**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13446-34-9 |Manganese (II) Chloride Tetrahydrate, | | unlisted |
| |P.A. | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.Hygroscopic.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed. In high doses, manganese may
increase anemia by interfering with iron absorption.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic manganese toxicity through inhalation may result in
"manganism", which is a disease of the central nervous system
involving psychic and neurological disorders.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Appearance: pink
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 58 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >100 deg C
Solubility in water: 1980 g/l (20 c)
Specific Gravity/Density: 2.0100g/cm3
Molecular Formula: Cl2Mn.4H2O
Molecular Weight: 197.91
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, zinc, potassium, sodium.
Hazardous Decomposition Products:
Hydrogen chloride.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13446-34-9: OO9650000
LD50/LC50:
CAS# 13446-34-9: Oral, rat: LD50 = 1484 mg/kg.
Carcinogenicity:
Manganese (II) Chloride Tetrahydrate, P.A. -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 13446-34-9: No information available.
United Kingdom Occupational Exposure Limits
CAS# 13446-34-9: OES-United Kingdom, TWA (listed as ** undefined
**): as Mn: 5 mg/m3 TWA
CAS# 13446-34-9: OES-United Kingdom, STEL (listed as ** undefined
**): fume, as Mn: 3 mg/m3 STEL
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13446-34-9 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 13446-34-9: OEL-AUSTRALIA:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL-BELGIUM:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL-CZECHOSLOVAKIA:TWA 2 mg(Mn)/m3;STEL 6 mg(Mn)/m3 JANUARY 1993
OEL-DENMARK:TWA 2.5 mg(Mn)/m3 JANUARY 1993
OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JANUARY 1993
OEL-HUNGARY:TWA 0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JANUARY 1993
OEL-JAPAN:TWA 0.3 mg(Mn)/m3 JANUARY 1993
OEL-THE NETHERLANDS:TWA 1 mg(Mn)/m3 JANUARY 1993
OEL-POLAND:TWA 0.3 mg(Mn)/m3 JANUARY 1993
OEL-SWEDEN:TWA 1 mg(Mn)/m3;STEL 2.5 mg(Mn)/m3 (resp. dust)
OEL-SWEDEN:TWA 2.5 mg(Mn)/m3;STEL 5 mg(Mn)/m3 (total dust)
OEL-UNITED KINGDOM:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 13446-34-9 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/15/1998 Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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4-Fluoro-2-methylphenol, 98%
| 452-72-2 |
|
1,2-Dimethyl-6,7-dimethoxy-1,2,3,4-tetrahydroisoquinoline
| 5852-92-6 |
|
D-(+)-Maltose monohydrate, 92-93%
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6,7-Dihydroxy-1-methyl-1,2,3,4-tetrahydroisoquinoline hydrobromide,
| 38221-21-5 |
|
Manganese (II) Chloride Tetrahydrate, P.A.
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6-Azabicyclo[3.2.0]Heptan-7-one, 98%
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Manganese(IV) Oxide, Precipitated Active, 88% (Titr.)
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|
7-Azabicyclo[4.2.0]heptan-8-one, 98%
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|
Manganese (II) Sulfate Monohydrate, Reagent ACS
| 10034-96-5 |
|
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| 0-01-1 |
|
3-Amino-4-Ethylhexanoic Acid, 98%
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|
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| 69-65-8 |
|
Stoddard Solvent
| 8052-41-3 |
|
3-Amino-5-methylhexanoic acid, 98%
| 3653-34-7 |
|
Dl-citrulline, 97%
| 627-77-0 |
|
2-Mercaptoethanol, 99%
| 60-24-2 |
|
Aluminum Hydroxide, Powder
| 21645-51-2 |
|
N,N'-bis(p-butoxybenzylidene)-alpha, alpha'-bi-p-toluidine
| 59261-10-8 |
|
Mercuric acetate, p.a.
| 1600-27-7 |
|
Mercury (II) Bromide, P.A.
| 7789-47-1 |
|
Hexaethylbenzene
| 604-88-6 |
|
3-Amino-5-phenylpentanoic acid, 98%
| 91247-38-0 |
|
Ethyl-cis-2-isothiocyanato-1-cyclopentanecarboxylate, 97%
| 311341-94-3 |
|
Aluminum nitrate nonahydrate
| 7784-27-2 |
|
Mercury(II) chloride, reagent ACS, crystals
| 7487-94-7 |
|
Molybdenum, powder, 99.99%, - 200 mesh
| 7439-98-7 |
|
Ethyl-cis-2-Isothiocyanato-1-Cyclohexanecarboxylate, 97%
| 0-01-1 |
|
Boc-L-Alanine, 99+%
| 15761-38-3 |
|
Poly(caprolactone) Triol, Average M.W.300
| 39280-09-6 |
|
Mercury (II) Iodide, Red, P.A.
| 7774-29-0 |
|
Mercury (II) Nitrate Monohydrate, Reagent ACS
| 7783-34-8 |
|
Alumina (Activated/Adsorption/Dry Powder/Acid/Basic/Neutral/Polishing
| 1344-28-1 |
|
N-Isopropyl-1-Piperazineacetamide, 95+%
| 39890-42-1 |
|
2,5-Diethoxyaniline, 96%
| 94-85-9 |
|
Mercury (II) Oxide, Yellow, P.A.
| 21908-53-2 |
|
Mercury (II) Sulfate, Reagent ACS (Powder)
| 7783-35-9 |
|
Mercury Chloride, P.A
| 10112-91-1 |
|
Chloroacetyl chloride, 98%
| 79-04-9 |
|
2,2-Bis(hydroxymethyl)propionic acid, 99+%
| 4767-03-7 |
|
1,3-Dibromotetrafluorobenzene, 98%
| 1559-87-1 |
|
2-Methyl-1-buten-3-yne, 98%
| 78-80-8 |
|
Mercury, P.A.
| 7439-97-6 |
|
Methyl acetate, 99%
| 79-20-9 |
|
ACES
| 7365-82-4 |
|
Methyl benzoate, 99%
| 93-58-3 |
|
2-Methoxyethanol, 99+%
| 109-86-4 |
|
ADA, BioGRADE
| 26239-55-4 |
|
Methyl cellulose (2% solution in water) viscosity 3500-5600
| 9004-67-5 |
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BES, BioGRADE
| 10191-18-1 |
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4-Methyl-2-Pentanone, 99.5%, Spectrophoto- Metric Grade
| 108-10-1 |
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