**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 612-23-7 |2-Nitrobenzyl chloride | 98 | 210-300-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Lachrymator (substance which increases the flow of tears). Causes
severe eye irritation and possible burns.
Skin:
Causes severe skin irritation and possible burns.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea, and vomiting. Causes severe
respiratory tract irritation with possible burns.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Gently lift eyelids and flush continuously with water.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
hydrolyzes material liberating acidic gas which in contact with metal
surfaces can generate flammable and/or explosive hydrogen gas.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid generating dusty conditions. Cover with sand, dry lime or soda
ash and place in a closed container for disposal. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest
or inhale. Use with adequate ventilation. Use only in a chemical fume
hood. Discard contaminated shoes. Do not breathe dust.
Storage:
Keep containers tightly closed. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 612-23-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 127.0 - 133.0 deg C @ 10.00mm
Freezing/Melting Point: 46.00 - 48.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 109 deg C (> 228.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: Not available.
Molecular Formula: C7H6ClNO2
Molecular Weight: 171.58
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable, however, may violently decompose at temperatures above
125C.
Conditions to Avoid:
Incompatible materials, metals, oxidizers, amines, bases,
temperatures above 125C.
Incompatibilities with Other Materials:
Bases, alcohols, amines, steel, oxidizing agents (strong, e.g.
bromine, hydrogen peroxide, nitrogen dioxide, potassium nitrate),
moisture.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
chloride fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 612-23-7: XS9092000
LD50/LC50:
Not available.
Carcinogenicity:
2-Nitrobenzyl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 612-23-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 612-23-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 612-23-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/10/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Myristic acid, 99.5+%
| 544-63-8 |
|
Chlorodimethylphenylsilane 95%
| 768-33-2 |
|
2-Amino-5-Methyl-1,3,4-Thiadiazole, 97%
| 108-33-8 |
|
Acetic-d3 acid, sodium salt, 99+ atom % d
| 39230-37-0 |
|
3-Benzoylpyridine, 97%
| 5424-19-1 |
|
p-Propylbenzaldehyde diethyl acetal, 99%
| 89557-35-7 |
|
5-(Trifluoromethyl)-4h-1,2,4-triazole-- 3(2h)-thione hemihydrate, 97%
| 68744-64-1 |
|
4-Dimethylamino-2-Methylazobenzene, 98% (Titr.)
| 54-88-6 |
|
Gallium, 99.9999%
| 7440-55-3 |
|
Hexanoic acid
| 142-62-1 |
|
2,4-Dichloro-alpha-methylbenzyl alcohol
| 1475-13-4 |
|
P-Methylanisole, 96% (GC)
| 104-93-8 |
|
D,l-isoproterenol sulfate dihydrate, 97%
| 6078-56-4 |
|
3,4-Lutidine, 98%
| 583-58-4 |
|
1-(3-Chloropropoxy)-4-fluorobenzene, mixture of chloro- and
| 1716-42-3 |
|
Zinc Nitrate Hexahydrate
| 10196-18-6 |
|
Zinc oxide
| 1314-13-2 |
|
4-Bromothioanisole, 97%
| 104-95-0 |
|
1,2-Bis-(4-Pyridyl)-Ethane, 97%
| 4916-57-8 |
|
4-Nitrophenyl Sulfate, Potassium Salt Monohydrate, 99+%
| 6217-68-1 |
|
Chicago sky blue 6B
| 2610-05-1 |
|
1H-Benzimidazole-5-carboxylic acid, 98%
| 15788-16-6 |
|
Zinc sulfate heptahydrate
| 7446-20-0 |
|
Cellulose Acetate Butyrate, Average M.W. 16000
| 9004-36-8 |
|
Bromoacetaldehyde Diethyl Acetal, 99% (GC)
| 2032-35-1 |
|
2-Methoxyfuran, 97%
| 25414-22-6 |
|
4-Methoxy-1-naphthol, 98+%
| 84-85-5 |
|
4-Methylpyrimidine, 97%
| 3438-46-8 |
|
Mixture of Silicon(IV)Chloride (57.5%) and Chlorotrimethylsilane
| 75-77-4 |
|
5-(4-Methylphenyl)-5-Phenylhydantoin, 99+%
| 51169-17-6 |
|
4-Fluoro-3-nitrobenzotrifluoride, 96%
| 367-86-2 |
|
2,6-Difluoroaniline, 97%
| 5509-65-9 |
|
4-(Diethylamino)butanenitrile, 97%
| 5336-75-4 |
|
Ethylene Sulfide, 98+%, stabilized with 0.5% Butylmercaptane
| |
|
Cycloheptene, 97%
| 628-92-2 |
|
Tricosanoic Acid, 99%
| 2433-96-7 |
|
2-Amino-P-Cresol, 97%
| 95-84-1 |
|
Isopulegyl acetate, 98%, mixture of isomers
| 89-49-6 |
|
Dimethyl Cis-1,2-Cyclopropanedicarboxylate 98%
| 826-34-6 |
|
Phenolphthalein Complexon
| 62698-58-2 |
|
4-Cyano-9-Fluorenone, 99.5+%
| 0-00-1 |
|
Borane-Triethylamine Complex
| 1722-26-5 |
|
2,6-Dithiopurine 98%
| 5437-25-2 |
|
p-Benzyloxyphenol, 98%
| 103-16-2 |
|
1-Bromonaphthalene
| 90-11-9 |
|
Ethyl 4-Chlorobutyrate, 97+%(GC)
| 3153-36-4 |
|
Hexatriacontane, 98%
| 630-06-8 |
|
Erbium Oxide, 99.99+%
| 12061-16-4 |
|
1,1'-Diethyl-2,2'-Dicarbocyanine Iodide, 99% (UV-Vis)
| 14187-31-6 |
|
2-Nitrobenzyl chloride, 98%
| 612-23-7 |
|
|