**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4637-24-5 |N,N-Dimethylformamide dimethyl acetal | 97.0 | 225-063-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes and skin.The toxicological
properties of this material have not been fully
investigated.Moisture sensitive.Flammable liquid.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Flammable liquid and vapor.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Will be easily ignited by heat,
sparks or flame. Vapors may form an explosive mixture with air.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. For large fires,
use water spray, fog or alcohol-resistant foam. Do NOT use straight
streams of water. For small fires, use carbon dioxide, dry chemical,
dry sand, or alcohol-resistant foam. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Ground and bond containers when transferring material.
Use spark-proof tools and explosion proof equipment. Avoid contact
with skin and eyes. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Do not store in direct sunlight. Keep container closed
when not in use. Store in a tightly closed container. Store in a
cool, dry, well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4637-24-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 102-104 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 43 deg F ( 6.11 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Hydrolyzed with water.
Specific Gravity/Density: 0.894
Molecular Formula: C5H13NO2
Molecular Weight: 119.0965
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, exposure
to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents and acids. Hydrolyzed with water.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of nitrogen, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4637-24-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N,N-Dimethylformamide dimethyl acetal -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 4637-24-5: 2
Canada
CAS# 4637-24-5 is listed on Canada's DSL List.
CAS# 4637-24-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4637-24-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/02/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-(-)-Arabitol, 99+%
| 7643-75-6 |
|
7-Amino-1,3-Naphthalenedisulfonic Acid Monopotassium Salt (Techn)
| 842-15-9 |
|
4-Chloro-4'-Methoxybutyrophenone, 98%
| 40877-19-8 |
|
Lanthionine, 98%
| 922-55-4 |
|
Boc-On, 99%
| 58632-95-4 |
|
Diisopropanolamine, 99% (Titr.)
| 110-97-4 |
|
Tetrahydrothiopyran-4-one, 99%
| 1072-72-6 |
|
1-Ethyl-4-Piperidone, 98%
| 3612-18-8 |
|
1-Chloro-3-Hydroxypropane, 98%
| 627-30-5 |
|
1,1-Diphenylethanol
| 599-67-7 |
|
4-Aminoquinaldine, 98%
| 6628-04-2 |
|
1,1-Dichlorobutane, 95% (GC)
| 541-33-3 |
|
2-Chloro-4-fluoroaniline
| 2106-02-7 |
|
alpha-Dimethylamino-3',4'-dihydroxyaceto- phenone, hydrochloride
| 16899-83-5 |
|
2,2-Dimethoxypropane, 98%
| 77-76-9 |
|
2,2-Dimethyl-5-(2-Tetrahydropyrrolylidene) -1,3-Dioxane-4,6-Dione,
| 0-00-1 |
|
2-(4-Methoxyphenyl)-4,4-Bis(Methylthio)-
| 0-01-1 |
|
Hydrazine Monohydrochloride, 98+%
| 2644-70-4 |
|
Poly(acrylamide), carboxyl modified, high carboxyl content
| |
|
Mordant yellow 12
| 6470-98-0 |
|
Bismuth Nitrate, 5-Hydrate, 98%
| 10035-06-0 |
|
Squalene, 99+% (GC)
| 111-02-4 |
|
O-Fluorocinnamic Acid, 98%
| 451-69-4 |
|
3-Cyanobenzoic Acid, 98%
| 1877-72-1 |
|
p-Toluenesulfonic acid, 12% in acetic acid
| 64-19-7 |
|
o-Anisidine, 99+%
| 90-04-0 |
|
(R)-(-)-2-Amino-1-Propanol
| 35320-23-1 |
|
3-Fluorobenzoyl chloride, 97%
| 1711-07-5 |
|
7-Methylquinoline (Pract)
| 612-60-2 |
|
Cis-1,2-Dihydro-3-Fluorocatechol, 95%
| 0-00-1 |
|
Trans-2-Hydroxy-1-Cyclohexyl-Amine Hydrochloride, 99%
| 5456-63-3 |
|
3-Bromo-1,1,1-trifluoroacetone
| 431-35-6 |
|
Titanium(IV)Ethoxide,33-35% TiO2
| 3087-36-3 |
|
n,n-Dimethylformamide dimethyl acetal, ca 97% (gc)
| 4637-24-5 |
|
Diisopropylcyanamide, 97+%
| 3085-76-5 |
|
2-Naphthylacetonitrile
| 7498-57-9 |
|
Methylaminoacetonitrile hydrochloride 98+%
| 25808-30-4 |
|
2,3-Dihydroxyquinoxaline, 99+%
| 15804-19-0 |
|
4,4'-Trimethylenedipiperidine, 97%
| 16898-52-5 |
|
3-Methyl-1-cyclohexene, 98%
| 591-48-0 |
|
4-Methylsulfonyl-3-nitrobenzoic acid, 99%
| |
|
2,2,5-Trimethyl-1,3-Dioxane-4,6-Dione, 98%
| 3709-18-0 |
|
(p-methoxyphenyl)acetonitrile, 97%
| 104-47-2 |
|
1,9-Dichlorononane, 99%
| 821-99-8 |
|
Samarium(III) Sulfate Octahydrate, 99.999%
| 13465-58-2 |
|
Pyrrole-2-Carboxaldehyde, 99%
| 1003-29-8 |
|
1,4-Butanediol Diglycidyl Ether, Tech., 50-60% (GC)
| 2425-79-8 |
|
n-Pentyl-triphenylphosphoniumbromide, 99+%
| 21406-61-1 |
|
Trans-4-Hydroxystilbene, 98%
| 6554-98-9 |
|
Ethyl Phenylglyoxylate, 95% (GC)
| 1603-79-8 |
|
|