**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 142-28-9 |1,3-Dichloropropane | 99.0 | 205-531-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.The toxicological properties of this material have
not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Vapors cause eye irritation.
Skin:
Causes skin irritation. Prolonged exposure may cause a smarting and
reddening of the skin.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. For large fires,
use water spray, fog or regular foam. For small fires, use dry
chemical, carbon dioxide, water spray or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. A vapor suppressing foam may be used to
reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 142-28-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: sweetish odor
pH: Not available.
Vapor Pressure: 20 mbar @ 20 deg C
Viscosity: 1.1 mPas 20 deg C
Boiling Point: 120 - 122 deg C @ 760.00mm Hg
Freezing/Melting Point: -99 deg C
Autoignition Temperature: 480 deg C ( 896.00 deg F)
Flash Point: 70 deg F ( 21.11 deg C)
Explosion Limits, lower: 3.4
Explosion Limits, upper: 14.5
Decomposition Temperature:
Solubility in water: IN WATER: 0.8 G/L (20C)
Specific Gravity/Density: 1.1900g/cm3
Molecular Formula: C3H6Cl2
Molecular Weight: 112.99
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, acids, , aluminum, orthodichlorobenzene + ethylene
dichloride + aluminum.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 142-28-9: TX9660000
LD50/LC50:
Not available.
Carcinogenicity:
1,3-Dichloropropane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
See also Dictionary of Substances and Their Effects.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
USA RQ: CAS# 142-28-9: 1000 lb final RQ (Listed under Dichloropropane); 454 kg f
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 142-28-9: 3
Canada
CAS# 142-28-9 is listed on Canada's NDSL List.
CAS# 142-28-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 142-28-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cadmium cyclohexanebutyrate
| 55700-14-6 |
|
1,3-Dichloropropane, 99%
| 142-28-9 |
|
1,2,3,4-Tetrahydrocarbazole, 99%
| 942-01-8 |
|
2-Chloro-4-Nitroaniline, 99%
| 121-87-9 |
|
4,6-Dihydroxypyrimidine, 98%
| 1193-24-4 |
|
(+)-Dehydroisoandrosterone, 99% (hplc)
| 53-43-0 |
|
Tiron(R)
| 149-45-1 |
|
Allyltributyltin, 97%
| 24850-33-7 |
|
Vanadium oxobis(1-phenyl-1,3-butane- dionate)
| 14767-37-4 |
|
Alpha-Methyl-D-Mannopyranoside, 99%
| 617-04-9 |
|
4-Chloro-3-Nitrobenzyl Alcohol, 98%
| 55912-20-4 |
|
3-Ethoxyacrylic Acid Ethyl Ester
| 1001-26-9 |
|
DL-4-Amino-3-Hydroxybutyric Acid, 98%
| 352-21-6 |
|
2-Bromo-4-Methylphenol, 96%
| 6627-55-0 |
|
4-Hydroxy-3-Methoxycinnamic Acid, 99%
| 1135-24-6 |
|
2,4-Dibromothiophene, 96%
| 3140-92-9 |
|
Acridine-9-Carboxylic Acid Hydrate
| 5336-90-3 |
|
Platinum on alumina (5% pt)
| 7440-06-4 |
|
l-Methionine methylsulfonium iodide, 99% e.e.
| 34236-06-1 |
|
N,n'-diheptyl-4,4'-bipyridinium dibromide, 99% (titr.)
| 6159-05-3 |
|
Ethyl 3-exo-aminobicyclo[2.2.1]heptane-2-exo-carboxylate
| 95630-75-4 |
|
Benzenesulfonic Acid Sodium Salt, 98% (uv-vis)
| 515-42-4 |
|
3,4'-Dimethylbenzophenone
| 13152-94-8 |
|
2-Bromobutyric acid, 99%
| 80-58-0 |
|
2-Methylbutylamine, 98%
| 96-15-1 |
|
4-Bromophenyl Methyl Carbinol, 98%
| 5391-88-8 |
|
2,3-Dimethylphenol, 97% (GC)
| 526-75-0 |
|
Phorone (2,6-dimethyl-2,5-heptadien-4- one), 98%
| 504-20-1 |
|
Alpha-Cyano-4-Hydroxycinnamic Acid, 97%
| 28166-41-8 |
|
Cibacron Brilliant Yellow 3G-P
| 50662-99-2 |
|
1-Bromo-2,6-Dichlorobenzene, 99%
| 19393-92-1 |
|
3-Hydroxypiperidine Hydrochloride, 99%
| 64051-79-2 |
|
Brij?? 58, contains 0.01% BHA and 0.005% citric acid as preservatives
| 9004-95-9 |
|
3'-Ethoxyacetanilide, 99+%
| 591-33-3 |
|
2-Fluoro-5-methylsulphonylnitrobenzene 95+%
| |
|
(s)-(-)-2-Phenyl-1-propanol, 99+%
| 1517-68-6 |
|
3,6-Dichloropyridazine, 97%
| 141-30-0 |
|
2-Butoxytetrahydrofuran, 99%
| 1927-59-9 |
|
Benzethonium chloride, 97%
| 121-54-0 |
|
DL-Glyceraldehyde, 98%
| 56-82-6 |
|
Borane-N,N-diethylaniline complex
| 13289-97-9 |
|
4-Octylphenol, 99% (GC)
| 1806-26-4 |
|
Dibenzyldiselenide, 99+%
| 1482-82-2 |
|
1-Pentadecene, 98%
| 13360-61-7 |
|
5-Bromoacenaphthene, 94%
| 2051-98-1 |
|
Acetal, 99%
| 105-57-7 |
|
Niobium atomic absorption standard solution, 1 mg/ml Nb in 5% HF
| 7440-03-1 |
|
Cytochalasin A
| 14110-64-6 |
|
Cumene, 99%
| 98-82-8 |
|
Pentaerythrityl Tetrastearate (Pract)
| 115-83-3 |
|
|