**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 27610-45-3 |Sodium sulfide hydrate | 60-62 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 31 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with acids liberates toxic gas. Causes burns.Hygroscopic
(absorbs moisture from the air).Air sensitive.Light
sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage. Direct contact with liquid may cause blindness or permanent
eye damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
Place under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Minimize dust
generation and accumulation. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Do not ingest or inhale. Store protected from light.
Handle under an inert atmosphere. Store protected from air. Use only
in a chemical fume hood. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from acids. Do not expose to air. Store protected from moisture.
Store protected from light. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 27610-45-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Flakes
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: Na2S.xH2O
Molecular Weight: 78.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Contact with acid
liberates gas.
Conditions to Avoid:
Incompatible materials, light, dust generation, exposure to air,
excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, air, acids, oxidizing agents, aluminum, zinc, zinc alloys,
aluminum alloys.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, hydrogen
sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 27610-45-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Sodium sulfide hydrate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: SODIUM SULPHIDE, HYDRATED
Hazard Class: 8
UN Number: 1849
Packing Group: II
IMO
Shipping Name: SODIUM SULPHIDE, HYDRATED
Hazard Class: 8
UN Number: 1849
Packing Group: II
RID/ADR
Shipping Name: SODIUM SULPHIDE, HYDRATED
Hazard Class: 8
UN Number: 1849
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 31 Contact with acids liberates toxic gas.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 27610-45-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 27610-45-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 27610-45-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Tridecanenitrile, 98%
| 629-60-7 |
|
Nitrosylsulfuric acid (40% in 87% sulfuric acid), 40%
| 7664-93-9 |
|
Nickel Cyclohexanebutyrate, min. 13.5%Ni
| 3906-55-6 |
|
4-Aminophenyl Sulfone, 97%
| 80-08-0 |
|
5-Fluorosalicylic Acid, 99%
| 345-16-4 |
|
4'-Bromo-3'-Nitroacetophenone, 99+%(TLC)
| 18640-58-9 |
|
1,3,5-Triethylhexahydro-S-Triazine, 97%
| 7779-27-3 |
|
Indole-3-Carbinol Hydrate, 99%
| 123334-15-6 |
|
3,5,5-Trimethylhexanoic acid, 95%(gc)
| 3302-10-1 |
|
3,4-Dimethoxybenzoic Acid, 99+%
| 93-07-2 |
|
2-Ethynylpyridine, 98+%
| 1945-84-2 |
|
Nitromethane
| 75-52-5 |
|
3,7-Dimethyl-2,6-Octadienenitrile, 97%, (Mixture of Isomers)
| 5146-66-7 |
|
Rhodium (III) Chloride, Anhydrous
| 10049-07-7 |
|
Methyl 4-Amino-1-Benzyl-1,2,5,6-Tetrahydropyridine-3-Carboxylate, 99%
| 0-01-1 |
|
Ruthenium on carbon 5% ruthenium, ca. 50% moisture
| |
|
5-Chloro-2-nitrobenzotrifluoride, 99%
| 118-79-6 |
|
4-Iodotoluene, 98%
| 624-31-7 |
|
Sodium Nitroprusside
| 14402-89-2 |
|
1,2,4-Butanetriol, 95%
| 3068-00-6 |
|
Ethyl dichlorophosphite, 98%
| 1498-42-6 |
|
L-(-)-Malic Acid, Disodium Salt Monohydrate, 98%
| 64887-73-6 |
|
Riboflavin 5'-Phosphate Sodium Salt, Dihydrate, 73.0-79.0% (on Dry
| 6184-17-4 |
|
3-Fluorophthalic anhydride, 98%
| 652-39-1 |
|
2,4-Thiazolidinedione, 99%
| 2295-31-0 |
|
Tris-Phosphate, 98%
| 6992-39-8 |
|
Mercurochrome, 24-27% Mercury (corrected for volatiles)
| 129-16-8 |
|
3-Bromophenylhydrazine Hydrochloride, 98%
| 27246-81-7 |
|
1,2-Diiodoethane, 99%
| 624-60-2 |
|
4-Methylbenzhydrol, 98%
| 1517-63-1 |
|
2-Propoxyethanol, 98% (gc)
| 2807-30-9 |
|
3,5-Dimethyl-p-anisic acid, 98%
| 21553-46-8 |
|
n-Methylisatin 3-(thiosemicarbazone), 96%
| 1910-68-5 |
|
Benzeneseleninic anhydride, 98%
| 17697-12-0 |
|
Sodium Sulfide Hydrate, 60-62%, scales
| 27610-45-3 |
|
N-(2-Chloroethyl)benzamide, 99%
| 26385-07-9 |
|
2-Chlorophenyl isothiocyanate, 99%
| 2740-81-0 |
|
4-Indanol, 98%
| 1641-41-4 |
|
1,4-Thioxane, 98%
| 15980-15-1 |
|
Quinine, anhydrous, 99% (titr)
| 130-95-0 |
|
Potassium Phosphate, Dibasic Trihydrate, 99+%
| 16788-57-1 |
|
Benzyl Methyl Sulfide, 98%
| 766-92-7 |
|
5-Nitro-2-furaldehyde, 99%
| 698-63-5 |
|
o-Cresol, 99+% (gc)
| 95-48-7 |
|
(+)-Octopine
| 34522-32-2 |
|
o-Dichlorobenzene
| 95-50-1 |
|
5,7-Dichloro-8-Hydroxyquinoline, 99%
| 773-76-2 |
|
3,3,5,5-Tetramethylcyclohexanol, 96%
| 2650-40-0 |
|
Pentafluoropyridine, 99+%
| 700-16-3 |
|
Perfluoro-1-iodohexane, 99%
| 355-43-1 |
|
|