should
be applied. The embedded products should be covered with a light
oil.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Water Reactive.
Material will react with water and may release a flammable and/or
toxic gas. Use water spray to keep fire-exposed containers cool. Use
water with caution and in flooding amounts. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. May ignite or explode on contact with steam or moist
air. Containers may explode when heated.
Extinguishing Media:
Use dry sand or earth to smother fire. Use agent most appropriate to
extinguish fire. DO NOT USE WATER! Contact professional fire-fighters
immediately. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Do not expose spill to
water. Do not use combustible materials such as paper towels to
clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not allow water to get into the container
because of violent reaction. Keep container tightly closed. Avoid
contact with clothing and other combustible materials. Do not get on
skin or in eyes. Do not ingest or inhale. Use with adequate
ventilation. Do not allow contact with water. Discard contaminated
shoes. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Keep away from water. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7664-93-9:
United States OSHA: 1 mg/m3 TWA
Belgium - TWA: 1 mg/m3 VLE
Belgium - STEL: 3 mg/m3 VLE
France - VME: 1 mg/m3 VME
France - VLE: 3 mg/m3 VLE
Germany: 0.5 mg/m3 TWA (inhalable fraction, battery manufacture,
metal working in a close
Japan: 1 mg/m3 Ceiling
Malaysia: 1 mg/m3 TWA
Netherlands: 1 mg/m3 MAC
Russia: 1 mg/m3 TWA
Spain: 1 mg/m3 VLA-ED
Spain: 3 mg/m3 VLA-EC
CAS# 7732-18-5:
CAS# 7782-78-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to
prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: almost colorless
Odor: sulfurous odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: > 100 deg C
Freezing/Melting Point: > 0 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.9000g/cm3
Molecular Formula: HNO5S
Molecular Weight: 127.08
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. Combines vigorously or explosively with water.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation,
combustible materials, reducing agents, strong oxidants, exposure to
moist air or water.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7664-93-9: WS5600000
CAS# 7732-18-5: ZC0110000
CAS# 7782-78-7 unlisted.
LD50/LC50:
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation,
mouse: LC50 = 320 mg/m3/2H; Inhalation, mouse: LC50 = 320 mg/m3;
Inhalation, rat: LC50 = 510 mg/m3/2H; Inhalation, rat: LC50 = 510
mg/m3; Oral, rat: LD50 = 2140 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 7782-78-7.
Carcinogenicity:
Sulfuric acid -
ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg
California: carcinogen, initial date 3/14/03 (listed as Strong inorgan
NTP: Known carcinogen (listed as Strong inorganic acid mists co
IARC: Group 1 carcinogen
Water -
Not listed by ACGIH, IARC, or NTP.
Nitrosylsulphuric Acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
USA RQ: CAS# 7664-93-9: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 14 Reacts violently with water.
R 35 Causes severe burns.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 2 Keep out of reach of children.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 30 Never add water to this product.
WGK (Water Danger/Protection)
CAS# 7664-93-9: 2
CAS# 7732-18-5: No information available.
CAS# 7782-78-7: 2
Canada
CAS# 7664-93-9 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7782-78-7 is listed on Canada's DSL List.
CAS# 7664-93-9 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7782-78-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7782-78-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 35 Causes severe burns.
MSDS Creation Date: 7/29/1999 Revision #3 Date: 11/06/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tridecanenitrile, 98%
| 629-60-7 |
|
Nitrosylsulfuric acid (40% in 87% sulfuric acid), 40%
| 7664-93-9 |
|
Nickel Cyclohexanebutyrate, min. 13.5%Ni
| 3906-55-6 |
|
4-Aminophenyl Sulfone, 97%
| 80-08-0 |
|
5-Fluorosalicylic Acid, 99%
| 345-16-4 |
|
4'-Bromo-3'-Nitroacetophenone, 99+%(TLC)
| 18640-58-9 |
|
1,3,5-Triethylhexahydro-S-Triazine, 97%
| 7779-27-3 |
|
Indole-3-Carbinol Hydrate, 99%
| 123334-15-6 |
|
3,5,5-Trimethylhexanoic acid, 95%(gc)
| 3302-10-1 |
|
3,4-Dimethoxybenzoic Acid, 99+%
| 93-07-2 |
|
2-Ethynylpyridine, 98+%
| 1945-84-2 |
|
Nitromethane
| 75-52-5 |
|
3,7-Dimethyl-2,6-Octadienenitrile, 97%, (Mixture of Isomers)
| 5146-66-7 |
|
Rhodium (III) Chloride, Anhydrous
| 10049-07-7 |
|
Methyl 4-Amino-1-Benzyl-1,2,5,6-Tetrahydropyridine-3-Carboxylate, 99%
| 0-01-1 |
|
Ruthenium on carbon 5% ruthenium, ca. 50% moisture
| |
|
5-Chloro-2-nitrobenzotrifluoride, 99%
| 118-79-6 |
|
4-Iodotoluene, 98%
| 624-31-7 |
|
Sodium Nitroprusside
| 14402-89-2 |
|
1,2,4-Butanetriol, 95%
| 3068-00-6 |
|
Ethyl dichlorophosphite, 98%
| 1498-42-6 |
|
L-(-)-Malic Acid, Disodium Salt Monohydrate, 98%
| 64887-73-6 |
|
Riboflavin 5'-Phosphate Sodium Salt, Dihydrate, 73.0-79.0% (on Dry
| 6184-17-4 |
|
3-Fluorophthalic anhydride, 98%
| 652-39-1 |
|
2,4-Thiazolidinedione, 99%
| 2295-31-0 |
|
Tris-Phosphate, 98%
| 6992-39-8 |
|
Mercurochrome, 24-27% Mercury (corrected for volatiles)
| 129-16-8 |
|
3-Bromophenylhydrazine Hydrochloride, 98%
| 27246-81-7 |
|
1,2-Diiodoethane, 99%
| 624-60-2 |
|
4-Methylbenzhydrol, 98%
| 1517-63-1 |
|
2-Propoxyethanol, 98% (gc)
| 2807-30-9 |
|
3,5-Dimethyl-p-anisic acid, 98%
| 21553-46-8 |
|
n-Methylisatin 3-(thiosemicarbazone), 96%
| 1910-68-5 |
|
Benzeneseleninic anhydride, 98%
| 17697-12-0 |
|
Sodium Sulfide Hydrate, 60-62%, scales
| 27610-45-3 |
|
N-(2-Chloroethyl)benzamide, 99%
| 26385-07-9 |
|
2-Chlorophenyl isothiocyanate, 99%
| 2740-81-0 |
|
4-Indanol, 98%
| 1641-41-4 |
|
1,4-Thioxane, 98%
| 15980-15-1 |
|
Quinine, anhydrous, 99% (titr)
| 130-95-0 |
|
Potassium Phosphate, Dibasic Trihydrate, 99+%
| 16788-57-1 |
|
Benzyl Methyl Sulfide, 98%
| 766-92-7 |
|
5-Nitro-2-furaldehyde, 99%
| 698-63-5 |
|
o-Cresol, 99+% (gc)
| 95-48-7 |
|
(+)-Octopine
| 34522-32-2 |
|
o-Dichlorobenzene
| 95-50-1 |
|
5,7-Dichloro-8-Hydroxyquinoline, 99%
| 773-76-2 |
|
3,3,5,5-Tetramethylcyclohexanol, 96%
| 2650-40-0 |
|
Pentafluoropyridine, 99+%
| 700-16-3 |
|
Perfluoro-1-iodohexane, 99%
| 355-43-1 |
|
|