**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 578-54-1 |2-Ethylaniline | 98 | 209-424-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Methemoglobinemia is characterized by dizziness, drowsiness,
headache, shortness of breath, cyanosis (bluish discoloration of
skin due to deficient oxygenation of the blood), rapid heart rate and
chocolate-brown colored blood. Overexposure may cause
methemoglobinemia.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Absorption into the body leads to the formation of methemoglobin
which in sufficient concentrations causes cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Containers may explode when heated. Combustible liquid and
vapor. Vapors are heavier than air and may travel to a source of
ignition and flash back. Vapors can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
This material is lighter than water and insoluble in water. The fire
could easily be spread by the use of water in an area where the water
cannot be contained. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Keep away from heat and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 578-54-1:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear pale yellow to red brown
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.11 mmHg @ 20
Viscosity: Not available.
Boiling Point: 210 deg C @ 760 mmHg
Freezing/Melting Point: -44 deg C
Autoignition Temperature: Not available.
Flash Point: 85 deg C ( 185.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: .980g/cm3
Molecular Formula: C8H11N
Molecular Weight: 121.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, acid chlorides, acid anhydrides,
chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 578-54-1: BX9800000
LD50/LC50:
CAS# 578-54-1: Oral, rat: LD50 = 1260 mg/kg.
Carcinogenicity:
2-Ethylaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 2-ETHYLANILINE
Hazard Class: 6.1
UN Number: 2273
Packing Group: III
IMO
Shipping Name: 2-ETHYLANILINE
Hazard Class: 6.1
UN Number: 2273
Packing Group: III
RID/ADR
Shipping Name: 2-ETHYLANILINE
Hazard Class: 6.1
UN Number: 2273
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 578-54-1: 2
Canada
CAS# 578-54-1 is listed on Canada's DSL List.
CAS# 578-54-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 578-54-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/09/1998 Revision #3 Date: 12/02/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Dimethylaminoacrylonitrile, 99%
| 2407-68-3 |
|
(-)-8-Phenylmenthol, 98%
| 65253-04-5 |
|
4-Nitrophenyl Phosphate, Bis-(Cyclohexyl- Ammonium) Salt, 99+%
| 14545-82-5 |
|
3,3,5-Trimethylcyclohexanol,98% Mixture of Cis and Trans
| 116-02-9 |
|
L(-)-Phenylephrine Hydrochloride, 99%
| 61-76-7 |
|
(S)-(+)-2-Chloropropan-1-ol, 96%
| 19210-21-0 |
|
Dimethylthexylsilyl Chloride
| 67373-56-2 |
|
DL-Alanine, 99%
| 302-72-7 |
|
(-)-Menthyl lactate, 98%
| 59259-38-0 |
|
1,1-Diphenyl-2-Picrylhydrazine
| 1707-75-1 |
|
9-Nitroanthracene, 97%
| 602-60-8 |
|
Cis-Stilbene, 97%
| 645-49-8 |
|
2-Fluorobenzoyl Chloride, 97%
| 393-52-2 |
|
Alizarin Yellow R Sodium Salt, 96% (UV-VIS)
| 1718-34-9 |
|
Phenyl carbamate, 97%
| 622-46-8 |
|
m-Methoxybenzyl chloride, 97%
| 824-98-6 |
|
Methyl Violet 2B, Indicator Grade
| 8004-87-3 |
|
4,7-Diphenyl-1,10-Phenanthroline, 99% (UV-Vis)
| 1662-01-7 |
|
4'-Fluoro-2'-nitroacetanilide, 99+%
| 448-39-5 |
|
DL-2-Amino-4-Pentenoic Acid, 99+%
| 7685-44-1 |
|
4-Chloro-3,5-Dinitrobenzonitrile, 94% (GC)
| 1930-72-9 |
|
(n-Butyl)triphenylphosphonium bromide, 99%
| 1779-51-7 |
|
L-Tyrosine-D11
| 39748-77-1 |
|
Dimethyl pimelate, 99%
| 1732-08-7 |
|
Decahydronaphthalene-d18, 99.5 atom % D
| 91-17-8 |
|
4,4'-Dimethoxybiphenyl, 98%
| 2132-80-1 |
|
4-Bromo-N,N-Dimethylaniline, 99%
| 586-77-6 |
|
n-Benzylethanolamine, 96% (gc)
| 104-63-2 |
|
Dioctyl phenylphosphonate 98%
| 1754-47-8 |
|
4-Nitrobenzenesulfonyl chloride, 95% (titr.)
| 98-74-8 |
|
1,4-Diisopropylbenzene, 99%
| 100-18-5 |
|
4,4'-bis(pentyloxy)azoxybenzene
| 19482-05-4 |
|
Benzyl Cinnamate, 99%
| 103-41-3 |
|
4'-Methoxybutyrophenone, Tech., 93% (GC)
| 4160-51-4 |
|
2,2,5,5-Tetramethyl-3-Imidazoline-1-Oxyl-Carboxylic Acid, Sodium
| 0-00-0 |
|
2-Ethylaniline, 98%
| 578-54-1 |
|
1-Amino-4-methylpiperazine, 99%
| 6928-85-4 |
|
Squalane, 99%
| 111-01-3 |
|
Triphenylcarbenium hexachloroantimonate, 98%
| 1586-91-0 |
|
3-(Trifluoromethyl)-Cinnamic Acid, 98%
| 779-89-5 |
|
3-Pentyn-1-ol, 99%
| 10229-10-4 |
|
Rhodium Acetate Dimer, Anhydrous,ca 46% Rh
| 5503-41-3 |
|
Diethyl Carbonate, P.A.
| 105-58-8 |
|
Methyl 3-oxo-pentanoate, 98%
| 30414-53-0 |
|
Ethyl 3-hydroxybutyrate, 99%
| 5405-41-4 |
|
4-Propylaniline, 98%
| 2696-84-6 |
|
2'-Fluoro-4'-Methoxyacetophenone, 99%
| 74457-86-6 |
|
Lithiumtriethylborodeuteride, 1M solution in THF
| 109-99-9 |
|
2-Chlorobenzotrifluoride, 99%
| 88-16-4 |
|
1-Chloro-1-phenylethane, 99%
| 672-65-1 |
|
|