**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 554-13-2 |Lithium carbonate | 3 | 209-062-5 |
|----------------|--------------------------------------|----------|-----------|
| 1310-65-2 |LITHIUM HYDROXIDE | >96 | 215-183-4 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 20/22 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Causes severe
burns.Hygroscopic (absorbs moisture from the air).Corrosive.Air
sensitive.
Potential Health Effects
Eye:
Causes severe eye burns. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes severe burns with delayed tissue destruction.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. May cause
kidney damage. May cause corrosion and permanent tissue destruction
of the esophagus and digestive tract. May cause tremors and
convulsions. May cause nausea and vomiting. May cause burning
sensations, coughing, wheezing, laryngitis, shortness of breath and
headache.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema. May
cause burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea, and vomiting.
Chronic:
Repeated exposure may cause central nervous system damage. Effects
may be delayed. Chronic ingestion may cause dizziness, ringing in the
ears, visual disturbances, tremors, and mental confusion. Prolonged
absorption may affect electrolyte balance and impair kidney function.
Dehydration, weight loss, skin effects, and thyroid disturbances have
been reported. May cause kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Wear
appropriate protective clothing to prevent contact with skin and
eyes. Wear a self-contained breathing apparatus (SCBA) to prevent
contact with thermal decomposition products.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Minimize
dust generation and accumulation. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Do not ingest or inhale.
Use with adequate ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Keep under a nitrogen
blanket. Corrosives area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 554-13-2:
CAS# 1310-65-2:
United Kingdom, WEL - STEL: 1 mg/m3 STEL
Japan: 1 mg/m3 OEL
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: colorless to white
Odor: none reported
pH: 14 (1N sol.)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 1695 deg F
Freezing/Melting Point: 842 deg F
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 1695 deg F
Solubility in water: Soluble in water.
Specific Gravity/Density: 2.5 (water=1)
Molecular Formula: LiOH
Molecular Weight: 23.9474
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Absorbs carbon dioxide from the air. Air sensitive. Hygroscopic:
absorbs moisture or water from the air.
Conditions to Avoid:
Dust generation, exposure to moist air or water, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, aluminum, carbon dioxide,
zinc, moisture.
Hazardous Decomposition Products:
Oxides of lithium.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 554-13-2: OJ5800000
CAS# 1310-65-2: OJ6307070
LD50/LC50:
CAS# 554-13-2: Oral, mouse: LD50 = 531 mg/kg; Oral, mouse: LD50 =
531 mg/kg; Oral, rabbit: LD50 = 404 mg/kg; Oral, rat: LD50 = 525
mg/kg; Oral, rat: LD50 = 553 mg/kg.
CAS# 1310-65-2: Inhalation, rat: LC50 = 960 mg/m3/4H; Oral, mouse:
LD50 = 363 mg/kg; Oral, rat: LD50 = 210 mg/kg.
Carcinogenicity:
Lithium carbonate -
Not listed by ACGIH, IARC, or NTP.
LITHIUM HYDROXIDE -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: LITHIUM HYDROXIDE,SOLID
Hazard Class: 8
UN Number: 2680
Packing Group: II
IMO
Shipping Name: LITHIUM HYDROXIDE,SOLID
Hazard Class: 8
UN Number: 2680
Packing Group: II
RID/ADR
Shipping Name: LITHIUM HYDROXIDE,SOLID
Hazard Class:
UN Number: 2680
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 554-13-2: 1
CAS# 1310-65-2: No information available.
Canada
CAS# 554-13-2 is listed on Canada's DSL List.
CAS# 1310-65-2 is listed on Canada's DSL List.
CAS# 554-13-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 1310-65-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 554-13-2 is listed on the TSCA inventory.
CAS# 1310-65-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #6 Date: 9/22/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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