**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1546-79-8 |1-(Trifluoroacetyl)imidazole | 95% | 216-282-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Flammable liquid
and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Do not ingest or
inhale. Use only in a chemical fume hood. Discard contaminated shoes.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Keep away from
heat, sparks and flame.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Store in a dry area.
Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 1546-79-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 137 - 138 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 44 deg C ( 111.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.441
Molecular Formula: C5H3F3N2O
Molecular Weight: 164.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride
gas, fluoride fumes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1546-79-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(Trifluoroacetyl)imidazole -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1546-79-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1546-79-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1546-79-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/20/2004 Revision #3 Date: 12/02/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl 2-isocyano-3-methylpentanoate, 96%
| 0-01-1 |
|
4-Bromobenzonitrile, 98%
| 623-00-7 |
|
Methyl 3,4,5-Trihydroxybenzoate, 99 %
| 99-24-1 |
|
3-Hydroxy-2-nitropyridine, 97%
| 15128-82-2 |
|
Methyl 2-isocyano-3-methylbutyrate, 96%
| 40846-66-0 |
|
Methyl 3-isocyanopropionate, 96%
| 0-01-1 |
|
Methyl 2-isocyanopropionate, 96%
| 33115-74-1 |
|
1-Isocyano-3-isopropoxypropane, 96%
| 602262-07-7 |
|
1,1,3,3-Tetramethylbutyl isocyanide
| 14542-93-9 |
|
2,3-Dihydro-6-isocyano-1,4-benzodioxine, 95%
| 174092-82-1 |
|
Butyl Lactate, 99% (GC)
| 138-22-7 |
|
Dimethyl-d6 sulfate, 99+ atom % d
| 15199-43-6 |
|
Cyclopentyl isocyanide, 96%
| 68498-54-4 |
|
2-Cyclohexen-1-ylethyl isocyanide, 96%
| 172223-58-4 |
|
Diphenylmethyl isocyanide, 96%
| 3128-85-6 |
|
Methyl 2-isocyano-3-phenylpropionate, 96%
| 63157-14-2 |
|
alpha-Methylbenzyl isocyanide, 96%
| 17329-20-3 |
|
4-Fluorophenyl isocyanide, 95%
| 24075-34-1 |
|
3-Phenylpropyl isocyanide, 96%
| 111944-21-9 |
|
Phenylethyl isocyanide, 96%
| 59795-89-0 |
|
Benzo[a]pyrene, 96.5%
| 50-32-8 |
|
1-(Trifluoroacetyl)imidazole, 95%
| 1546-79-8 |
|
Ethylurea, 97%
| 625-52-5 |
|
1-Naphthalenemethanol, 98%
| 4780-79-4 |
|
Trimethylaluminum, 1,0M solution in heptane
| 75-24-1 |
|
Triisobutylaluminium, 1.1M solution in toluene
| 100-99-2 |
|
Ethylmagnesium chloride, 2.0M solution in THF
| 109-99-9 |
|
Triethylaluminium, 1,3M solution in heptane
| 97-93-8 |
|
Diethylzinc, 1,5M solution in toluene
| 108-88-3 |
|
Sodium thiophosphate hydrate
| 10489-48-2 |
|
cis-2,6-Dimethylmorpholine, 97%
| 6485-55-8 |
|
N-(2-Chloroethyl)pyrrolidine hydrochloride, 98%
| 7250-67-1 |
|
MP Alumina R, ICN material
| 1344-28-1 |
|
Tributylborane, 98%
| 122-56-5 |
|
L(-)-10-Camphorsulfonyl chloride
| 39262-22-1 |
|
Sodium cyanoborohydride, solution in THF
| 109-99-9 |
|
1-Phenyl-2-propanol, 99%
| 14898-87-4 |
|
N-(4-Dimethylamino-3,5-dinitrophenyl)maleimide
| 3475-74-9 |
|
8-Chloro-1-octanol, 98%
| 23144-52-7 |
|
1,10-Diamino-4,7-dioxadecane
| 2997-01-5 |
|
(4-Methoxybenzylidene)malonitrile, 98%
| 2826-26-8 |
|
1-(2-Hydroxyphenyl)piperazine, 98%
| 1011-17-2 |
|
5-Bromo-2-methylaniline, 98%
| 39478-78-9 |
|
1-Iodo-3-methylbutane, stabilized, 98%
| 541-28-6 |
|
2,4,6-Trivinylcyclotriboroxane-pyridine complex
| 92988-08-4 |
|
2-Methyl-5-nitroanisole, 99%
| 13120-77-9 |
|
Methyl 3-benzoylpropionate, 97%
| 25333-24-8 |
|
Ethyl 3-methylbenzoate, 98%
| 120-33-2 |
|
3,4-Dichlorostyrene, stabilized, 95%
| 2039-83-0 |
|
Dihydroquinine hydrobromide hydrate
| 0-01-1 |
|
|