**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 603-35-0 |Triphenylphosphine | 99-100 | 210-036-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 20/22 43 50 53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. May cause sensitization by
skin contact. Very toxic to aquatic organisms. May cause long-term
adverse effects in the aquatic environment.Dangerous for the
environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause effects similar to those for
inhalation exposure.
Inhalation:
May cause respiratory tract irritation. May cause dyspnea (difficult
or labored breathing). May cause neurotoxic effects including
paresthesia. Harmful if inhaled.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Use
with adequate ventilation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 603-35-0:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: characteristic odor
pH: Not available.
Vapor Pressure: 5 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 377 deg C @ 760.00mm Hg
Freezing/Melting Point: 80 - 81 deg C
Autoignition Temperature: Not available.
Flash Point: 181 deg C ( 357.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: practically insoluble
Specific Gravity/Density:
Molecular Formula: C18H15P
Molecular Weight: 262.28
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Oxidizing agents, acids.
Hazardous Decomposition Products:
Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 603-35-0: SZ3500000
LD50/LC50:
CAS# 603-35-0: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = 1135
ppm/4H; Oral, mouse: LD50 = 1 gm/kg; Oral, rat: LD50 = 700 mg/kg;
Skin, rabbit: LD50 = >5 gm/kg.
Carcinogenicity:
Triphenylphosphine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fishtoxicity - Leuciscus idus LC50:>10000 mg/l/96h Daphniatoxicity
EC/LC50 (48h):0.6 mg/l Bacteriatoxicity EC/LC50(0.5h):> 10000 mg/l
log Pow: 4.5
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3278
Packing Group: II
IMO
Shipping Name: ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing Group: II
RID/ADR
Shipping Name: ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 43 May cause sensitization by skin contact.
R 50 Very toxic to aquatic organisms.
R 53 May cause long-term adverse effects in the
aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 603-35-0: 1
Canada
CAS# 603-35-0 is listed on Canada's DSL List.
CAS# 603-35-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 603-35-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 9/27/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Ethylaniline, 98%
| 587-02-0 |
|
Hydroxypropyl-Betha-Cyclodextrin, 97+% (TLC), (on the dry substance)
| 94035-02-6 |
|
4-Chloro-3-nitrophenyl cyclopropyl ketone, 99+%
| 31545-26-3 |
|
Acetonitrile-D3, 100.0 Atom % D
| 2206-26-0 |
|
Bromopentafluorobenzene, 99%
| 344-04-7 |
|
Normal-Propyl Sulfoxide, Tech.
| 0-01-1 |
|
p-Toluenesulfinic Acid, Sodium Salt, 98+% Hydrate
| 824-79-3 |
|
2-Acetylbutyrolactone, 99+%
| 517-23-7 |
|
Formamidine Disulfide Dihydrochloride, 94%
| 14807-75-1 |
|
4,4'-Dichloro-alpha-methylbenzhydrol, 99%
| 80-06-8 |
|
3-O-Methylglucose, 99%
| 13224-94-7 |
|
Mithramycin, 90% (HPLC)
| 18378-89-7 |
|
Phosphorus pentasulfide, 98+%
| 1314-80-3 |
|
5-Hydroxymethyl-5-methyl-1,3-dioxane, 97%
| 1121-97-7 |
|
2,3,5-Triiodobenzoic Acid, 98%
| 88-82-4 |
|
n-Methylbutylamine, 98% (GC)
| 110-68-9 |
|
Quinacrine dihydrochloride dihydrate, 97+%
| 0-00-0 |
|
4-(Diethylamino)salicylaldehyde, 98%
| 17754-90-4 |
|
3,3'-Diazido-Diphenylsulfone, 97%
| 75742-13-1 |
|
n-Methylethylamine hydrochloride, 99%
| 624-60-2 |
|
Triethylenemelamine, 98%
| 51-18-3 |
|
Exo-2-Bromo-5,5-Ethylenedioxy-Bicyclo ??2.2.1??Heptane-Syn-7-Carboxylic
| 65877-98-7 |
|
3-(Trimethylsilyl)-1-propanol, 97%
| 2917-47-7 |
|
4-Phenylimidazole, 99%
| 670-95-1 |
|
Ethyl phenylpropiolate, 98%
| 2216-94-6 |
|
4-Amino-2-butanol, 98%
| 39884-48-5 |
|
Diethyl p-aminobenzylphosphonate
| 20074-79-7 |
|
1,2-Cyclohexanedicarboxylic anhydride, cis and trans mixture, 98%
| 85-42-7 |
|
1,3,6,8-Pyrenetetrasulfonic Acid Tetra- Sodium Salt, 99% (UV-VIS)
| 59572-10-0 |
|
Tetraphenylene, 98%
| 212-74-8 |
|
5-Nitroanthranilonitrile, 99%
| 17420-30-3 |
|
2,2-Dichlorooctadecanoic acid, 90%
| 56279-50-6 |
|
[1,3-Bis(Diphenylphosphino)Propane]Nickel (II) Chloride
| 15629-92-2 |
|
1-Chloro-2,5-Dibromobenzene, 99+%
| 3460-24-0 |
|
1,8-Diamino-3,6-dioxaoctane, 98%
| 929-59-9 |
|
2-(1-Naphthylmethyl)-2-imidazoline hydrochloride, 99%
| 550-99-2 |
|
Monomethylviologen, 99% (titr.)
| |
|
3-Phenoxypropionic acid, 99%
| 7170-38-9 |
|
1-Heptanol, 98%
| 111-70-6 |
|
2,6-Dihydroxyanthraquinone ,94%
| 84-60-6 |
|
Ethyl Eosin (Potassium Salt)
| 6359-04-2 |
|
2-Hydroxypropyl methacrylate, stabilized with 0.11% MEHQ
| 923-26-2 |
|
Triphenylphosphine
| 603-35-0 |
|
o-Fluorophenylacetonitrile, 97%
| 326-62-5 |
|
1-(Trimethylsilyl)-1-propyne, 98%
| 6224-91-5 |
|
Tetraethylammonium Chloride Hydrate, 99%
| 56-34-8 |
|
Chromium (III) Sulfide, 99%
| 12018-22-3 |
|
Alpha-2-Chloroisodurene, 98%
| 1585-16-6 |
|
2-Amino-5-Nitrothiazole, 97%
| 121-66-4 |
|
3-Methyl-1-(4-sulfophenyl)-2-pyrazolin-5- one (pract), 98% (titr.)
| 89-36-1 |
|
|