**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1314-13-2 |Zinc oxide | >99 | 215-222-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: N
Risk Phrases: 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
Prolonged and/or repeated contact may cause irritation and/or
dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Moderately toxic to humans by ingestion. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
Effects may be delayed. May cause respiratory tract irritation.
Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white
blood cell count. The toxicological properties of this substance have
not been fully investigated. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material will not burn.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Use with adequate
ventilation. Wash clothing before reuse. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 1314-13-2:
United States OSHA: 5 mg/m3 TWA (fume); 15 mg/m3 TWA (total dust)
mg/m3 TWA (respirable fraction)
Belgium - TWA: 10 mg/m3 VLE (dust); 5 mg/m3 VLE (fumes)
Belgium - STEL: 10 mg/m3 VLE (fumes)
France - VME: 5 mg/m3 VME (fume); 10 mg/m3 VME (dust)
Germany: 5 mg/m3 TWA (respirable fraction, smoke)
Japan: 1 mg/m3 OEL (respirable dust); 4 mg/m3 OEL (total dust)
Malaysia: 5 mg/m3 TWA (fume); 10 mg/m3 TWA (dust)
Netherlands: 5 mg/m3 MAC (smoke)
Spain: 5 mg/m3 VLA-ED (vapor); 10 mg/m3 VLA-ED (dust)
Spain: 10 mg/m3 VLA-EC (fume)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white or yellow-white
Odor: odorless
pH: Not applicable.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 1975 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Sublimes.
Solubility in water: Negligible in water
Specific Gravity/Density: 5.6
Molecular Formula: ZnO
Molecular Weight: 81.37
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Magnesium, chlorinated rubber.
Hazardous Decomposition Products:
Toxic fumes of zinc oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1314-13-2: ZH4810000 ZH4817000
LD50/LC50:
CAS# 1314-13-2: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 2500
mg/m3; Oral, mouse: LD50 = 7950 mg/kg.
Carcinogenicity:
Zinc oxide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: N
Risk Phrases:
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1314-13-2: 0
Canada
CAS# 1314-13-2 is listed on Canada's DSL List.
CAS# 1314-13-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1314-13-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #8 Date: 11/18/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Myristic acid, 99.5+%
| 544-63-8 |
|
Chlorodimethylphenylsilane 95%
| 768-33-2 |
|
2-Amino-5-Methyl-1,3,4-Thiadiazole, 97%
| 108-33-8 |
|
Acetic-d3 acid, sodium salt, 99+ atom % d
| 39230-37-0 |
|
3-Benzoylpyridine, 97%
| 5424-19-1 |
|
p-Propylbenzaldehyde diethyl acetal, 99%
| 89557-35-7 |
|
5-(Trifluoromethyl)-4h-1,2,4-triazole-- 3(2h)-thione hemihydrate, 97%
| 68744-64-1 |
|
4-Dimethylamino-2-Methylazobenzene, 98% (Titr.)
| 54-88-6 |
|
Gallium, 99.9999%
| 7440-55-3 |
|
Hexanoic acid
| 142-62-1 |
|
2,4-Dichloro-alpha-methylbenzyl alcohol
| 1475-13-4 |
|
P-Methylanisole, 96% (GC)
| 104-93-8 |
|
D,l-isoproterenol sulfate dihydrate, 97%
| 6078-56-4 |
|
3,4-Lutidine, 98%
| 583-58-4 |
|
1-(3-Chloropropoxy)-4-fluorobenzene, mixture of chloro- and
| 1716-42-3 |
|
Zinc Nitrate Hexahydrate
| 10196-18-6 |
|
Zinc oxide
| 1314-13-2 |
|
4-Bromothioanisole, 97%
| 104-95-0 |
|
1,2-Bis-(4-Pyridyl)-Ethane, 97%
| 4916-57-8 |
|
4-Nitrophenyl Sulfate, Potassium Salt Monohydrate, 99+%
| 6217-68-1 |
|
Chicago sky blue 6B
| 2610-05-1 |
|
1H-Benzimidazole-5-carboxylic acid, 98%
| 15788-16-6 |
|
Zinc sulfate heptahydrate
| 7446-20-0 |
|
Cellulose Acetate Butyrate, Average M.W. 16000
| 9004-36-8 |
|
Bromoacetaldehyde Diethyl Acetal, 99% (GC)
| 2032-35-1 |
|
2-Methoxyfuran, 97%
| 25414-22-6 |
|
4-Methoxy-1-naphthol, 98+%
| 84-85-5 |
|
4-Methylpyrimidine, 97%
| 3438-46-8 |
|
Mixture of Silicon(IV)Chloride (57.5%) and Chlorotrimethylsilane
| 75-77-4 |
|
5-(4-Methylphenyl)-5-Phenylhydantoin, 99+%
| 51169-17-6 |
|
4-Fluoro-3-nitrobenzotrifluoride, 96%
| 367-86-2 |
|
2,6-Difluoroaniline, 97%
| 5509-65-9 |
|
4-(Diethylamino)butanenitrile, 97%
| 5336-75-4 |
|
Ethylene Sulfide, 98+%, stabilized with 0.5% Butylmercaptane
| |
|
Cycloheptene, 97%
| 628-92-2 |
|
Tricosanoic Acid, 99%
| 2433-96-7 |
|
2-Amino-P-Cresol, 97%
| 95-84-1 |
|
Isopulegyl acetate, 98%, mixture of isomers
| 89-49-6 |
|
Dimethyl Cis-1,2-Cyclopropanedicarboxylate 98%
| 826-34-6 |
|
Phenolphthalein Complexon
| 62698-58-2 |
|
4-Cyano-9-Fluorenone, 99.5+%
| 0-00-1 |
|
Borane-Triethylamine Complex
| 1722-26-5 |
|
2,6-Dithiopurine 98%
| 5437-25-2 |
|
p-Benzyloxyphenol, 98%
| 103-16-2 |
|
1-Bromonaphthalene
| 90-11-9 |
|
Ethyl 4-Chlorobutyrate, 97+%(GC)
| 3153-36-4 |
|
Hexatriacontane, 98%
| 630-06-8 |
|
Erbium Oxide, 99.99+%
| 12061-16-4 |
|
1,1'-Diethyl-2,2'-Dicarbocyanine Iodide, 99% (UV-Vis)
| 14187-31-6 |
|
2-Nitrobenzyl chloride, 98%
| 612-23-7 |
|
|