**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 603-83-8 |2-Methyl-3-nitroaniline | 97% | 210-059-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/24/25 33 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects. Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. Absorption into the body may cause
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood).
Ingestion:
Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown colored blood. Causes digestive tract irritation.
Inhalation:
May cause irritation of the mucous membranes.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. May polymerize explosively when involved in a fire.
Combustible material; may burn but does not ignite readily.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Remove
all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 603-83-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 305 deg C @ 760.00mmHg
Freezing/Melting Point: 88.00 - 90.00 deg C
Autoignition Temperature: Not available.
Flash Point: 305 deg C ( 581.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 305 deg C
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula: C7H8N2O2
Molecular Weight: 152.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, acids.
Incompatibilities with Other Materials:
Acids - acid chlorides - acid anhydrides - chloroformates - strong
oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 603-83-8: XU8200000
LD50/LC50:
Not available.
Carcinogenicity:
2-Methyl-3-nitroaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITROTOLUIDINES (MONO)
Hazard Class: 6.1
UN Number: 2660
Packing Group: III
IMO
Shipping Name: NITROTOLUIDINES
Hazard Class: 6.1
UN Number: 2660
Packing Group: III
RID/ADR
Shipping Name: NITROTOLUIDINES (MONO)
Hazard Class: 6.1
UN Number: 2660
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 603-83-8: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 603-83-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 603-83-8 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/27/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Dimethylaminopropiophenone Hydrochloride, 99%
| 879-72-1 |
|
Polycarbonate resin, approximate m.w. 64.000,pellets
| 24936-68-3 |
|
Serotonin Hydrochloride Hydrate, 99%
| 153-98-0 |
|
Triphenylmethyl bromide, 98%
| 596-43-0 |
|
2-Amino-5-picoline, 99%
| 1603-41-4 |
|
Lead subacetate
| 1335-32-6 |
|
5,6-Diamino-2,4-dihydroxypyrimidine hemisulfate, hydrate, 98%
| 63981-35-1 |
|
Trans-2-Heptene, 97%
| 14686-13-6 |
|
Lead Sulfide
| 1314-87-0 |
|
Uric acid, 99+%
| 69-93-2 |
|
Tetrabutylammonium Perchlorate, 99% (Titr.)
| 1923-70-2 |
|
Cis-1,2,3,6-Tetrahydrophthalimide, 96%
| 27813-21-4 |
|
Lead Tetraoxide
| 1314-41-6 |
|
trans-2-Methylcyclohexanol, 97%
| 7443-52-9 |
|
Lecithin
| 8002-43-5 |
|
2-Pyridinealdoxime methochloride, 99%
| 51-15-0 |
|
4-Fluorobenzal chloride, 98%
| 456-19-9 |
|
Dimethyl cyanamide, 97+%
| 1467-79-4 |
|
d-Camphoroquinone
| 2767-84-2 |
|
Light Green SF, Yellowish
| 5141-20-8 |
|
Petroleum ether (EMD)
| 8032-32-4 |
|
2-Ethylanisole, 99%
| 14804-32-1 |
|
4-(2-Keto-1-benzimidazolinyl)piperidine, 97%
| 20662-53-7 |
|
n-Methoxymethylaza-12-crown-4, 95%
| |
|
1-Hexyne, 99%
| 693-02-7 |
|
Ethyl 1-methylpipecolinate, 97%
| 30727-18-5 |
|
Lithium
| 7439-93-2 |
|
4-Chloro-3,5-Dinitrobenzoic Acid, 99%
| 118-97-8 |
|
1,5-Hexadiene, Tech. 80+%
| 592-42-7 |
|
Lithium Bromide
| 7550-35-8 |
|
Lithium Carbonate
| 554-13-2 |
|
Myristanilide, 96% (gc)
| 622-56-0 |
|
Lithium chloride
| 7447-41-8 |
|
2,6-Di-Tert.-Butyl-P-Benzoquinone, 98%
| 719-22-2 |
|
2-Methyl-3-nitroaniline 97%
| 603-83-8 |
|
9-Amino-1,2,3,4-tetrahydroacridine hydrochloride hydrate, 99+% (tlc)
| 321-64-2 |
|
Lithium dodecyl sulfate
| 2044-56-6 |
|
Lithium Fluoride
| 7789-24-4 |
|
Silver Difluoride, 99%
| 7783-95-1 |
|
Lithium Hydroxide Anhydrous
| 554-13-2 |
|
Lithium Hydroxide Monohydrate
| 1310-66-3 |
|
Lithium nitrate
| 7790-69-4 |
|
(r)-(+)-2-Phenyl-1-propanol, 99+%
| 1572-95-8 |
|
2S,4s-(+)-pentanediol, 99%
| 72345-23-4 |
|
Alpha, Alpha, Alpha-Trifluoro-M-Cresol 98+%
| 98-16-8 |
|
Thallic Trifluoroacetate
| 23586-53-0 |
|
2-(4-Chloro-3-Nitrobenzoyl)benzoic Acid, 98%
| 85-54-1 |
|
2-AMINO-QUINOLINE
| 580-22-3 |
|
4-Bromobutyl acetate, 98%
| 18991-98-5 |
|
4-Morpholinoacetophenone, 99%
| 39910-98-0 |
|
|