**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13446-03-2 |Manganese dibromide | 99 | 236-591-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. The lowest exposure
concentration of manganese at which early effects on the CNS and the
lungs may occur is still unknown. However, once neurological signs
are present, they tend to continue and worsen after exposure ends.
Chronic:
Chronic inhalation or ingestion may result in manganism
characterized by neurological symptoms such as headache, apathy, and
weakness of the legs, followed by psychosis and neurological symptoms
similar to those of Parkinson's disease. May impair fertility. Other
chronic effects from inhaling high amounts of manganese include an
increased incidence of cough and bronchitis and susceptibility to
infectious lung disease.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 13446-03-2:
United Kingdom, WEL - TWA: (listed as manganese, inorganic
compounds): 0.5 mg/m3 TWA
United Kingdom, WEL - STEL: (listed as manganese, inorganic
compounds): 1.5 mg/m3 STEL
United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan
compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3
(as Mn)
Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex
organic compounds, as Mn)
Malaysia: (listed as manganese, inorganic compounds): 0.2 mg/m3 T
(as Mn)
Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE
(as Mn)
Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC
Mn)
Spain: (listed as manganese, inorganic compounds): 0.2 mg/m3 VLA-
(as Mn)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: pink
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 4.380 g/cm3
Molecular Formula: Br2Mn
Molecular Weight: 214.76
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat, confined spaces.
Incompatibilities with Other Materials:
No significant incompatibilities identified with common materials and
contaminants..
Hazardous Decomposition Products:
Hydrogen bromide, oxides of manganese.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13446-03-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Manganese dibromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 13446-03-2: No information available.
Canada
CAS# 13446-03-2 is listed on Canada's NDSL List.
CAS# 13446-03-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13446-03-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 9/02/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Poly(diallyl phthalate), average m.w. 65000 (gpc)
| 25053-15-0 |
|
Suberoyl chloride, 97%
| 10027-07-3 |
|
4,4'-Di-Tert.-Butylbiphenyl, 99+%
| 1625-91-8 |
|
1,1,2,2,-Tetrachloroethane, 99% (gc)
| 79-34-5 |
|
4-Nitroimidazole, 98%
| 3034-38-6 |
|
Isobutyl cyanoacetate, 99+%
| 13361-31-4 |
|
1,1,2,2-Tetrachloroethane-d2, 99 atom % d
| 33685-54-0 |
|
p-Phenylenediamine, 99% (uv-vis)
| 106-50-3 |
|
3-Fluoro-2-methylaniline, 97%
| 443-86-7 |
|
Propionitrile, 99%
| 107-12-0 |
|
Manganese(II) carbonate hydrate, 90%
| 598-62-9 |
|
1-Methoxy-1,4-cyclohexadiene, tech., 75%
| 2886-59-1 |
|
Hemin, 99% (uv-vis)
| 16009-13-5 |
|
L-Asparagine, Monohydrate, 99% (Titr.)
| 5794-13-8 |
|
2,6-Dimethylphenol, 99%
| 576-26-1 |
|
Isopropyl(S)-(-)-lactate, 99%
| 63697-00-7 |
|
Vinyltoluene, stabilized with 10 to 15 ppm p-tert-Butylcatechol
| 25013-15-4 |
|
1-Benzylpiperazine, 97+%
| 2759-28-6 |
|
4-Phenylazobenzoyl Chloride
| 104-24-5 |
|
Ethyl Indole-2-Carboxylate, 97%
| 3770-50-1 |
|
2-Chloro-6-Methylbenzonitrile, 97%
| 6575-09-3 |
|
DL-3-Hydroxy-4-Methoxymandelic Acid, 99%
| 3695-24-7 |
|
2,4-Difluorobenzoyl chloride
| 72482-64-5 |
|
2-Methylcyclohexylamine, 98%, mixture of cis and trans
| 7003-32-9 |
|
Manganese Phthalocyanine
| 14325-24-7 |
|
Diethyl Sulfate, 95% (GC)
| 64-67-5 |
|
L-(-)-Perillic Acid, 95%
| 7694-45-3 |
|
m-Phenylenediamine, 99+%
| 108-45-2 |
|
Trimethyl Orthoformate, 99%
| 149-73-5 |
|
5-Methyl-2-nitrophenol, 97%
| 700-38-9 |
|
N-(4-nitrobenzoyl)-l-glutamic acid diethyl ester, 98%
| |
|
5,5-Diphenyl-2-Thiohydantoin, 99%
| 21083-47-6 |
|
Propionic acid-d6, 98.5+ atom% d
| 19448-61-4 |
|
2-Amino-6-methylmercaptopurine
| 1198-47-6 |
|
Manganese(II) bromide, anhydrous, 99%
| 13446-03-2 |
|
2-Methylthiophene, 98%
| 554-14-3 |
|
Cyclohexyl Mercaptan, 99+%
| 1569-69-3 |
|
Trans-4-Octyl-Alpha-Chloro-4'- Ethoxystilbene, 99+%
| 33468-15-4 |
|
2,5-Dihydroxybenzaldehyde, 99%
| 1194-98-5 |
|
Cyclopentyl Bromide, 98%
| 137-43-9 |
|
3,5-Diiodosalicylic Acid, 99% (Titr.)
| 133-91-5 |
|
Tris-(3-(Trifluoromethylhydroxymethylene)- D-Camphorato), YB(III)
| 38054-03-4 |
|
4-Chloro-O-Tolylhydrazine Hydrochloride
| 19690-59-6 |
|
Methyltriethoxysilane, 98+%
| 2031-67-6 |
|
Thorin I, Indicator Grade
| 132-33-2 |
|
2-Amino-6-Chlorobenzothiazole, 99%
| 95-24-9 |
|
10-Undecenoyl chloride, 98%
| 38460-95-6 |
|
D(-)-p-Hydroxyphenylglycine, 98+%
| 22818-40-2 |
|
Methyl 2-Isothiocyanatobenzoate, 98%
| 16024-82-1 |
|
Ethyl 2-oxocyclopentanecarboxylate, tech., 90%
| 611-10-9 |
|
|