**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1569-69-3 |Cyclohexyl Mercaptan | 99+% | 216-378-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/22 36/37/38 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and if swallowed. Irritating to
eyes, respiratory system and skin. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.Stench.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May cause cardiac disturbances.
Ingestion of large amounts may cause CNS depression.
Inhalation:
Causes respiratory tract irritation. May cause kidney damage.
Aspiration may lead to pulmonary edema. Vapors may cause dizziness
or suffocation. May cause cardiac abnormalities. Exposure may produce
metabolic acidosis. Inhalation at high concentrations may cause CNS
depression and asphixiation. May cause burning sensation in the
chest.
Chronic:
Effects may be delayed. May cause kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Use with adequate ventilation. Wash clothing before
reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 1569-69-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 5 mbar @ 20 C
Viscosity: 1.69 cP 20.00 deg
Boiling Point: 158 - 160 deg C @ 760.00mmHg
Freezing/Melting Point: -30 deg C
Autoignition Temperature: 510 deg C ( 950.00 deg F)
Flash Point: 49 deg C ( 120.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .9500g/cm3
Molecular Formula: C6H12S
Molecular Weight: 116.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, bases, alkali metals.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1569-69-3: GV7525000
LD50/LC50:
CAS# 1569-69-3: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 2 mg/24H Severe.
Carcinogenicity:
Cyclohexyl Mercaptan -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CYCLOHEXYL MERCAPTAN
Hazard Class: 3
UN Number: 3054
Packing Group: III
IMO
Shipping Name: CYCLOHEXYL MERCAPTAN
Hazard Class: 3.3
UN Number: 3054
Packing Group: III
RID/ADR
Shipping Name: CYCLOHEXYL MERCAPTAN
Hazard Class: 3
UN Number: 3054
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 1569-69-3: No information available.
Canada
CAS# 1569-69-3 is listed on Canada's DSL List.
CAS# 1569-69-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1569-69-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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4,4'-Di-Tert.-Butylbiphenyl, 99+%
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1,1,2,2,-Tetrachloroethane, 99% (gc)
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3-Fluoro-2-methylaniline, 97%
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| 63697-00-7 |
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| 25013-15-4 |
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| 2759-28-6 |
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| 104-24-5 |
|
Ethyl Indole-2-Carboxylate, 97%
| 3770-50-1 |
|
2-Chloro-6-Methylbenzonitrile, 97%
| 6575-09-3 |
|
DL-3-Hydroxy-4-Methoxymandelic Acid, 99%
| 3695-24-7 |
|
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| 7003-32-9 |
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| 14325-24-7 |
|
Diethyl Sulfate, 95% (GC)
| 64-67-5 |
|
L-(-)-Perillic Acid, 95%
| 7694-45-3 |
|
m-Phenylenediamine, 99+%
| 108-45-2 |
|
Trimethyl Orthoformate, 99%
| 149-73-5 |
|
5-Methyl-2-nitrophenol, 97%
| 700-38-9 |
|
N-(4-nitrobenzoyl)-l-glutamic acid diethyl ester, 98%
| |
|
5,5-Diphenyl-2-Thiohydantoin, 99%
| 21083-47-6 |
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Propionic acid-d6, 98.5+ atom% d
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2-Amino-6-methylmercaptopurine
| 1198-47-6 |
|
Manganese(II) bromide, anhydrous, 99%
| 13446-03-2 |
|
2-Methylthiophene, 98%
| 554-14-3 |
|
Cyclohexyl Mercaptan, 99+%
| 1569-69-3 |
|
Trans-4-Octyl-Alpha-Chloro-4'- Ethoxystilbene, 99+%
| 33468-15-4 |
|
2,5-Dihydroxybenzaldehyde, 99%
| 1194-98-5 |
|
Cyclopentyl Bromide, 98%
| 137-43-9 |
|
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| 133-91-5 |
|
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| 38054-03-4 |
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| 19690-59-6 |
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| 2031-67-6 |
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| 132-33-2 |
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| 95-24-9 |
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| 38460-95-6 |
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| 22818-40-2 |
|
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| 16024-82-1 |
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| 611-10-9 |
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