**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 5391-88-8 |4-Bromophenyl Methyl Carbinol | 98 | 226-389-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Aspiration may
lead to pulmonary edema. Inhalation at high concentrations may cause
CNS depression and asphixiation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Remove all sources of ignition. Use a spark-proof
tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 5391-88-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid above room te
Color: colorless - white crystalline solid
Odor: bromine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 119-121 deg C @ 7.00mmHg
Freezing/Melting Point: 36.00 - 38.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 63 deg C ( 145.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density: 1.4600g/cm3
Molecular Formula: C8H9BrO
Molecular Weight: 201.06
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide, bromine fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 5391-88-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromophenyl Methyl Carbinol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 5391-88-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5391-88-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5391-88-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Cadmium cyclohexanebutyrate
| 55700-14-6 |
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1,3-Dichloropropane, 99%
| 142-28-9 |
|
1,2,3,4-Tetrahydrocarbazole, 99%
| 942-01-8 |
|
2-Chloro-4-Nitroaniline, 99%
| 121-87-9 |
|
4,6-Dihydroxypyrimidine, 98%
| 1193-24-4 |
|
(+)-Dehydroisoandrosterone, 99% (hplc)
| 53-43-0 |
|
Tiron(R)
| 149-45-1 |
|
Allyltributyltin, 97%
| 24850-33-7 |
|
Vanadium oxobis(1-phenyl-1,3-butane- dionate)
| 14767-37-4 |
|
Alpha-Methyl-D-Mannopyranoside, 99%
| 617-04-9 |
|
4-Chloro-3-Nitrobenzyl Alcohol, 98%
| 55912-20-4 |
|
3-Ethoxyacrylic Acid Ethyl Ester
| 1001-26-9 |
|
DL-4-Amino-3-Hydroxybutyric Acid, 98%
| 352-21-6 |
|
2-Bromo-4-Methylphenol, 96%
| 6627-55-0 |
|
4-Hydroxy-3-Methoxycinnamic Acid, 99%
| 1135-24-6 |
|
2,4-Dibromothiophene, 96%
| 3140-92-9 |
|
Acridine-9-Carboxylic Acid Hydrate
| 5336-90-3 |
|
Platinum on alumina (5% pt)
| 7440-06-4 |
|
l-Methionine methylsulfonium iodide, 99% e.e.
| 34236-06-1 |
|
N,n'-diheptyl-4,4'-bipyridinium dibromide, 99% (titr.)
| 6159-05-3 |
|
Ethyl 3-exo-aminobicyclo[2.2.1]heptane-2-exo-carboxylate
| 95630-75-4 |
|
Benzenesulfonic Acid Sodium Salt, 98% (uv-vis)
| 515-42-4 |
|
3,4'-Dimethylbenzophenone
| 13152-94-8 |
|
2-Bromobutyric acid, 99%
| 80-58-0 |
|
2-Methylbutylamine, 98%
| 96-15-1 |
|
4-Bromophenyl Methyl Carbinol, 98%
| 5391-88-8 |
|
2,3-Dimethylphenol, 97% (GC)
| 526-75-0 |
|
Phorone (2,6-dimethyl-2,5-heptadien-4- one), 98%
| 504-20-1 |
|
Alpha-Cyano-4-Hydroxycinnamic Acid, 97%
| 28166-41-8 |
|
Cibacron Brilliant Yellow 3G-P
| 50662-99-2 |
|
1-Bromo-2,6-Dichlorobenzene, 99%
| 19393-92-1 |
|
3-Hydroxypiperidine Hydrochloride, 99%
| 64051-79-2 |
|
Brij?? 58, contains 0.01% BHA and 0.005% citric acid as preservatives
| 9004-95-9 |
|
3'-Ethoxyacetanilide, 99+%
| 591-33-3 |
|
2-Fluoro-5-methylsulphonylnitrobenzene 95+%
| |
|
(s)-(-)-2-Phenyl-1-propanol, 99+%
| 1517-68-6 |
|
3,6-Dichloropyridazine, 97%
| 141-30-0 |
|
2-Butoxytetrahydrofuran, 99%
| 1927-59-9 |
|
Benzethonium chloride, 97%
| 121-54-0 |
|
DL-Glyceraldehyde, 98%
| 56-82-6 |
|
Borane-N,N-diethylaniline complex
| 13289-97-9 |
|
4-Octylphenol, 99% (GC)
| 1806-26-4 |
|
Dibenzyldiselenide, 99+%
| 1482-82-2 |
|
1-Pentadecene, 98%
| 13360-61-7 |
|
5-Bromoacenaphthene, 94%
| 2051-98-1 |
|
Acetal, 99%
| 105-57-7 |
|
Niobium atomic absorption standard solution, 1 mg/ml Nb in 5% HF
| 7440-03-1 |
|
Cytochalasin A
| 14110-64-6 |
|
Cumene, 99%
| 98-82-8 |
|
Pentaerythrityl Tetrastearate (Pract)
| 115-83-3 |
|
|