**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 824-98-6 |3-Methoxybenzyl chloride | 97 | 212-541-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. The
toxicological properties of this substance have not been fully
investigated. May cause burns to the digestive tract.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. The
toxicological properties of this substance have not been fully
investigated. May cause burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Discard contaminated clothing in a manner
which limits further exposure. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Use with adequate ventilation.
Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 824-98-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear to light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 124 deg C @ 13.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 101 deg C ( 213.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0780g/cm3
Molecular Formula: C8H9ClO
Molecular Weight: 156.5154
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Bases, amines, oxidizing agents, alcohols, steel.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 824-98-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Methoxybenzyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 824-98-6: No information available.
Canada
CAS# 824-98-6 is listed on Canada's DSL List.
CAS# 824-98-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 824-98-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Dimethylaminoacrylonitrile, 99%
| 2407-68-3 |
|
(-)-8-Phenylmenthol, 98%
| 65253-04-5 |
|
4-Nitrophenyl Phosphate, Bis-(Cyclohexyl- Ammonium) Salt, 99+%
| 14545-82-5 |
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3,3,5-Trimethylcyclohexanol,98% Mixture of Cis and Trans
| 116-02-9 |
|
L(-)-Phenylephrine Hydrochloride, 99%
| 61-76-7 |
|
(S)-(+)-2-Chloropropan-1-ol, 96%
| 19210-21-0 |
|
Dimethylthexylsilyl Chloride
| 67373-56-2 |
|
DL-Alanine, 99%
| 302-72-7 |
|
(-)-Menthyl lactate, 98%
| 59259-38-0 |
|
1,1-Diphenyl-2-Picrylhydrazine
| 1707-75-1 |
|
9-Nitroanthracene, 97%
| 602-60-8 |
|
Cis-Stilbene, 97%
| 645-49-8 |
|
2-Fluorobenzoyl Chloride, 97%
| 393-52-2 |
|
Alizarin Yellow R Sodium Salt, 96% (UV-VIS)
| 1718-34-9 |
|
Phenyl carbamate, 97%
| 622-46-8 |
|
m-Methoxybenzyl chloride, 97%
| 824-98-6 |
|
Methyl Violet 2B, Indicator Grade
| 8004-87-3 |
|
4,7-Diphenyl-1,10-Phenanthroline, 99% (UV-Vis)
| 1662-01-7 |
|
4'-Fluoro-2'-nitroacetanilide, 99+%
| 448-39-5 |
|
DL-2-Amino-4-Pentenoic Acid, 99+%
| 7685-44-1 |
|
4-Chloro-3,5-Dinitrobenzonitrile, 94% (GC)
| 1930-72-9 |
|
(n-Butyl)triphenylphosphonium bromide, 99%
| 1779-51-7 |
|
L-Tyrosine-D11
| 39748-77-1 |
|
Dimethyl pimelate, 99%
| 1732-08-7 |
|
Decahydronaphthalene-d18, 99.5 atom % D
| 91-17-8 |
|
4,4'-Dimethoxybiphenyl, 98%
| 2132-80-1 |
|
4-Bromo-N,N-Dimethylaniline, 99%
| 586-77-6 |
|
n-Benzylethanolamine, 96% (gc)
| 104-63-2 |
|
Dioctyl phenylphosphonate 98%
| 1754-47-8 |
|
4-Nitrobenzenesulfonyl chloride, 95% (titr.)
| 98-74-8 |
|
1,4-Diisopropylbenzene, 99%
| 100-18-5 |
|
4,4'-bis(pentyloxy)azoxybenzene
| 19482-05-4 |
|
Benzyl Cinnamate, 99%
| 103-41-3 |
|
4'-Methoxybutyrophenone, Tech., 93% (GC)
| 4160-51-4 |
|
2,2,5,5-Tetramethyl-3-Imidazoline-1-Oxyl-Carboxylic Acid, Sodium
| 0-00-0 |
|
2-Ethylaniline, 98%
| 578-54-1 |
|
1-Amino-4-methylpiperazine, 99%
| 6928-85-4 |
|
Squalane, 99%
| 111-01-3 |
|
Triphenylcarbenium hexachloroantimonate, 98%
| 1586-91-0 |
|
3-(Trifluoromethyl)-Cinnamic Acid, 98%
| 779-89-5 |
|
3-Pentyn-1-ol, 99%
| 10229-10-4 |
|
Rhodium Acetate Dimer, Anhydrous,ca 46% Rh
| 5503-41-3 |
|
Diethyl Carbonate, P.A.
| 105-58-8 |
|
Methyl 3-oxo-pentanoate, 98%
| 30414-53-0 |
|
Ethyl 3-hydroxybutyrate, 99%
| 5405-41-4 |
|
4-Propylaniline, 98%
| 2696-84-6 |
|
2'-Fluoro-4'-Methoxyacetophenone, 99%
| 74457-86-6 |
|
Lithiumtriethylborodeuteride, 1M solution in THF
| 109-99-9 |
|
2-Chlorobenzotrifluoride, 99%
| 88-16-4 |
|
1-Chloro-1-phenylethane, 99%
| 672-65-1 |
|
|