**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1711-07-5 |3-Fluorobenzoyl chloride | 97 | 216-977-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.Lachrymator (substance
which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. If absorbed, may cause central nervous system
effects. May cause skin rash (in milder cases), and cold and clammy
skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause central nervous system depression. May cause
systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Aspiration may
lead to pulmonary edema. May cause systemic effects. Inhalation may
produce burning sensation, coughing, wheezing, laryngitis, shortness
of breath, headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
hydrolyzes material liberating acidic gas which in contact with metal
surfaces can generate flammable and/or explosive hydrogen gas.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation. Do not get
water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not get in eyes, on skin, or on clothing. Do not ingest or
inhale. Do not allow contact with water. Use only in a chemical fume
hood. Discard contaminated shoes. Keep from contact with moist air
and steam.
Storage:
Store in a tightly closed container. Corrosives area. Store
protected from moisture. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 1711-07-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 189 deg C @ 760.00mmHg
Freezing/Melting Point: -30 deg C
Autoignition Temperature: Not applicable.
Flash Point: 82 deg C ( 179.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: decomposes
Specific Gravity/Density: 1.3040g/cm3
Molecular Formula: C7H4ClFO
Molecular Weight: 158.56
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, contact with water, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, alcohols, moisture, water.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1711-07-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Fluorobenzoyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 1711-07-5: 1
Canada
CAS# 1711-07-5 is listed on Canada's NDSL List.
CAS# 1711-07-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1711-07-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-(-)-Arabitol, 99+%
| 7643-75-6 |
|
7-Amino-1,3-Naphthalenedisulfonic Acid Monopotassium Salt (Techn)
| 842-15-9 |
|
4-Chloro-4'-Methoxybutyrophenone, 98%
| 40877-19-8 |
|
Lanthionine, 98%
| 922-55-4 |
|
Boc-On, 99%
| 58632-95-4 |
|
Diisopropanolamine, 99% (Titr.)
| 110-97-4 |
|
Tetrahydrothiopyran-4-one, 99%
| 1072-72-6 |
|
1-Ethyl-4-Piperidone, 98%
| 3612-18-8 |
|
1-Chloro-3-Hydroxypropane, 98%
| 627-30-5 |
|
1,1-Diphenylethanol
| 599-67-7 |
|
4-Aminoquinaldine, 98%
| 6628-04-2 |
|
1,1-Dichlorobutane, 95% (GC)
| 541-33-3 |
|
2-Chloro-4-fluoroaniline
| 2106-02-7 |
|
alpha-Dimethylamino-3',4'-dihydroxyaceto- phenone, hydrochloride
| 16899-83-5 |
|
2,2-Dimethoxypropane, 98%
| 77-76-9 |
|
2,2-Dimethyl-5-(2-Tetrahydropyrrolylidene) -1,3-Dioxane-4,6-Dione,
| 0-00-1 |
|
2-(4-Methoxyphenyl)-4,4-Bis(Methylthio)-
| 0-01-1 |
|
Hydrazine Monohydrochloride, 98+%
| 2644-70-4 |
|
Poly(acrylamide), carboxyl modified, high carboxyl content
| |
|
Mordant yellow 12
| 6470-98-0 |
|
Bismuth Nitrate, 5-Hydrate, 98%
| 10035-06-0 |
|
Squalene, 99+% (GC)
| 111-02-4 |
|
O-Fluorocinnamic Acid, 98%
| 451-69-4 |
|
3-Cyanobenzoic Acid, 98%
| 1877-72-1 |
|
p-Toluenesulfonic acid, 12% in acetic acid
| 64-19-7 |
|
o-Anisidine, 99+%
| 90-04-0 |
|
(R)-(-)-2-Amino-1-Propanol
| 35320-23-1 |
|
3-Fluorobenzoyl chloride, 97%
| 1711-07-5 |
|
7-Methylquinoline (Pract)
| 612-60-2 |
|
Cis-1,2-Dihydro-3-Fluorocatechol, 95%
| 0-00-1 |
|
Trans-2-Hydroxy-1-Cyclohexyl-Amine Hydrochloride, 99%
| 5456-63-3 |
|
3-Bromo-1,1,1-trifluoroacetone
| 431-35-6 |
|
Titanium(IV)Ethoxide,33-35% TiO2
| 3087-36-3 |
|
n,n-Dimethylformamide dimethyl acetal, ca 97% (gc)
| 4637-24-5 |
|
Diisopropylcyanamide, 97+%
| 3085-76-5 |
|
2-Naphthylacetonitrile
| 7498-57-9 |
|
Methylaminoacetonitrile hydrochloride 98+%
| 25808-30-4 |
|
2,3-Dihydroxyquinoxaline, 99+%
| 15804-19-0 |
|
4,4'-Trimethylenedipiperidine, 97%
| 16898-52-5 |
|
3-Methyl-1-cyclohexene, 98%
| 591-48-0 |
|
4-Methylsulfonyl-3-nitrobenzoic acid, 99%
| |
|
2,2,5-Trimethyl-1,3-Dioxane-4,6-Dione, 98%
| 3709-18-0 |
|
(p-methoxyphenyl)acetonitrile, 97%
| 104-47-2 |
|
1,9-Dichlorononane, 99%
| 821-99-8 |
|
Samarium(III) Sulfate Octahydrate, 99.999%
| 13465-58-2 |
|
Pyrrole-2-Carboxaldehyde, 99%
| 1003-29-8 |
|
1,4-Butanediol Diglycidyl Ether, Tech., 50-60% (GC)
| 2425-79-8 |
|
n-Pentyl-triphenylphosphoniumbromide, 99+%
| 21406-61-1 |
|
Trans-4-Hydroxystilbene, 98%
| 6554-98-9 |
|
Ethyl Phenylglyoxylate, 95% (GC)
| 1603-79-8 |
|
|