**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13292-87-0 |Borane-methyl sulfide complex | >98 % | 236-313-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 15 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Contact with water liberates extremely flammable
gases. Irritating to eyes, respiratory system and
skin.Water-reactive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver damage. May cause headache.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts violently with water giving off flammable
gas which may explode. Will burn if involved in a fire.
Extinguishing Media:
Use dry chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Remove all sources of ignition. Use a
spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Do not allow water to get into the container because of
violent reaction. Avoid breathing dust, vapor, mist, or gas. Avoid
contact with eyes, skin, and clothing. Keep away from heat, sparks
and flame. Avoid ingestion and inhalation. Use only in a chemical
fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 13292-87-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: Stench.
pH: Not available.
Vapor Pressure: 54.75 mm Hg @ 4
Viscosity: Not available.
Boiling Point: 44 deg C @ 760.00mm Hg
Freezing/Melting Point: -27 deg C
Autoignition Temperature: Not available.
Flash Point: 18 deg C ( 64.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .7900g/cm3
Molecular Formula: C2H9BS
Molecular Weight: 75.95
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, contact with water, excess heat.
Incompatibilities with Other Materials:
Acids; acid chlorides; acid anhydrides; oxidizing agents; alcohols;
and water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide,
oxides of boron, borane.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13292-87-0: PV5080000
LD50/LC50:
CAS# 13292-87-0: Draize test, rabbit, eye: 100 mg Severe.
Carcinogenicity:
Borane-methyl sulfide complex -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE
, N.O.S.*
Hazard Class: 4.3 (3)
UN Number: 3207
Packing Group: III
IMO
Shipping Name: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE
, N.O.S.
Hazard Class: 4.3 (3)
UN Number: 3207
Packing Group: III
RID/ADR
Shipping Name: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE
, N.O.S.
Hazard Class: 4.3
UN Number: 3207
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 15 Contact with water liberates extremely
flammable gases.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 13292-87-0: No information available.
Canada
CAS# 13292-87-0 is listed on Canada's NDSL List.
CAS# 13292-87-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13292-87-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
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Myricetin, 95%
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3,3-Diphenylpropylamine, 98%
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2,4,5-Trimethoxycinnamic Acid, 98+% Trans
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cis-1,2,3,6-Tetrahydrophthalic anhydride, 98%
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|
2,4,6-Triaminopyrimidine, 97%
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|
4-Acetylpiperidine Hydrochloride, 98%
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3-Chloro-Benzophenone, 99+%
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|
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| 107-40-4 |
|
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| 104-67-6 |
|
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| 78291-99-3 |
|
3,4-Dichlorobenzylamine, 98%
| 102-49-8 |
|
Trifluoroacetic acid 2,2,2-trifluoroethyl ester, 99+%
| 407-38-5 |
|
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| 67-51-6 |
|
5-Chloroindole, 99%
| 17422-32-1 |
|
3,4-Dibromothiophene, 97%
| 3141-26-2 |
|
4,5,6-Triaminopyrimidine Sulfate Hydrate, 97%
| 6640-23-9 |
|
(S,S)-(+)-2,5-Bis(Methoxymethyl)Pyrrolidine, 96%
| 93621-94-4 |
|
DL-Camphor, 98%
| 76-22-2 |
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3-Bromobenzyl alcohol, 99%
| 15852-73-0 |
|
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| 123-91-1 |
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Phosphorus Pentachloride, Reagent (Crystals)
| 10026-13-8 |
|
Beryllium fluoride, 98.5+%
| 7787-49-7 |
|
Cholesteryl Oleyl Carbonate, 99+%(TLC)
| 17110-51-9 |
|
Phenylacetone, 99+%
| 103-79-7 |
|
2-Amino-9-Fluorenone
| 3096-57-9 |
|
3,3-Tetramethyleneglutaric Acid, 99%
| 16713-66-9 |
|
Dimethyl Suberimidate Dihydrochloride, 99%
| 34490-86-3 |
|
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| 700-84-5 |
|
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| 95111-49-2 |
|
3'-Bromoacetophenone, 97%
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|
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