**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 456-19-9 |4-Fluorobenzal chloride | 98 | 207-258-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Lachrymator (substance which increases the
flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects. Inhalation at high
concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Do not ingest or inhale. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 456-19-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear dark green
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 81.0 - 83.0 deg C @ 15.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 90 deg C ( 194.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.3320g/cm3
Molecular Formula: C7H5Cl2F
Molecular Weight: 179.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 456-19-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Fluorobenzal chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 456-19-9: 1
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 456-19-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 456-19-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Dimethylaminopropiophenone Hydrochloride, 99%
| 879-72-1 |
|
Polycarbonate resin, approximate m.w. 64.000,pellets
| 24936-68-3 |
|
Serotonin Hydrochloride Hydrate, 99%
| 153-98-0 |
|
Triphenylmethyl bromide, 98%
| 596-43-0 |
|
2-Amino-5-picoline, 99%
| 1603-41-4 |
|
Lead subacetate
| 1335-32-6 |
|
5,6-Diamino-2,4-dihydroxypyrimidine hemisulfate, hydrate, 98%
| 63981-35-1 |
|
Trans-2-Heptene, 97%
| 14686-13-6 |
|
Lead Sulfide
| 1314-87-0 |
|
Uric acid, 99+%
| 69-93-2 |
|
Tetrabutylammonium Perchlorate, 99% (Titr.)
| 1923-70-2 |
|
Cis-1,2,3,6-Tetrahydrophthalimide, 96%
| 27813-21-4 |
|
Lead Tetraoxide
| 1314-41-6 |
|
trans-2-Methylcyclohexanol, 97%
| 7443-52-9 |
|
Lecithin
| 8002-43-5 |
|
2-Pyridinealdoxime methochloride, 99%
| 51-15-0 |
|
4-Fluorobenzal chloride, 98%
| 456-19-9 |
|
Dimethyl cyanamide, 97+%
| 1467-79-4 |
|
d-Camphoroquinone
| 2767-84-2 |
|
Light Green SF, Yellowish
| 5141-20-8 |
|
Petroleum ether (EMD)
| 8032-32-4 |
|
2-Ethylanisole, 99%
| 14804-32-1 |
|
4-(2-Keto-1-benzimidazolinyl)piperidine, 97%
| 20662-53-7 |
|
n-Methoxymethylaza-12-crown-4, 95%
| |
|
1-Hexyne, 99%
| 693-02-7 |
|
Ethyl 1-methylpipecolinate, 97%
| 30727-18-5 |
|
Lithium
| 7439-93-2 |
|
4-Chloro-3,5-Dinitrobenzoic Acid, 99%
| 118-97-8 |
|
1,5-Hexadiene, Tech. 80+%
| 592-42-7 |
|
Lithium Bromide
| 7550-35-8 |
|
Lithium Carbonate
| 554-13-2 |
|
Myristanilide, 96% (gc)
| 622-56-0 |
|
Lithium chloride
| 7447-41-8 |
|
2,6-Di-Tert.-Butyl-P-Benzoquinone, 98%
| 719-22-2 |
|
2-Methyl-3-nitroaniline 97%
| 603-83-8 |
|
9-Amino-1,2,3,4-tetrahydroacridine hydrochloride hydrate, 99+% (tlc)
| 321-64-2 |
|
Lithium dodecyl sulfate
| 2044-56-6 |
|
Lithium Fluoride
| 7789-24-4 |
|
Silver Difluoride, 99%
| 7783-95-1 |
|
Lithium Hydroxide Anhydrous
| 554-13-2 |
|
Lithium Hydroxide Monohydrate
| 1310-66-3 |
|
Lithium nitrate
| 7790-69-4 |
|
(r)-(+)-2-Phenyl-1-propanol, 99+%
| 1572-95-8 |
|
2S,4s-(+)-pentanediol, 99%
| 72345-23-4 |
|
Alpha, Alpha, Alpha-Trifluoro-M-Cresol 98+%
| 98-16-8 |
|
Thallic Trifluoroacetate
| 23586-53-0 |
|
2-(4-Chloro-3-Nitrobenzoyl)benzoic Acid, 98%
| 85-54-1 |
|
2-AMINO-QUINOLINE
| 580-22-3 |
|
4-Bromobutyl acetate, 98%
| 18991-98-5 |
|
4-Morpholinoacetophenone, 99%
| 39910-98-0 |
|
|