**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2106-02-7 |2-Chloro-4-fluoroaniline | 99+ | 218-282-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. The toxicological properties of this
substance have not been fully investigated. May form methemoglobin
which in sufficient concentration causes cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. The
toxicological properties of this substance have not been fully
investigated. Inhalation of aniline causes anoxia due to the
formation of methemoglobin.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood. Treat
symptomatically and supportively.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2106-02-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: brown - orange-brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 192 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 98 deg C ( 208.40 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.2190g/cm3
Molecular Formula: C6H5ClFN
Molecular Weight: 145.56
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2106-02-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Chloro-4-fluoroaniline -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 2106-02-7: No information available.
Canada
CAS# 2106-02-7 is listed on Canada's NDSL List.
CAS# 2106-02-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2106-02-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/28/1998 Revision #5 Date: 10/19/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-(-)-Arabitol, 99+%
| 7643-75-6 |
|
7-Amino-1,3-Naphthalenedisulfonic Acid Monopotassium Salt (Techn)
| 842-15-9 |
|
4-Chloro-4'-Methoxybutyrophenone, 98%
| 40877-19-8 |
|
Lanthionine, 98%
| 922-55-4 |
|
Boc-On, 99%
| 58632-95-4 |
|
Diisopropanolamine, 99% (Titr.)
| 110-97-4 |
|
Tetrahydrothiopyran-4-one, 99%
| 1072-72-6 |
|
1-Ethyl-4-Piperidone, 98%
| 3612-18-8 |
|
1-Chloro-3-Hydroxypropane, 98%
| 627-30-5 |
|
1,1-Diphenylethanol
| 599-67-7 |
|
4-Aminoquinaldine, 98%
| 6628-04-2 |
|
1,1-Dichlorobutane, 95% (GC)
| 541-33-3 |
|
2-Chloro-4-fluoroaniline
| 2106-02-7 |
|
alpha-Dimethylamino-3',4'-dihydroxyaceto- phenone, hydrochloride
| 16899-83-5 |
|
2,2-Dimethoxypropane, 98%
| 77-76-9 |
|
2,2-Dimethyl-5-(2-Tetrahydropyrrolylidene) -1,3-Dioxane-4,6-Dione,
| 0-00-1 |
|
2-(4-Methoxyphenyl)-4,4-Bis(Methylthio)-
| 0-01-1 |
|
Hydrazine Monohydrochloride, 98+%
| 2644-70-4 |
|
Poly(acrylamide), carboxyl modified, high carboxyl content
| |
|
Mordant yellow 12
| 6470-98-0 |
|
Bismuth Nitrate, 5-Hydrate, 98%
| 10035-06-0 |
|
Squalene, 99+% (GC)
| 111-02-4 |
|
O-Fluorocinnamic Acid, 98%
| 451-69-4 |
|
3-Cyanobenzoic Acid, 98%
| 1877-72-1 |
|
p-Toluenesulfonic acid, 12% in acetic acid
| 64-19-7 |
|
o-Anisidine, 99+%
| 90-04-0 |
|
(R)-(-)-2-Amino-1-Propanol
| 35320-23-1 |
|
3-Fluorobenzoyl chloride, 97%
| 1711-07-5 |
|
7-Methylquinoline (Pract)
| 612-60-2 |
|
Cis-1,2-Dihydro-3-Fluorocatechol, 95%
| 0-00-1 |
|
Trans-2-Hydroxy-1-Cyclohexyl-Amine Hydrochloride, 99%
| 5456-63-3 |
|
3-Bromo-1,1,1-trifluoroacetone
| 431-35-6 |
|
Titanium(IV)Ethoxide,33-35% TiO2
| 3087-36-3 |
|
n,n-Dimethylformamide dimethyl acetal, ca 97% (gc)
| 4637-24-5 |
|
Diisopropylcyanamide, 97+%
| 3085-76-5 |
|
2-Naphthylacetonitrile
| 7498-57-9 |
|
Methylaminoacetonitrile hydrochloride 98+%
| 25808-30-4 |
|
2,3-Dihydroxyquinoxaline, 99+%
| 15804-19-0 |
|
4,4'-Trimethylenedipiperidine, 97%
| 16898-52-5 |
|
3-Methyl-1-cyclohexene, 98%
| 591-48-0 |
|
4-Methylsulfonyl-3-nitrobenzoic acid, 99%
| |
|
2,2,5-Trimethyl-1,3-Dioxane-4,6-Dione, 98%
| 3709-18-0 |
|
(p-methoxyphenyl)acetonitrile, 97%
| 104-47-2 |
|
1,9-Dichlorononane, 99%
| 821-99-8 |
|
Samarium(III) Sulfate Octahydrate, 99.999%
| 13465-58-2 |
|
Pyrrole-2-Carboxaldehyde, 99%
| 1003-29-8 |
|
1,4-Butanediol Diglycidyl Ether, Tech., 50-60% (GC)
| 2425-79-8 |
|
n-Pentyl-triphenylphosphoniumbromide, 99+%
| 21406-61-1 |
|
Trans-4-Hydroxystilbene, 98%
| 6554-98-9 |
|
Ethyl Phenylglyoxylate, 95% (GC)
| 1603-79-8 |
|
|