**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7446-20-0 |Zinc sulfate, heptahydrate | 99 | unlisted |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN N
Risk Phrases: 22 41 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Risk of serious damage to eyes. Very toxic to
aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Potential Health Effects
Eye:
Contact may cause severe eye irritation and possible eye damage.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Dust is irritating to the respiratory tract. May be harmful if
inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation.
This material is a water pollutant and should not be emptied into
drains.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7446-20-0:
CAS# 7733-02-0:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white
Odor: odorless
pH: 4.4-6 (5% aq soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 100 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 500 deg C
Solubility in water: Soluble in water
Specific Gravity/Density: 3.54 g/cm3 @ 25C
Molecular Formula: ZnSO4.7H2O
Molecular Weight: 287.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Efflorescent
(tending to lose water molecules of hydration) in dry air.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong bases.
Hazardous Decomposition Products:
Oxides of sulfur, toxic fumes of zinc oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7446-20-0: ZH5300000
CAS# 7733-02-0: ZH5260000
LD50/LC50:
CAS# 7446-20-0: Oral, mouse: LD50 = 200 mg/kg; Oral, rat: LD50 =
1260 mg/kg.
CAS# 7733-02-0: Draize test, rabbit, eye: 420 ug Moderate; Oral,
mouse: LD50 = 245 mg/kg; Oral, rabbit: LD50 = 2 gm/kg.
Carcinogenicity:
Zinc sulfate, heptahydrate -
Not listed by ACGIH, IARC, or NTP.
Zinc sulfate anhydrous -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7733-02-0: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 41 Risk of serious damage to eyes.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 39 Wear eye/face protection.
S 46 If swallowed, seek medical advice immediately
and show this container or label.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7446-20-0: 1
CAS# 7733-02-0: 1
Canada
CAS# 7446-20-0 is listed on Canada's DSL List.
CAS# 7733-02-0 is listed on Canada's DSL List.
CAS# 7446-20-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 7733-02-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7446-20-0 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 7733-02-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 12/12/1997 Revision #5 Date: 1/18/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Myristic acid, 99.5+%
| 544-63-8 |
|
Chlorodimethylphenylsilane 95%
| 768-33-2 |
|
2-Amino-5-Methyl-1,3,4-Thiadiazole, 97%
| 108-33-8 |
|
Acetic-d3 acid, sodium salt, 99+ atom % d
| 39230-37-0 |
|
3-Benzoylpyridine, 97%
| 5424-19-1 |
|
p-Propylbenzaldehyde diethyl acetal, 99%
| 89557-35-7 |
|
5-(Trifluoromethyl)-4h-1,2,4-triazole-- 3(2h)-thione hemihydrate, 97%
| 68744-64-1 |
|
4-Dimethylamino-2-Methylazobenzene, 98% (Titr.)
| 54-88-6 |
|
Gallium, 99.9999%
| 7440-55-3 |
|
Hexanoic acid
| 142-62-1 |
|
2,4-Dichloro-alpha-methylbenzyl alcohol
| 1475-13-4 |
|
P-Methylanisole, 96% (GC)
| 104-93-8 |
|
D,l-isoproterenol sulfate dihydrate, 97%
| 6078-56-4 |
|
3,4-Lutidine, 98%
| 583-58-4 |
|
1-(3-Chloropropoxy)-4-fluorobenzene, mixture of chloro- and
| 1716-42-3 |
|
Zinc Nitrate Hexahydrate
| 10196-18-6 |
|
Zinc oxide
| 1314-13-2 |
|
4-Bromothioanisole, 97%
| 104-95-0 |
|
1,2-Bis-(4-Pyridyl)-Ethane, 97%
| 4916-57-8 |
|
4-Nitrophenyl Sulfate, Potassium Salt Monohydrate, 99+%
| 6217-68-1 |
|
Chicago sky blue 6B
| 2610-05-1 |
|
1H-Benzimidazole-5-carboxylic acid, 98%
| 15788-16-6 |
|
Zinc sulfate heptahydrate
| 7446-20-0 |
|
Cellulose Acetate Butyrate, Average M.W. 16000
| 9004-36-8 |
|
Bromoacetaldehyde Diethyl Acetal, 99% (GC)
| 2032-35-1 |
|
2-Methoxyfuran, 97%
| 25414-22-6 |
|
4-Methoxy-1-naphthol, 98+%
| 84-85-5 |
|
4-Methylpyrimidine, 97%
| 3438-46-8 |
|
Mixture of Silicon(IV)Chloride (57.5%) and Chlorotrimethylsilane
| 75-77-4 |
|
5-(4-Methylphenyl)-5-Phenylhydantoin, 99+%
| 51169-17-6 |
|
4-Fluoro-3-nitrobenzotrifluoride, 96%
| 367-86-2 |
|
2,6-Difluoroaniline, 97%
| 5509-65-9 |
|
4-(Diethylamino)butanenitrile, 97%
| 5336-75-4 |
|
Ethylene Sulfide, 98+%, stabilized with 0.5% Butylmercaptane
| |
|
Cycloheptene, 97%
| 628-92-2 |
|
Tricosanoic Acid, 99%
| 2433-96-7 |
|
2-Amino-P-Cresol, 97%
| 95-84-1 |
|
Isopulegyl acetate, 98%, mixture of isomers
| 89-49-6 |
|
Dimethyl Cis-1,2-Cyclopropanedicarboxylate 98%
| 826-34-6 |
|
Phenolphthalein Complexon
| 62698-58-2 |
|
4-Cyano-9-Fluorenone, 99.5+%
| 0-00-1 |
|
Borane-Triethylamine Complex
| 1722-26-5 |
|
2,6-Dithiopurine 98%
| 5437-25-2 |
|
p-Benzyloxyphenol, 98%
| 103-16-2 |
|
1-Bromonaphthalene
| 90-11-9 |
|
Ethyl 4-Chlorobutyrate, 97+%(GC)
| 3153-36-4 |
|
Hexatriacontane, 98%
| 630-06-8 |
|
Erbium Oxide, 99.99+%
| 12061-16-4 |
|
1,1'-Diethyl-2,2'-Dicarbocyanine Iodide, 99% (UV-Vis)
| 14187-31-6 |
|
2-Nitrobenzyl chloride, 98%
| 612-23-7 |
|
|