**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 19448-61-4 |PROPIONIC ACID-D6 | ATOM | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Toxic.
Potential Health Effects
Eye:
May cause transient corneal injury. Causes redness and pain.
Causes eye irritation and burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns. Prolonged
skin contact may cause injury especially if the skin is abraded.
Ingestion:
Aspiration hazard. May cause irritation of the digestive tract.
Possible aspiration hazard. May cause burns to the digestive tract.
Inhalation:
Dust is irritating to the respiratory tract. May cause asthma and
shortness of breath.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation may cause effects similar to those of acute inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Flammable Liquid. Can release vapors that form explosive
mixtures at temperatures above the flashpoint. Use water spray to
keep fire-exposed containers cool.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Use water spray to disperse the
gas/vapor. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Do not get in eyes, on
skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 19448-61-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Not available.
Odor: Rancid odor.
pH: Not available.
Vapor Pressure: 2 mm Hg @20C
Viscosity: Not available.
Boiling Point: 138 - 140 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 51 deg C ( 123.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C3D6O2
Molecular Weight: 80.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Bases, oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 19448-61-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
PROPIONIC ACID-D6 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish toxicity:
LC50 (24 hr) bluegill sunfish 188 mg/l
Invertebrate
toxicity:
LC50 (48 hr) Daphnia magna 50 mg/l
(Dictionary of
Substances and Their Effects 1992).
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PROPIONIC ACID
Hazard Class: 8
UN Number: 1848
Packing Group: III
IMO
Shipping Name: PROPIONIC ACID
Hazard Class: 8
UN Number: 1848
Packing Group: III
RID/ADR
Shipping Name: PROPIONIC ACID
Hazard Class: 8
UN Number: 1848
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 19448-61-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 19448-61-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 19448-61-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Poly(diallyl phthalate), average m.w. 65000 (gpc)
| 25053-15-0 |
|
Suberoyl chloride, 97%
| 10027-07-3 |
|
4,4'-Di-Tert.-Butylbiphenyl, 99+%
| 1625-91-8 |
|
1,1,2,2,-Tetrachloroethane, 99% (gc)
| 79-34-5 |
|
4-Nitroimidazole, 98%
| 3034-38-6 |
|
Isobutyl cyanoacetate, 99+%
| 13361-31-4 |
|
1,1,2,2-Tetrachloroethane-d2, 99 atom % d
| 33685-54-0 |
|
p-Phenylenediamine, 99% (uv-vis)
| 106-50-3 |
|
3-Fluoro-2-methylaniline, 97%
| 443-86-7 |
|
Propionitrile, 99%
| 107-12-0 |
|
Manganese(II) carbonate hydrate, 90%
| 598-62-9 |
|
1-Methoxy-1,4-cyclohexadiene, tech., 75%
| 2886-59-1 |
|
Hemin, 99% (uv-vis)
| 16009-13-5 |
|
L-Asparagine, Monohydrate, 99% (Titr.)
| 5794-13-8 |
|
2,6-Dimethylphenol, 99%
| 576-26-1 |
|
Isopropyl(S)-(-)-lactate, 99%
| 63697-00-7 |
|
Vinyltoluene, stabilized with 10 to 15 ppm p-tert-Butylcatechol
| 25013-15-4 |
|
1-Benzylpiperazine, 97+%
| 2759-28-6 |
|
4-Phenylazobenzoyl Chloride
| 104-24-5 |
|
Ethyl Indole-2-Carboxylate, 97%
| 3770-50-1 |
|
2-Chloro-6-Methylbenzonitrile, 97%
| 6575-09-3 |
|
DL-3-Hydroxy-4-Methoxymandelic Acid, 99%
| 3695-24-7 |
|
2,4-Difluorobenzoyl chloride
| 72482-64-5 |
|
2-Methylcyclohexylamine, 98%, mixture of cis and trans
| 7003-32-9 |
|
Manganese Phthalocyanine
| 14325-24-7 |
|
Diethyl Sulfate, 95% (GC)
| 64-67-5 |
|
L-(-)-Perillic Acid, 95%
| 7694-45-3 |
|
m-Phenylenediamine, 99+%
| 108-45-2 |
|
Trimethyl Orthoformate, 99%
| 149-73-5 |
|
5-Methyl-2-nitrophenol, 97%
| 700-38-9 |
|
N-(4-nitrobenzoyl)-l-glutamic acid diethyl ester, 98%
| |
|
5,5-Diphenyl-2-Thiohydantoin, 99%
| 21083-47-6 |
|
Propionic acid-d6, 98.5+ atom% d
| 19448-61-4 |
|
2-Amino-6-methylmercaptopurine
| 1198-47-6 |
|
Manganese(II) bromide, anhydrous, 99%
| 13446-03-2 |
|
2-Methylthiophene, 98%
| 554-14-3 |
|
Cyclohexyl Mercaptan, 99+%
| 1569-69-3 |
|
Trans-4-Octyl-Alpha-Chloro-4'- Ethoxystilbene, 99+%
| 33468-15-4 |
|
2,5-Dihydroxybenzaldehyde, 99%
| 1194-98-5 |
|
Cyclopentyl Bromide, 98%
| 137-43-9 |
|
3,5-Diiodosalicylic Acid, 99% (Titr.)
| 133-91-5 |
|
Tris-(3-(Trifluoromethylhydroxymethylene)- D-Camphorato), YB(III)
| 38054-03-4 |
|
4-Chloro-O-Tolylhydrazine Hydrochloride
| 19690-59-6 |
|
Methyltriethoxysilane, 98+%
| 2031-67-6 |
|
Thorin I, Indicator Grade
| 132-33-2 |
|
2-Amino-6-Chlorobenzothiazole, 99%
| 95-24-9 |
|
10-Undecenoyl chloride, 98%
| 38460-95-6 |
|
D(-)-p-Hydroxyphenylglycine, 98+%
| 22818-40-2 |
|
Methyl 2-Isothiocyanatobenzoate, 98%
| 16024-82-1 |
|
Ethyl 2-oxocyclopentanecarboxylate, tech., 90%
| 611-10-9 |
|
|