**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 62476-62-4 |Alpha, Alpha, 2-Trichloro-6-Fluorotolu| 99 | 263-562-8 |
| |ene | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Lachrymator
(substance which increases the flow of tears).Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. Lachrymator (substance which increases the flow of tears).
May cause chemical conjunctivitis and corneal damage.
Skin:
May cause severe irritation and possible burns. May cause skin rash
(in milder cases), and cold and clammy skin with cyanosis or pale
color.
Ingestion:
May cause severe and permanent damage to the digestive tract. May
cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause perforation of the digestive tract. The
toxicological properties of this substance have not been fully
investigated. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with
flooding quantities of water until well after fire is out. Use water
spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Wash clothing
before reuse. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 62476-62-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: toluene-like odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 228.0 - 230.0 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4460g/cm3
Molecular Formula: C7H4Cl3F
Molecular Weight: 213.47
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 62476-62-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Alpha, Alpha, 2-Trichloro-6-Fluorotoluene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 62476-62-4: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 62476-62-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 62476-62-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Phenyl-4,5-Dichloro-6-Pyridazone, 99+%
| 1698-53-9 |
|
N,N-Dimethyl-P-Phenylenediamine Dihydrochloride 99%
| 536-46-9 |
|
1-Adamantanecarboxylic Acid, 99%
| 828-51-3 |
|
Dl-2-(M-Chlorophenoxy)Propionic Acid, 98%
| 101-10-0 |
|
Mercaptoacetic acid, sodium salt, 98%
| 367-51-1 |
|
Heptanophenone, 98+%
| 1671-75-6 |
|
Cyclobutanone, 98+%
| 1191-95-3 |
|
m-Tolualdehyde, 98%, stabilized with 0.1% Hydroquinone
| 620-23-5 |
|
D(+)-raffinose pentahydrate, 99+%
| 17629-30-0 |
|
Cyclohexanone 2,4-Dinitrophenylhydrazone, 99+%
| 1589-62-4 |
|
DL-Aspartic Acid
| 617-45-8 |
|
Diallyldisulfide, 70%, Remainder Mainly Diallyl Sulfide
| 2179-57-9 |
|
DL-2-Aminoadipic Acid Hydrate
| 542-32-5 |
|
3,3'-Diethylthiatricarbocyanine Iodide, Laser Grade
| 3071-70-3 |
|
Hexadecanedioic acid, 97%
| 505-54-4 |
|
Sodium tri-sec-butylborohydride, 1M solution in tetrahydrofuran
| 109-99-9 |
|
L-Phenylalanine Methyl Ester Hydrochloride, 98%
| 7524-50-7 |
|
3,3',4',5-Tetrachlorosalicylanilide, 99% (UV-Vis)
| 1154-59-2 |
|
p-Toluene Sulfonic Acid Monohydrate Cr 500g
| 6192-52-5 |
|
4-Chlorobenzoic acid, 99%
| 74-11-3 |
|
Chlortetracycline Hydrochloride, can be used as Secondary Standard
| 64-72-2 |
|
2-Bromopyridine-N-oxide hydrochloride, 97%
| 80866-91-7 |
|
2,6-Difluorophenylacetic Acid, 99% (Titr.)
| 85068-28-6 |
|
4-Aminobenzoic Acid, Sodium Salt, Hydrate
| 555-06-6 |
|
Neocuproine hydrochloride monohydrate, 99%
| 7296-20-0 |
|
9-Fluorenylmethyl chloroformate 97%
| 28920-43-6 |
|
Butadiene monoxide, 97%
| 930-22-3 |
|
L-(-)-Fucose, 97%
| 2438-80-4 |
|
Ethenesulfonyl fluoride, 97% (gc)
| 677-25-8 |
|
P-(2,4-Dinitroanilino)phenol Moist Solid Containing 30% Water
| 119-15-3 |
|
1,3-Dichlorobenzene, 98%
| 541-73-1 |
|
Bis-(acetonitrile)-palladium(ii)chloride, 99%
| 14592-56-4 |
|
Tri-tert-butyl borate, 98%
| 7397-43-5 |
|
D(-)-Glucose Diethyl Mercaptal
| 1941-52-2 |
|
Piperonylonitrile, 97%
| 4421-09-4 |
|
D(+)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt, 99%
| 14575-84-9 |
|
3-Iodoaniline, 98%
| 626-01-7 |
|
Citronellol, 95%
| 106-22-9 |
|
Methyl-5-doxyl-stearate, free radical
| 38568-24-0 |
|
N-Methyl-N-Phenylcarbamoyl Chloride, 99% (Titr.)
| 4285-42-1 |
|
Alpha, Alpha,2-Trichloro-6-Fluorotoluene, 99%
| 62476-62-4 |
|
3-(2-Maleimidoethyl-carbomoyl)-Proxyl, Free Radical
| 66641-27-8 |
|
(Methoxymethyl)-triphenylphosphonium chloride, 98%
| 4009-98-7 |
|
n-Methylisatoic anhydride, tech., 90+%
| 10328-92-4 |
|
(+)-Camptothecin, 98%
| 7689-03-4 |
|
Pentachlorophenol
| 87-86-5 |
|
Humic acid, sodium salt, tech
| 68131-04-4 |
|
N-Aminophthalimide, Tech., 90+%
| 1875-48-5 |
|
n-Acetyl-s-phenyl-l-cysteine methyl ester
| 19542-77-9 |
|
3-(4-Hydroxyphenyl)propionic acid, 98%
| 501-97-3 |
|
|