**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 22115-41-9 |Alpha-Bromo-O-Tolunitrile | 98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.Lachrymator (substance
which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Produces irritation, characterized by a burning
sensation, redness, tearing, inflammation, and possible corneal
injury. Lachrymator (substance which increases the flow of tears).
May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause cardiac disturbances. May cause central nervous
system effects. Metabolism may release cyanide, which may result in
headache, dizziness, weakness, collapse, unconsciousness and possible
death. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause cardiac abnormalities. May cause
systemic effects. May be metabolized to cyanide which in turns act by
inhibiting cytochrome oxidase impairing cellular respiration.
Chronic:
May be metabolized to cyanide which in turn acts by inhibiting
cytochrome oxidase impairing cellular respiration.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
May be partially metabolized to cyanide in the body.
Antidote:
Always have a cyanide antidote kit on hand when working with cyanide
compounds. Get medical advice to use.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Reacts with
water to form explosive hydrogen gas. Contact with metals may evolve
flammable hydrogen gas. Containers may explode if exposed to fire.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide. Do NOT get water inside containers. Cool containers with
flooding quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Do not allow contact with water. Discard
contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Corrosives area. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 22115-41-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: pale yellow to tan
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 67.00 - 72.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H6BrN
Molecular Weight: 196.05
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, bases, alcohols, amines, steel, moisture.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen bromide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 22115-41-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Alpha-Bromo-O-Tolunitrile -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 22115-41-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 22115-41-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 22115-41-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Alpha, Alpha, Alpha-Trifluoro-P-Tolunitrile, 99%
| 455-18-5 |
|
Ethyl 4-methoxybenzoate, 98%
| 94-30-4 |
|
Ethanesulfonic Acid, 95% (Titr.)
| 594-45-6 |
|
3,6-Dihydroxybenzonorbornane, 96% (uv-vis)
| 15155-91-5 |
|
Ethyl 3-Aminobenzoate, 99+%
| 582-33-2 |
|
Chromium(III)acetylacetonate, 97%
| 21679-31-2 |
|
2-(2-(Methylamino)ethyl)pyridine dihydrochloride
| 5579-84-0 |
|
2-Amino-4-chlorobenzoic acid, 98%
| 89-77-0 |
|
N-(2-Hydroxyethyl)Pyrrolidine, 95%
| 2955-88-6 |
|
2,2,2-Trifluoroethyl P-Toluenesulfonate 98%
| 433-06-7 |
|
3,4-Diethoxybenzoic Acid, 99%
| 5409-31-4 |
|
1-Octadecanol 95%
| 112-92-5 |
|
DL-2,3-Diaminopropionic Acid Monohydrochloride, 99%
| 54897-59-5 |
|
5-Methyl-3-heptanone, 96% (gc)
| 541-85-5 |
|
1-Bromo-2,2-dimethoxypropane, 97%
| 126-38-5 |
|
Phenyl 4-Aminosalicylate, 99%
| 133-11-9 |
|
Tetraethyltin, 97%
| 597-64-8 |
|
1-Piperazinepropanol, 98%
| 5317-32-8 |
|
Diethyl Methylmalonate, 99%
| 609-08-5 |
|
2,2,6,6-Tetramethylcyclohexanone, 98%
| 1195-93-3 |
|
2-Nitroresorcinol
| 601-89-8 |
|
o-Methoxycinnamic acid, predominantly trans
| 6099-03-2 |
|
4-Aminobenzyl cyanide, 99%
| 3544-25-0 |
|
2,3-Dichloropyridine, 99%
| 2402-77-9 |
|
2-Amino-1-Phenylethanol, 98%
| 7568-93-6 |
|
Dipropylene Glycol, Tech., 99% (GC) Mixture of Isomeric Propylene
| 25265-71-8 |
|
Dibenzylamine, 98%
| 103-49-1 |
|
6-Chloro-2-picoline, 98%
| 18368-63-3 |
|
Diethyl Oxalacetate Sodium Salt (PRACT)
| 40876-98-0 |
|
Cyclobutanecarboxylic Acid, 98%
| 3721-95-7 |
|
2-(2-Ethoxyethoxy)ethyl Acetate, 99%
| 112-15-2 |
|
2-Mercapto-6-Nitrobenzothiazole, 96% (Titr.)
| 4845-58-3 |
|
Dihydrocytochalasin B
| 39156-67-7 |
|
3-Chloropropylamine Hydrochloride, 98%
| 6276-54-6 |
|
2-Amino-3-Methylbenzoic Acid, 98%
| 4389-45-1 |
|
m-Phenetidine, 96% (gc)
| 621-33-0 |
|
4,4-Diphenylsemicarbazide, 98%
| 603-51-0 |
|
3-Methyl-1-pentyn-3-ol, 99+%
| 77-75-8 |
|
(R)-(+)-N-Benzyl-alpha-methylbenzylamine, 98%
| 38235-77-7 |
|
1,7-Diaza-15-Crown-5, 99%
| 31249-95-3 |
|
l-(-)-Xylose, p.a.
| 609-06-3 |
|
4-Hydroxybenzylidenemalonodinitrile, 99%
| 3785-90-8 |
|
2,2'-Dithiodipyridine, 98%
| 2127-03-9 |
|
Mercury atomic absorption standard solution, 1 mg/ml Hg in 10% HNO3
| 7439-97-6 |
|
Lissamine Rhodamine B Sulfonyl Chloride, 99+% (UV-VIS)
| 62796-29-6 |
|
2,4-Diethyl-2,6-heptadienal, 97% Mixture of Isomers
| 85136-07-8 |
|
Dimethyldiselenide, 99+%
| 7101-31-7 |
|
2-Amino-4-Hydroxy-1H-Pteridine
| 2236-60-4 |
|
Alpha-Bromo-O-Tolunitrile, 98%
| 22115-41-9 |
|
(2-Chloroethyl)trimethylammonium chloride, 98%
| 999-81-5 |
|
|