**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 554-13-2 |Lithium carbonate | 98.0 | 209-062-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic exposure to lithium salts may cause drowsiness, visual
abnormalities, weakness, ringing in the ears, and muscle tremors.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 554-13-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 1310 deg C
Freezing/Melting Point: 618 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: 1310 deg C
Solubility in water: 1.5% in water.
Specific Gravity/Density: 2.1 (water=1)
Molecular Formula: Li2CO3
Molecular Weight: 73.8802
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, fluorine.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of lithium.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 554-13-2: OJ5800000
LD50/LC50:
CAS# 554-13-2: Oral, mouse: LD50 = 531 mg/kg; Oral, mouse: LD50 =
531 mg/kg; Oral, rabbit: LD50 = 404 mg/kg; Oral, rat: LD50 = 525
mg/kg; Oral, rat: LD50 = 553 mg/kg.
Carcinogenicity:
Lithium carbonate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 554-13-2: 1
Canada
CAS# 554-13-2 is listed on Canada's DSL List.
CAS# 554-13-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 554-13-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/24/1998 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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| 879-72-1 |
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Polycarbonate resin, approximate m.w. 64.000,pellets
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| 153-98-0 |
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| 1603-41-4 |
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Lead subacetate
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5,6-Diamino-2,4-dihydroxypyrimidine hemisulfate, hydrate, 98%
| 63981-35-1 |
|
Trans-2-Heptene, 97%
| 14686-13-6 |
|
Lead Sulfide
| 1314-87-0 |
|
Uric acid, 99+%
| 69-93-2 |
|
Tetrabutylammonium Perchlorate, 99% (Titr.)
| 1923-70-2 |
|
Cis-1,2,3,6-Tetrahydrophthalimide, 96%
| 27813-21-4 |
|
Lead Tetraoxide
| 1314-41-6 |
|
trans-2-Methylcyclohexanol, 97%
| 7443-52-9 |
|
Lecithin
| 8002-43-5 |
|
2-Pyridinealdoxime methochloride, 99%
| 51-15-0 |
|
4-Fluorobenzal chloride, 98%
| 456-19-9 |
|
Dimethyl cyanamide, 97+%
| 1467-79-4 |
|
d-Camphoroquinone
| 2767-84-2 |
|
Light Green SF, Yellowish
| 5141-20-8 |
|
Petroleum ether (EMD)
| 8032-32-4 |
|
2-Ethylanisole, 99%
| 14804-32-1 |
|
4-(2-Keto-1-benzimidazolinyl)piperidine, 97%
| 20662-53-7 |
|
n-Methoxymethylaza-12-crown-4, 95%
| |
|
1-Hexyne, 99%
| 693-02-7 |
|
Ethyl 1-methylpipecolinate, 97%
| 30727-18-5 |
|
Lithium
| 7439-93-2 |
|
4-Chloro-3,5-Dinitrobenzoic Acid, 99%
| 118-97-8 |
|
1,5-Hexadiene, Tech. 80+%
| 592-42-7 |
|
Lithium Bromide
| 7550-35-8 |
|
Lithium Carbonate
| 554-13-2 |
|
Myristanilide, 96% (gc)
| 622-56-0 |
|
Lithium chloride
| 7447-41-8 |
|
2,6-Di-Tert.-Butyl-P-Benzoquinone, 98%
| 719-22-2 |
|
2-Methyl-3-nitroaniline 97%
| 603-83-8 |
|
9-Amino-1,2,3,4-tetrahydroacridine hydrochloride hydrate, 99+% (tlc)
| 321-64-2 |
|
Lithium dodecyl sulfate
| 2044-56-6 |
|
Lithium Fluoride
| 7789-24-4 |
|
Silver Difluoride, 99%
| 7783-95-1 |
|
Lithium Hydroxide Anhydrous
| 554-13-2 |
|
Lithium Hydroxide Monohydrate
| 1310-66-3 |
|
Lithium nitrate
| 7790-69-4 |
|
(r)-(+)-2-Phenyl-1-propanol, 99+%
| 1572-95-8 |
|
2S,4s-(+)-pentanediol, 99%
| 72345-23-4 |
|
Alpha, Alpha, Alpha-Trifluoro-M-Cresol 98+%
| 98-16-8 |
|
Thallic Trifluoroacetate
| 23586-53-0 |
|
2-(4-Chloro-3-Nitrobenzoyl)benzoic Acid, 98%
| 85-54-1 |
|
2-AMINO-QUINOLINE
| 580-22-3 |
|
4-Bromobutyl acetate, 98%
| 18991-98-5 |
|
4-Morpholinoacetophenone, 99%
| 39910-98-0 |
|
|