**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3279-26-3 |Methyl Dichlorophosphite | 98% | 221-915-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and
skin.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation and possible burns. May cause cyanosis of the
extremities. May cause skin rash (in milder cases), and cold and
clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. Ingestion of large amounts may cause CNS depression. May
cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. Vapors may cause dizziness or suffocation. May
cause systemic effects. Inhalation at high concentrations may cause
CNS depression and asphixiation. May cause burning sensation in the
chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. Contact with metals may evolve
flammable hydrogen gas. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not ingest
or inhale. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 3279-26-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 93 deg C @ 760.00mmHg
Freezing/Melting Point: -91 deg C
Autoignition Temperature: Not available.
Flash Point: 43 deg C ( 109.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4060g/cm3
Molecular Formula: CH3Cl2OP
Molecular Weight: 132.91
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of phosphorus, irritating
and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3279-26-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Methyl Dichlorophosphite -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 3279-26-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3279-26-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3279-26-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Platinum on calcium carbonate (5% pt)
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Myricetin, 95%
| 529-44-2 |
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3,3-Diphenylpropylamine, 98%
| 5586-73-2 |
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2,4,5-Trimethoxycinnamic Acid, 98+% Trans
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|
Bacitracin, zinc salt, potency min. 60 units/mg (on the dry
| 1405-89-6 |
|
Pyrithyldione 98%
| 77-04-3 |
|
cis-1,2,3,6-Tetrahydrophthalic anhydride, 98%
| 935-79-5 |
|
2,4,6-Triaminopyrimidine, 97%
| 1004-38-2 |
|
4-Acetylpiperidine Hydrochloride, 98%
| 0-00-1 |
|
3-Chloro-Benzophenone, 99+%
| 1016-78-0 |
|
p-Tolyl isocyanate, 99%
| 622-58-2 |
|
Allylthiourea, 98%
| 109-57-9 |
|
Tetramethylammonium Fluoride Tetrahydrate, 98%
| 17787-40-5 |
|
N,N-Diethylhydroxylamine, 97%
| 3710-84-7 |
|
Aceanthrenequinone, 99+%
| 6373-11-1 |
|
2-Methyl-1-hexene, 98%
| 6094-02-6 |
|
Borane-methyl sulfide complex
| 13292-87-0 |
|
Acetylcholine Iodide, 99% (Titr.)
| 2260-50-6 |
|
Cobalt phthalocyanine
| 3317-67-7 |
|
2,4,4-Trimethyl-2-pentene, 98%
| 107-40-4 |
|
Gamma-Undecalactone, 98%
| 104-67-6 |
|
2,3-Dihydroimidazo(2,1-b)Benzothiazol-6- Amine, 90% (Titr.)
| 78291-99-3 |
|
3,4-Dichlorobenzylamine, 98%
| 102-49-8 |
|
Trifluoroacetic acid 2,2,2-trifluoroethyl ester, 99+%
| 407-38-5 |
|
3,5-Dimethylpyrazole, 98.5%
| 67-51-6 |
|
5-Chloroindole, 99%
| 17422-32-1 |
|
3,4-Dibromothiophene, 97%
| 3141-26-2 |
|
4,5,6-Triaminopyrimidine Sulfate Hydrate, 97%
| 6640-23-9 |
|
(S,S)-(+)-2,5-Bis(Methoxymethyl)Pyrrolidine, 96%
| 93621-94-4 |
|
DL-Camphor, 98%
| 76-22-2 |
|
3-Bromobenzyl alcohol, 99%
| 15852-73-0 |
|
Formaldoxime hydrochloride, 99% (titr.)
| 3473-11-8 |
|
N-Phenyl Di-P-Tolylamine, 97% (GC)
| 20440-95-3 |
|
Poly(vinyl acetate), Secondary Standard, Molecular Weight Series
| 9003-20-7 |
|
Isopropyl beta-D-Thiogalactopyranoside, contains ca. 15% 1,4-Dioxane
| 123-91-1 |
|
Phosphorus Pentachloride, Reagent (Crystals)
| 10026-13-8 |
|
Beryllium fluoride, 98.5+%
| 7787-49-7 |
|
Cholesteryl Oleyl Carbonate, 99+%(TLC)
| 17110-51-9 |
|
Phenylacetone, 99+%
| 103-79-7 |
|
2-Amino-9-Fluorenone
| 3096-57-9 |
|
3,3-Tetramethyleneglutaric Acid, 99%
| 16713-66-9 |
|
Dimethyl Suberimidate Dihydrochloride, 99%
| 34490-86-3 |
|
5-Fluoro-1-indanone, 98%
| 700-84-5 |
|
2,3,5,6-Tetrabromo-4-Methyl-4-Nitrocyclo-Hexa-2,5-Dienone, 97%
| 95111-49-2 |
|
3'-Bromoacetophenone, 97%
| 2142-63-4 |
|
3,5-bis(trifluoromethyl)benzoic acid, 98%
| 725-89-3 |
|
1-Amino-1-cyclohexanecarboxylic acid, 98%
| 2756-85-6 |
|
Methyl Dichlorophosphite, 98%
| 3279-26-3 |
|
1-Chloro-3-Tosylamido-7-Amino-2-Heptanone Hydrochloride, 98%
| 4238-41-9 |
|
Reserpine, 97% (UV-Vis)
| 50-55-5 |
|
|