Search   
MSDS 
:
 Vanadium oxobis(1-phenyl-1,3-butane- dionate)
CAS 
:
 14767-37-4
SYNONYMS 
:
 Bis(1-phenyl-1,3-butanedione)oxovanadium(IV)
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 14767-37-4 |Vanadium,oxobis(1-phenyl-1,3-butanedio| ca. 100 | 238-832-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Heat sensitive.

Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. May cause contact dermatitis.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
Dust is irritating to the respiratory tract.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode when heated. Non-combustible, substance itself does not
burn but may decompose upon heating to produce corrosive and/or
toxic fumes.
Extinguishing Media:
Do NOT use straight streams of water. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use water
spray, fog or regular foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Avoid
generating dusty conditions. Provide ventilation. Do not get water
inside containers. Cover with plastic sheet to prevent spreading.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 14767-37-4:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Crystals
Color: shiny green
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 218 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density: >1
Molecular Formula: C20H18O5V
Molecular Weight: 389.29

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 14767-37-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Vanadium,oxobis(1-phenyl-1,3-butanedionato-o,o') -
Not listed by ACGIH, IARC, or NTP.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Other
No information available.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing Group: II
IMO
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing Group: II
RID/ADR
Shipping Name: VANADIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 3285
Packing group: II

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 14767-37-4: No information available.
Canada
CAS# 14767-37-4 is listed on Canada's NDSL List.
CAS# 14767-37-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14767-37-4 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 2/03/1999 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
Search More   
ALL MSDS PAGES IN THIS GROUP
NAMECAS
Cadmium cyclohexanebutyrate 55700-14-6
1,3-Dichloropropane, 99% 142-28-9
1,2,3,4-Tetrahydrocarbazole, 99% 942-01-8
2-Chloro-4-Nitroaniline, 99% 121-87-9
4,6-Dihydroxypyrimidine, 98% 1193-24-4
(+)-Dehydroisoandrosterone, 99% (hplc) 53-43-0
Tiron(R) 149-45-1
Allyltributyltin, 97% 24850-33-7
Vanadium oxobis(1-phenyl-1,3-butane- dionate) 14767-37-4
Alpha-Methyl-D-Mannopyranoside, 99% 617-04-9
4-Chloro-3-Nitrobenzyl Alcohol, 98% 55912-20-4
3-Ethoxyacrylic Acid Ethyl Ester 1001-26-9
DL-4-Amino-3-Hydroxybutyric Acid, 98% 352-21-6
2-Bromo-4-Methylphenol, 96% 6627-55-0
4-Hydroxy-3-Methoxycinnamic Acid, 99% 1135-24-6
2,4-Dibromothiophene, 96% 3140-92-9
Acridine-9-Carboxylic Acid Hydrate 5336-90-3
Platinum on alumina (5% pt) 7440-06-4
l-Methionine methylsulfonium iodide, 99% e.e. 34236-06-1
N,n'-diheptyl-4,4'-bipyridinium dibromide, 99% (titr.) 6159-05-3
Ethyl 3-exo-aminobicyclo[2.2.1]heptane-2-exo-carboxylate 95630-75-4
Benzenesulfonic Acid Sodium Salt, 98% (uv-vis) 515-42-4
3,4'-Dimethylbenzophenone 13152-94-8
2-Bromobutyric acid, 99% 80-58-0
2-Methylbutylamine, 98% 96-15-1
4-Bromophenyl Methyl Carbinol, 98% 5391-88-8
2,3-Dimethylphenol, 97% (GC) 526-75-0
Phorone (2,6-dimethyl-2,5-heptadien-4- one), 98% 504-20-1
Alpha-Cyano-4-Hydroxycinnamic Acid, 97% 28166-41-8
Cibacron Brilliant Yellow 3G-P 50662-99-2
1-Bromo-2,6-Dichlorobenzene, 99% 19393-92-1
3-Hydroxypiperidine Hydrochloride, 99% 64051-79-2
Brij?? 58, contains 0.01% BHA and 0.005% citric acid as preservatives 9004-95-9
3'-Ethoxyacetanilide, 99+% 591-33-3
2-Fluoro-5-methylsulphonylnitrobenzene 95+%
(s)-(-)-2-Phenyl-1-propanol, 99+% 1517-68-6
3,6-Dichloropyridazine, 97% 141-30-0
2-Butoxytetrahydrofuran, 99% 1927-59-9
Benzethonium chloride, 97% 121-54-0
DL-Glyceraldehyde, 98% 56-82-6
Borane-N,N-diethylaniline complex 13289-97-9
4-Octylphenol, 99% (GC) 1806-26-4
Dibenzyldiselenide, 99+% 1482-82-2
1-Pentadecene, 98% 13360-61-7
5-Bromoacenaphthene, 94% 2051-98-1
Acetal, 99% 105-57-7
Niobium atomic absorption standard solution, 1 mg/ml Nb in 5% HF 7440-03-1
Cytochalasin A 14110-64-6
Cumene, 99% 98-82-8
Pentaerythrityl Tetrastearate (Pract) 115-83-3

Free MSDS Search ( Providing 250,000+ Material Properties )
Chemcas.com| Ads link:todaystock.net