**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 626-01-7 |3-Iodoaniline | 98 | 210-922-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects.Light sensitive.The toxicological properties of
this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May form methemoglobin which in sufficient concentration
causes cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood).
Inhalation:
Causes respiratory tract irritation. This product contains nitrite
which may cause methemoglobinemia. Can produce delayed pulmonary
edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Minimize dust generation and accumulation. Do
not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Store protected from light. Do not breathe dust or fumes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 626-01-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: clear brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 145.0 - 146.0 deg C @ 15.00mm
Freezing/Melting Point: 25 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.8210g/cm3
Molecular Formula: C6H6IN
Molecular Weight: 219.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. May discolor on exposure to light.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat.
Incompatibilities with Other Materials:
Acid chlorides, acid anhydrides, acids, chloroformates, strong
oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen, hydrogen
iodide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 626-01-7: BY3750000
LD50/LC50:
Not available.
Carcinogenicity:
3-Iodoaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 626-01-7: No information available.
Canada
CAS# 626-01-7 is listed on Canada's NDSL List.
CAS# 626-01-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 626-01-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-Phenyl-4,5-Dichloro-6-Pyridazone, 99+%
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N,N-Dimethyl-P-Phenylenediamine Dihydrochloride 99%
| 536-46-9 |
|
1-Adamantanecarboxylic Acid, 99%
| 828-51-3 |
|
Dl-2-(M-Chlorophenoxy)Propionic Acid, 98%
| 101-10-0 |
|
Mercaptoacetic acid, sodium salt, 98%
| 367-51-1 |
|
Heptanophenone, 98+%
| 1671-75-6 |
|
Cyclobutanone, 98+%
| 1191-95-3 |
|
m-Tolualdehyde, 98%, stabilized with 0.1% Hydroquinone
| 620-23-5 |
|
D(+)-raffinose pentahydrate, 99+%
| 17629-30-0 |
|
Cyclohexanone 2,4-Dinitrophenylhydrazone, 99+%
| 1589-62-4 |
|
DL-Aspartic Acid
| 617-45-8 |
|
Diallyldisulfide, 70%, Remainder Mainly Diallyl Sulfide
| 2179-57-9 |
|
DL-2-Aminoadipic Acid Hydrate
| 542-32-5 |
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3,3'-Diethylthiatricarbocyanine Iodide, Laser Grade
| 3071-70-3 |
|
Hexadecanedioic acid, 97%
| 505-54-4 |
|
Sodium tri-sec-butylborohydride, 1M solution in tetrahydrofuran
| 109-99-9 |
|
L-Phenylalanine Methyl Ester Hydrochloride, 98%
| 7524-50-7 |
|
3,3',4',5-Tetrachlorosalicylanilide, 99% (UV-Vis)
| 1154-59-2 |
|
p-Toluene Sulfonic Acid Monohydrate Cr 500g
| 6192-52-5 |
|
4-Chlorobenzoic acid, 99%
| 74-11-3 |
|
Chlortetracycline Hydrochloride, can be used as Secondary Standard
| 64-72-2 |
|
2-Bromopyridine-N-oxide hydrochloride, 97%
| 80866-91-7 |
|
2,6-Difluorophenylacetic Acid, 99% (Titr.)
| 85068-28-6 |
|
4-Aminobenzoic Acid, Sodium Salt, Hydrate
| 555-06-6 |
|
Neocuproine hydrochloride monohydrate, 99%
| 7296-20-0 |
|
9-Fluorenylmethyl chloroformate 97%
| 28920-43-6 |
|
Butadiene monoxide, 97%
| 930-22-3 |
|
L-(-)-Fucose, 97%
| 2438-80-4 |
|
Ethenesulfonyl fluoride, 97% (gc)
| 677-25-8 |
|
P-(2,4-Dinitroanilino)phenol Moist Solid Containing 30% Water
| 119-15-3 |
|
1,3-Dichlorobenzene, 98%
| 541-73-1 |
|
Bis-(acetonitrile)-palladium(ii)chloride, 99%
| 14592-56-4 |
|
Tri-tert-butyl borate, 98%
| 7397-43-5 |
|
D(-)-Glucose Diethyl Mercaptal
| 1941-52-2 |
|
Piperonylonitrile, 97%
| 4421-09-4 |
|
D(+)-Alpha-Bromocamphor-Pi-Sulfonic Acid Ammonium Salt, 99%
| 14575-84-9 |
|
3-Iodoaniline, 98%
| 626-01-7 |
|
Citronellol, 95%
| 106-22-9 |
|
Methyl-5-doxyl-stearate, free radical
| 38568-24-0 |
|
N-Methyl-N-Phenylcarbamoyl Chloride, 99% (Titr.)
| 4285-42-1 |
|
Alpha, Alpha,2-Trichloro-6-Fluorotoluene, 99%
| 62476-62-4 |
|
3-(2-Maleimidoethyl-carbomoyl)-Proxyl, Free Radical
| 66641-27-8 |
|
(Methoxymethyl)-triphenylphosphonium chloride, 98%
| 4009-98-7 |
|
n-Methylisatoic anhydride, tech., 90+%
| 10328-92-4 |
|
(+)-Camptothecin, 98%
| 7689-03-4 |
|
Pentachlorophenol
| 87-86-5 |
|
Humic acid, sodium salt, tech
| 68131-04-4 |
|
N-Aminophthalimide, Tech., 90+%
| 1875-48-5 |
|
n-Acetyl-s-phenyl-l-cysteine methyl ester
| 19542-77-9 |
|
3-(4-Hydroxyphenyl)propionic acid, 98%
| 501-97-3 |
|
|