**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 21679-31-2 |Chromium (III) acetylacetonate | 97 | 244-526-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
Prolonged or repeated inhalation of dusts may cause neurological
damage. Chronic inhalation of fine dusts may cause lung damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Use only in a chemical fume hood. Wash clothing
before reuse.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 21679-31-2:
United Kingdom, WEL - TWA: (listed as chromium (vi) compounds): 0
mg/m3 TWA (as Cr)
United Kingdom, WEL - STEL: (listed as chromium (vi) compounds):
mg/m3 STEL (as Cr)
France - VME: (listed as chromium (vi) compounds): 0.05 mg/m3 VME
Cr)
Germany: (listed as chromium (vi) compounds): 0.05 mg/m3 VME (as
Japan: (listed as chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr
0.01 mg/m3 OEL (certain compounds, as Cr)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: dull purple
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 340 deg C @ 760.00mm Hg
Freezing/Melting Point: 212 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble in petroleum ether
Specific Gravity/Density:
Molecular Formula: C15H21CrO6
Molecular Weight: 349.32
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, 2,4-pentanedione.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 21679-31-2: GB7575000
LD50/LC50:
CAS# 21679-31-2: Oral, rat: LD50 = 3360 mg/kg; Skin, rabbit: LD50 =
6350 mg/kg.
Carcinogenicity:
Chromium (III) acetylacetonate -
California: carcinogen, initial date 2/27/87 (listed as Chromium (VI)
NTP: Known carcinogen (listed as Chromium (VI) compounds).
IARC: Group 1 carcinogen (listed as Chromium (VI) compounds).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 21679-31-2: No information available.
Canada
CAS# 21679-31-2 is listed on Canada's DSL List.
CAS# 21679-31-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 21679-31-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/26/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Alpha, Alpha, Alpha-Trifluoro-P-Tolunitrile, 99%
| 455-18-5 |
|
Ethyl 4-methoxybenzoate, 98%
| 94-30-4 |
|
Ethanesulfonic Acid, 95% (Titr.)
| 594-45-6 |
|
3,6-Dihydroxybenzonorbornane, 96% (uv-vis)
| 15155-91-5 |
|
Ethyl 3-Aminobenzoate, 99+%
| 582-33-2 |
|
Chromium(III)acetylacetonate, 97%
| 21679-31-2 |
|
2-(2-(Methylamino)ethyl)pyridine dihydrochloride
| 5579-84-0 |
|
2-Amino-4-chlorobenzoic acid, 98%
| 89-77-0 |
|
N-(2-Hydroxyethyl)Pyrrolidine, 95%
| 2955-88-6 |
|
2,2,2-Trifluoroethyl P-Toluenesulfonate 98%
| 433-06-7 |
|
3,4-Diethoxybenzoic Acid, 99%
| 5409-31-4 |
|
1-Octadecanol 95%
| 112-92-5 |
|
DL-2,3-Diaminopropionic Acid Monohydrochloride, 99%
| 54897-59-5 |
|
5-Methyl-3-heptanone, 96% (gc)
| 541-85-5 |
|
1-Bromo-2,2-dimethoxypropane, 97%
| 126-38-5 |
|
Phenyl 4-Aminosalicylate, 99%
| 133-11-9 |
|
Tetraethyltin, 97%
| 597-64-8 |
|
1-Piperazinepropanol, 98%
| 5317-32-8 |
|
Diethyl Methylmalonate, 99%
| 609-08-5 |
|
2,2,6,6-Tetramethylcyclohexanone, 98%
| 1195-93-3 |
|
2-Nitroresorcinol
| 601-89-8 |
|
o-Methoxycinnamic acid, predominantly trans
| 6099-03-2 |
|
4-Aminobenzyl cyanide, 99%
| 3544-25-0 |
|
2,3-Dichloropyridine, 99%
| 2402-77-9 |
|
2-Amino-1-Phenylethanol, 98%
| 7568-93-6 |
|
Dipropylene Glycol, Tech., 99% (GC) Mixture of Isomeric Propylene
| 25265-71-8 |
|
Dibenzylamine, 98%
| 103-49-1 |
|
6-Chloro-2-picoline, 98%
| 18368-63-3 |
|
Diethyl Oxalacetate Sodium Salt (PRACT)
| 40876-98-0 |
|
Cyclobutanecarboxylic Acid, 98%
| 3721-95-7 |
|
2-(2-Ethoxyethoxy)ethyl Acetate, 99%
| 112-15-2 |
|
2-Mercapto-6-Nitrobenzothiazole, 96% (Titr.)
| 4845-58-3 |
|
Dihydrocytochalasin B
| 39156-67-7 |
|
3-Chloropropylamine Hydrochloride, 98%
| 6276-54-6 |
|
2-Amino-3-Methylbenzoic Acid, 98%
| 4389-45-1 |
|
m-Phenetidine, 96% (gc)
| 621-33-0 |
|
4,4-Diphenylsemicarbazide, 98%
| 603-51-0 |
|
3-Methyl-1-pentyn-3-ol, 99+%
| 77-75-8 |
|
(R)-(+)-N-Benzyl-alpha-methylbenzylamine, 98%
| 38235-77-7 |
|
1,7-Diaza-15-Crown-5, 99%
| 31249-95-3 |
|
l-(-)-Xylose, p.a.
| 609-06-3 |
|
4-Hydroxybenzylidenemalonodinitrile, 99%
| 3785-90-8 |
|
2,2'-Dithiodipyridine, 98%
| 2127-03-9 |
|
Mercury atomic absorption standard solution, 1 mg/ml Hg in 10% HNO3
| 7439-97-6 |
|
Lissamine Rhodamine B Sulfonyl Chloride, 99+% (UV-VIS)
| 62796-29-6 |
|
2,4-Diethyl-2,6-heptadienal, 97% Mixture of Isomers
| 85136-07-8 |
|
Dimethyldiselenide, 99+%
| 7101-31-7 |
|
2-Amino-4-Hydroxy-1H-Pteridine
| 2236-60-4 |
|
Alpha-Bromo-O-Tolunitrile, 98%
| 22115-41-9 |
|
(2-Chloroethyl)trimethylammonium chloride, 98%
| 999-81-5 |
|
|