**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 17420-30-3 |5-Nitroanthranilonitrile | 99 | 241-446-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
colored blood.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Inhalation of
aniline causes anoxia due to the formation of methemoglobin.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 17420-30-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: orange to brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 200.00 - 207.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H5N3O2
Molecular Weight: 163.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, oxidizers.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 17420-30-3: BX2500000
LD50/LC50:
CAS# 17420-30-3: Oral, mouse: LD50 = 6710 mg/kg; Oral, rat: LD50 =
3884 mg/kg.
Carcinogenicity:
5-Nitroanthranilonitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 17420-30-3: 2
Canada
CAS# 17420-30-3 is listed on Canada's NDSL List.
CAS# 17420-30-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 17420-30-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/04/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Ethylaniline, 98%
| 587-02-0 |
|
Hydroxypropyl-Betha-Cyclodextrin, 97+% (TLC), (on the dry substance)
| 94035-02-6 |
|
4-Chloro-3-nitrophenyl cyclopropyl ketone, 99+%
| 31545-26-3 |
|
Acetonitrile-D3, 100.0 Atom % D
| 2206-26-0 |
|
Bromopentafluorobenzene, 99%
| 344-04-7 |
|
Normal-Propyl Sulfoxide, Tech.
| 0-01-1 |
|
p-Toluenesulfinic Acid, Sodium Salt, 98+% Hydrate
| 824-79-3 |
|
2-Acetylbutyrolactone, 99+%
| 517-23-7 |
|
Formamidine Disulfide Dihydrochloride, 94%
| 14807-75-1 |
|
4,4'-Dichloro-alpha-methylbenzhydrol, 99%
| 80-06-8 |
|
3-O-Methylglucose, 99%
| 13224-94-7 |
|
Mithramycin, 90% (HPLC)
| 18378-89-7 |
|
Phosphorus pentasulfide, 98+%
| 1314-80-3 |
|
5-Hydroxymethyl-5-methyl-1,3-dioxane, 97%
| 1121-97-7 |
|
2,3,5-Triiodobenzoic Acid, 98%
| 88-82-4 |
|
n-Methylbutylamine, 98% (GC)
| 110-68-9 |
|
Quinacrine dihydrochloride dihydrate, 97+%
| 0-00-0 |
|
4-(Diethylamino)salicylaldehyde, 98%
| 17754-90-4 |
|
3,3'-Diazido-Diphenylsulfone, 97%
| 75742-13-1 |
|
n-Methylethylamine hydrochloride, 99%
| 624-60-2 |
|
Triethylenemelamine, 98%
| 51-18-3 |
|
Exo-2-Bromo-5,5-Ethylenedioxy-Bicyclo ??2.2.1??Heptane-Syn-7-Carboxylic
| 65877-98-7 |
|
3-(Trimethylsilyl)-1-propanol, 97%
| 2917-47-7 |
|
4-Phenylimidazole, 99%
| 670-95-1 |
|
Ethyl phenylpropiolate, 98%
| 2216-94-6 |
|
4-Amino-2-butanol, 98%
| 39884-48-5 |
|
Diethyl p-aminobenzylphosphonate
| 20074-79-7 |
|
1,2-Cyclohexanedicarboxylic anhydride, cis and trans mixture, 98%
| 85-42-7 |
|
1,3,6,8-Pyrenetetrasulfonic Acid Tetra- Sodium Salt, 99% (UV-VIS)
| 59572-10-0 |
|
Tetraphenylene, 98%
| 212-74-8 |
|
5-Nitroanthranilonitrile, 99%
| 17420-30-3 |
|
2,2-Dichlorooctadecanoic acid, 90%
| 56279-50-6 |
|
[1,3-Bis(Diphenylphosphino)Propane]Nickel (II) Chloride
| 15629-92-2 |
|
1-Chloro-2,5-Dibromobenzene, 99+%
| 3460-24-0 |
|
1,8-Diamino-3,6-dioxaoctane, 98%
| 929-59-9 |
|
2-(1-Naphthylmethyl)-2-imidazoline hydrochloride, 99%
| 550-99-2 |
|
Monomethylviologen, 99% (titr.)
| |
|
3-Phenoxypropionic acid, 99%
| 7170-38-9 |
|
1-Heptanol, 98%
| 111-70-6 |
|
2,6-Dihydroxyanthraquinone ,94%
| 84-60-6 |
|
Ethyl Eosin (Potassium Salt)
| 6359-04-2 |
|
2-Hydroxypropyl methacrylate, stabilized with 0.11% MEHQ
| 923-26-2 |
|
Triphenylphosphine
| 603-35-0 |
|
o-Fluorophenylacetonitrile, 97%
| 326-62-5 |
|
1-(Trimethylsilyl)-1-propyne, 98%
| 6224-91-5 |
|
Tetraethylammonium Chloride Hydrate, 99%
| 56-34-8 |
|
Chromium (III) Sulfide, 99%
| 12018-22-3 |
|
Alpha-2-Chloroisodurene, 98%
| 1585-16-6 |
|
2-Amino-5-Nitrothiazole, 97%
| 121-66-4 |
|
3-Methyl-1-(4-sulfophenyl)-2-pyrazolin-5- one (pract), 98% (titr.)
| 89-36-1 |
|
|