**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3544-25-0 |4-Aminobenzyl cyanide | 99 | 222-587-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration. Chronic exposure
to cyanide solutions may lead to the development of a "cyanide" rash,
characterized by itching, and by macular, papular, and vesicular
eruptions, and may be accompanied by secondary infections. Exposure
to small amounts of cyanide compounds over long periods of time is
reported to cause loss of appetite, headache, weakness, nausea,
dizziness, and symptoms of irritation of the upper respiratory tract
and eyes.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustion generates toxic fumes. This material in
sufficient quantity and reduced particle size is capable of creating
a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Minimize dust generation
and accumulation. Avoid contact with eyes, skin, and clothing. Use
only with adequate ventilation. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3544-25-0:
United States OSHA: 5 mg/m3 TWA (listed under Cyanide anion).
Germany: (listed as cyanide anion): Skin absorber
Netherlands: (listed as cyanide anion): 5 mg/m3 MAC (as CN)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: yellow to brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 312 deg C @ 760 mm Hg
Freezing/Melting Point: 44-48 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble
Specific Gravity/Density:
Molecular Formula: C8H8N2
Molecular Weight: 132.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, and
strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, cyanides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3544-25-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Aminobenzyl cyanide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 0.36-0.40 mg/L; 5,15,30
minutes; Microtox test; 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRILES, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: Nitriles, Toxic, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: Nitriles, Toxic, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 3544-25-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3544-25-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3544-25-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/07/1999 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Alpha, Alpha, Alpha-Trifluoro-P-Tolunitrile, 99%
| 455-18-5 |
|
Ethyl 4-methoxybenzoate, 98%
| 94-30-4 |
|
Ethanesulfonic Acid, 95% (Titr.)
| 594-45-6 |
|
3,6-Dihydroxybenzonorbornane, 96% (uv-vis)
| 15155-91-5 |
|
Ethyl 3-Aminobenzoate, 99+%
| 582-33-2 |
|
Chromium(III)acetylacetonate, 97%
| 21679-31-2 |
|
2-(2-(Methylamino)ethyl)pyridine dihydrochloride
| 5579-84-0 |
|
2-Amino-4-chlorobenzoic acid, 98%
| 89-77-0 |
|
N-(2-Hydroxyethyl)Pyrrolidine, 95%
| 2955-88-6 |
|
2,2,2-Trifluoroethyl P-Toluenesulfonate 98%
| 433-06-7 |
|
3,4-Diethoxybenzoic Acid, 99%
| 5409-31-4 |
|
1-Octadecanol 95%
| 112-92-5 |
|
DL-2,3-Diaminopropionic Acid Monohydrochloride, 99%
| 54897-59-5 |
|
5-Methyl-3-heptanone, 96% (gc)
| 541-85-5 |
|
1-Bromo-2,2-dimethoxypropane, 97%
| 126-38-5 |
|
Phenyl 4-Aminosalicylate, 99%
| 133-11-9 |
|
Tetraethyltin, 97%
| 597-64-8 |
|
1-Piperazinepropanol, 98%
| 5317-32-8 |
|
Diethyl Methylmalonate, 99%
| 609-08-5 |
|
2,2,6,6-Tetramethylcyclohexanone, 98%
| 1195-93-3 |
|
2-Nitroresorcinol
| 601-89-8 |
|
o-Methoxycinnamic acid, predominantly trans
| 6099-03-2 |
|
4-Aminobenzyl cyanide, 99%
| 3544-25-0 |
|
2,3-Dichloropyridine, 99%
| 2402-77-9 |
|
2-Amino-1-Phenylethanol, 98%
| 7568-93-6 |
|
Dipropylene Glycol, Tech., 99% (GC) Mixture of Isomeric Propylene
| 25265-71-8 |
|
Dibenzylamine, 98%
| 103-49-1 |
|
6-Chloro-2-picoline, 98%
| 18368-63-3 |
|
Diethyl Oxalacetate Sodium Salt (PRACT)
| 40876-98-0 |
|
Cyclobutanecarboxylic Acid, 98%
| 3721-95-7 |
|
2-(2-Ethoxyethoxy)ethyl Acetate, 99%
| 112-15-2 |
|
2-Mercapto-6-Nitrobenzothiazole, 96% (Titr.)
| 4845-58-3 |
|
Dihydrocytochalasin B
| 39156-67-7 |
|
3-Chloropropylamine Hydrochloride, 98%
| 6276-54-6 |
|
2-Amino-3-Methylbenzoic Acid, 98%
| 4389-45-1 |
|
m-Phenetidine, 96% (gc)
| 621-33-0 |
|
4,4-Diphenylsemicarbazide, 98%
| 603-51-0 |
|
3-Methyl-1-pentyn-3-ol, 99+%
| 77-75-8 |
|
(R)-(+)-N-Benzyl-alpha-methylbenzylamine, 98%
| 38235-77-7 |
|
1,7-Diaza-15-Crown-5, 99%
| 31249-95-3 |
|
l-(-)-Xylose, p.a.
| 609-06-3 |
|
4-Hydroxybenzylidenemalonodinitrile, 99%
| 3785-90-8 |
|
2,2'-Dithiodipyridine, 98%
| 2127-03-9 |
|
Mercury atomic absorption standard solution, 1 mg/ml Hg in 10% HNO3
| 7439-97-6 |
|
Lissamine Rhodamine B Sulfonyl Chloride, 99+% (UV-VIS)
| 62796-29-6 |
|
2,4-Diethyl-2,6-heptadienal, 97% Mixture of Isomers
| 85136-07-8 |
|
Dimethyldiselenide, 99+%
| 7101-31-7 |
|
2-Amino-4-Hydroxy-1H-Pteridine
| 2236-60-4 |
|
Alpha-Bromo-O-Tolunitrile, 98%
| 22115-41-9 |
|
(2-Chloroethyl)trimethylammonium chloride, 98%
| 999-81-5 |
|
|