**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 5503-41-3 |Rhodium Acetate Dimer, Anhydrous,ca 46| ca. 54.0 | 226-843-6 |
| |% Rh | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin.The toxicological properties of this
material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation and possible burns. May cause chemical
conjunctivitis.
Skin:
Causes skin irritation and possible burns.
Ingestion:
May cause cardiac disturbances. The toxicological properties of this
substance have not been fully investigated. May cause central nervous
system effects. May cause irritation of the digestive tract and
possible burns.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Central nervous
system effects, which appear to predominate in acute cases are
characterized by abnormal fatigue, memory difficulties and
dizziness.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of soap and
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If breathing is
difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated. Non-combustible, substance itself does not burn but may
decompose upon heating to produce irritating, corrosive and/or toxic
fumes. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid
contact with eyes, skin, and clothing. Keep container tightly
closed. Avoid ingestion and inhalation. Use only in a chemical fume
hood. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use only under a
chemical fume hood.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Appearance: green to dark green - green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 88-90C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: .888
Molecular Formula: (CH3Co2)Rh2
Molecular Weight: 441.98
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, rhodium/rhodium oxides.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 5503-41-3: AJ3880000
LD50/LC50:
Not available.
Carcinogenicity:
Rhodium Acetate Dimer, Anhydrous,ca 46% Rh -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as **
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Dangerous Goods Code: 8(65C)
UN Number: 1759
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 15 Keep away from heat.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 5503-41-3: No information available.
United Kingdom Occupational Exposure Limits
CAS# 5503-41-3: OES-United Kingdom, TWA (listed as ** undefined
**): metal fume and dust, as Rh: 0.1 mg/m3 TWA
CAS# 5503-41-3: OES-United Kingdom, STEL (listed as ** undefined
**): metal fume and dust, as Rh: 0.3 mg/m3 STEL
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5503-41-3 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 5503-41-3: OEL-AUSTRALIA:TWA 1 mg(Rh)/m3
OEL-BELGIUM:TWA 1 mg(Rh)/m3
OEL-DENMARK:TWA 0.001 mg(Rh)/m3 JANUARY 1993
OEL-DENMARK:TWA 0.1 mg(Rh)/m3
OEL-FINLAND:TWA 0.001 mg(Rh)/m3;Skin JANUARY 199
OEL-FINLAND:TWA 0.1 mg(Rh)/m3
OEL-FRANCE:TWA 1 mg(Rh)/m3
OEL-THE NETHERLANDS:TWA 0.001 mg(Rh)/m3 JANUARY 1993
OEL-THE NETHERLANDS:TWA 0.1 mg(Rh)/m3
OEL-THE PHILIPPINES:TWA 0.1 mg(Rh)/m3
OEL-SWITZERLAND:TWA 0.001 mg(Rh)/m3 JANUARY 1993
OEL-SWITZERLAND:TWA 0.1 mg(Rh)/m3
OEL-UNITED KINGDOM:TWA 0.001 mg(Rh)/m3;STEL 0.003 mg(Rh)/m3
OEL-UNITED KINGDOM:TWA 0.1 mg(Rh)/m3;STEL 0.3 mg(Rh)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 5503-41-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/23/1999 Revision #3 Date: 8/29/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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(-)-8-Phenylmenthol, 98%
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3,3,5-Trimethylcyclohexanol,98% Mixture of Cis and Trans
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L(-)-Phenylephrine Hydrochloride, 99%
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(S)-(+)-2-Chloropropan-1-ol, 96%
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Dimethylthexylsilyl Chloride
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DL-Alanine, 99%
| 302-72-7 |
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(-)-Menthyl lactate, 98%
| 59259-38-0 |
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1,1-Diphenyl-2-Picrylhydrazine
| 1707-75-1 |
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9-Nitroanthracene, 97%
| 602-60-8 |
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Cis-Stilbene, 97%
| 645-49-8 |
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2-Fluorobenzoyl Chloride, 97%
| 393-52-2 |
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Alizarin Yellow R Sodium Salt, 96% (UV-VIS)
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Phenyl carbamate, 97%
| 622-46-8 |
|
m-Methoxybenzyl chloride, 97%
| 824-98-6 |
|
Methyl Violet 2B, Indicator Grade
| 8004-87-3 |
|
4,7-Diphenyl-1,10-Phenanthroline, 99% (UV-Vis)
| 1662-01-7 |
|
4'-Fluoro-2'-nitroacetanilide, 99+%
| 448-39-5 |
|
DL-2-Amino-4-Pentenoic Acid, 99+%
| 7685-44-1 |
|
4-Chloro-3,5-Dinitrobenzonitrile, 94% (GC)
| 1930-72-9 |
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| 1779-51-7 |
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L-Tyrosine-D11
| 39748-77-1 |
|
Dimethyl pimelate, 99%
| 1732-08-7 |
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Decahydronaphthalene-d18, 99.5 atom % D
| 91-17-8 |
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4,4'-Dimethoxybiphenyl, 98%
| 2132-80-1 |
|
4-Bromo-N,N-Dimethylaniline, 99%
| 586-77-6 |
|
n-Benzylethanolamine, 96% (gc)
| 104-63-2 |
|
Dioctyl phenylphosphonate 98%
| 1754-47-8 |
|
4-Nitrobenzenesulfonyl chloride, 95% (titr.)
| 98-74-8 |
|
1,4-Diisopropylbenzene, 99%
| 100-18-5 |
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4,4'-bis(pentyloxy)azoxybenzene
| 19482-05-4 |
|
Benzyl Cinnamate, 99%
| 103-41-3 |
|
4'-Methoxybutyrophenone, Tech., 93% (GC)
| 4160-51-4 |
|
2,2,5,5-Tetramethyl-3-Imidazoline-1-Oxyl-Carboxylic Acid, Sodium
| 0-00-0 |
|
2-Ethylaniline, 98%
| 578-54-1 |
|
1-Amino-4-methylpiperazine, 99%
| 6928-85-4 |
|
Squalane, 99%
| 111-01-3 |
|
Triphenylcarbenium hexachloroantimonate, 98%
| 1586-91-0 |
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3-(Trifluoromethyl)-Cinnamic Acid, 98%
| 779-89-5 |
|
3-Pentyn-1-ol, 99%
| 10229-10-4 |
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Rhodium Acetate Dimer, Anhydrous,ca 46% Rh
| 5503-41-3 |
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Diethyl Carbonate, P.A.
| 105-58-8 |
|
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| 30414-53-0 |
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Ethyl 3-hydroxybutyrate, 99%
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4-Propylaniline, 98%
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| 109-99-9 |
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| 88-16-4 |
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