**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 14592-56-4 |Bis(acetonitrile)palladium(II) chlorid| 99 % | 238-637-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.Toxic.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Harmful if absorbed through the skin. Exposure may cause irritation
and possible burns.
Ingestion:
Harmful if swallowed. May cause severe digestive tract irritation
with abdominal pain, nausea, vomiting and diarrhea.
Inhalation:
Harmful if inhaled. May cause irritation of the respiratory tract
with burning pain in the nose and throat, coughing, wheezing,
shortness of breath and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Do not get on skin or in eyes. Do not ingest
or inhale. Handle under an inert atmosphere.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 14592-56-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: rust
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: @ 760.00mm Hg
Freezing/Melting Point: 300 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C4H6Cl2N2Pd
Molecular Weight: 259.40
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidants.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide, nitrogen, benzonitrile.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 14592-56-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Bis(acetonitrile)palladium(II) chloride, 99% -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 14592-56-4: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 14592-56-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14592-56-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Phenyl-4,5-Dichloro-6-Pyridazone, 99+%
| 1698-53-9 |
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N,N-Dimethyl-P-Phenylenediamine Dihydrochloride 99%
| 536-46-9 |
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1-Adamantanecarboxylic Acid, 99%
| 828-51-3 |
|
Dl-2-(M-Chlorophenoxy)Propionic Acid, 98%
| 101-10-0 |
|
Mercaptoacetic acid, sodium salt, 98%
| 367-51-1 |
|
Heptanophenone, 98+%
| 1671-75-6 |
|
Cyclobutanone, 98+%
| 1191-95-3 |
|
m-Tolualdehyde, 98%, stabilized with 0.1% Hydroquinone
| 620-23-5 |
|
D(+)-raffinose pentahydrate, 99+%
| 17629-30-0 |
|
Cyclohexanone 2,4-Dinitrophenylhydrazone, 99+%
| 1589-62-4 |
|
DL-Aspartic Acid
| 617-45-8 |
|
Diallyldisulfide, 70%, Remainder Mainly Diallyl Sulfide
| 2179-57-9 |
|
DL-2-Aminoadipic Acid Hydrate
| 542-32-5 |
|
3,3'-Diethylthiatricarbocyanine Iodide, Laser Grade
| 3071-70-3 |
|
Hexadecanedioic acid, 97%
| 505-54-4 |
|
Sodium tri-sec-butylborohydride, 1M solution in tetrahydrofuran
| 109-99-9 |
|
L-Phenylalanine Methyl Ester Hydrochloride, 98%
| 7524-50-7 |
|
3,3',4',5-Tetrachlorosalicylanilide, 99% (UV-Vis)
| 1154-59-2 |
|
p-Toluene Sulfonic Acid Monohydrate Cr 500g
| 6192-52-5 |
|
4-Chlorobenzoic acid, 99%
| 74-11-3 |
|
Chlortetracycline Hydrochloride, can be used as Secondary Standard
| 64-72-2 |
|
2-Bromopyridine-N-oxide hydrochloride, 97%
| 80866-91-7 |
|
2,6-Difluorophenylacetic Acid, 99% (Titr.)
| 85068-28-6 |
|
4-Aminobenzoic Acid, Sodium Salt, Hydrate
| 555-06-6 |
|
Neocuproine hydrochloride monohydrate, 99%
| 7296-20-0 |
|
9-Fluorenylmethyl chloroformate 97%
| 28920-43-6 |
|
Butadiene monoxide, 97%
| 930-22-3 |
|
L-(-)-Fucose, 97%
| 2438-80-4 |
|
Ethenesulfonyl fluoride, 97% (gc)
| 677-25-8 |
|
P-(2,4-Dinitroanilino)phenol Moist Solid Containing 30% Water
| 119-15-3 |
|
1,3-Dichlorobenzene, 98%
| 541-73-1 |
|
Bis-(acetonitrile)-palladium(ii)chloride, 99%
| 14592-56-4 |
|
Tri-tert-butyl borate, 98%
| 7397-43-5 |
|
D(-)-Glucose Diethyl Mercaptal
| 1941-52-2 |
|
Piperonylonitrile, 97%
| 4421-09-4 |
|
D(+)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt, 99%
| 14575-84-9 |
|
3-Iodoaniline, 98%
| 626-01-7 |
|
Citronellol, 95%
| 106-22-9 |
|
Methyl-5-doxyl-stearate, free radical
| 38568-24-0 |
|
N-Methyl-N-Phenylcarbamoyl Chloride, 99% (Titr.)
| 4285-42-1 |
|
Alpha, Alpha,2-Trichloro-6-Fluorotoluene, 99%
| 62476-62-4 |
|
3-(2-Maleimidoethyl-carbomoyl)-Proxyl, Free Radical
| 66641-27-8 |
|
(Methoxymethyl)-triphenylphosphonium chloride, 98%
| 4009-98-7 |
|
n-Methylisatoic anhydride, tech., 90+%
| 10328-92-4 |
|
(+)-Camptothecin, 98%
| 7689-03-4 |
|
Pentachlorophenol
| 87-86-5 |
|
Humic acid, sodium salt, tech
| 68131-04-4 |
|
N-Aminophthalimide, Tech., 90+%
| 1875-48-5 |
|
n-Acetyl-s-phenyl-l-cysteine methyl ester
| 19542-77-9 |
|
3-(4-Hydroxyphenyl)propionic acid, 98%
| 501-97-3 |
|
|